AIIMS 1987 Chemistry Question Paper with Answer and Solution

11 QuestionsEnglishWith Solutions

ChemistryQ111 of 11 questions

Page 1 of 1 · English

1
ChemistryEasyMCQAIIMS · 1987
In $HCHO$,the carbon atom has which hybridization?
A
$sp$
B
$sp^2$
C
$sp^3$
D
All of the above

Solution

(B) In $HCHO$ (formaldehyde),the carbon atom is bonded to two hydrogen atoms by single bonds and one oxygen atom by a double bond.
The steric number of the carbon atom is calculated as: $\text{Steric Number} = \text{Number of sigma bonds} + \text{Number of lone pairs} = 3 + 0 = 3$.
$A$ steric number of $3$ corresponds to $sp^2$ hybridization.
Therefore,the correct option is $(B)$.
2
ChemistryMediumMCQAIIMS · 1987
The elements of group $IA$ provide a colour to the flame of a Bunsen burner due to
A
Low ionization potential
B
Low melting point
C
Softness
D
Presence of one electron in the outermost orbit

Solution

(A) The alkali metals $(Group \ IA)$ exhibit a characteristic flame color because they possess low ionization potential.
When heated in a Bunsen burner,the valence electrons absorb energy and are excited from a lower energy level to a higher energy level.
As these excited electrons return to their ground state,they emit the absorbed energy in the form of visible light,which corresponds to a specific color.
3
ChemistryEasyMCQAIIMS · 1987
Solvay's process is used for the preparation of
A
Ammonia
B
Sodium bicarbonate
C
Sodium carbonate
D
Calcium carbonate

Solution

(C) The Solvay process is an industrial method used for the large-scale production of $Na_2CO_3$ (Sodium carbonate).
In this process,$CO_2$ and $NH_3$ are passed through a concentrated solution of $NaCl$ (brine) to form $NaHCO_3$,which is then heated to yield $Na_2CO_3$.
4
ChemistryMediumMCQAIIMS · 1987
Which of the following is not formed by the reaction of $Cl_2$ on $CH_4$ in sunlight?
A
$CHCl_3$
B
$CH_3Cl$
C
$CH_3CH_3$
D
$CH_3CH_2CH_3$

Solution

(D) The reaction of $CH_4$ with $Cl_2$ in the presence of sunlight follows a free radical substitution mechanism.
The successive chlorination products are $CH_3Cl$, $CH_2Cl_2$, $CHCl_3$, and $CCl_4$.
Additionally, the coupling of methyl free radicals $(\cdot CH_3 + \cdot CH_3 \to CH_3-CH_3)$ leads to the formation of ethane $(CH_3CH_3)$.
Propane $(CH_3CH_2CH_3)$ is not formed in this reaction because it requires a higher carbon chain length than what is available from the reactants.
5
ChemistryMediumMCQAIIMS · 1987
$A$ compound '$X$' on ozonolysis forms two molecules of $HCHO$. Compound '$X$' is
A
$C_2H_4$
B
$C_2H_2$
C
$C_2H_6$
D
$C_6H_6$

Solution

(A) Ozonolysis of an alkene involves the cleavage of the $C=C$ double bond to form carbonyl compounds.
For a compound '$X$' to yield two molecules of formaldehyde $(HCHO)$ upon ozonolysis,the structure must be ethene $(CH_2=CH_2)$.
The reaction is: $CH_2=CH_2 \xrightarrow[(2) Zn/H_2O]{(1) O_3} 2HCHO$.
Therefore,the compound '$X$' is $C_2H_4$.
6
ChemistryMediumMCQAIIMS · 1987
Which of the following bonds makes a hydrocarbon most reactive?
A
$C \equiv C$
B
$C = C$
C
$C - C$
D
All of these

Solution

(A) The correct answer is $A$. The $C \equiv C$ bond (alkyne) is generally considered more reactive towards electrophilic addition reactions compared to $C = C$ (alkene) and $C - C$ (alkane) due to the presence of two $\pi$-bonds and the nature of $sp$-hybridized carbon atoms.
7
ChemistryMediumMCQAIIMS · 1987
What happens when a mixture of acetylene and hydrogen is passed over heated Lindlar's catalyst?
A
$Ethane$ and water are formed
B
$Ethylene$ is formed
C
$Acetylene$ and $ethane$ are formed
D
None of these

Solution

(B) The reaction of acetylene $(CH \equiv CH)$ with hydrogen $(H_2)$ in the presence of Lindlar's catalyst $(Pd/BaSO_4)$ is a partial hydrogenation reaction.
$CH \equiv CH + H_2 \xrightarrow[Lindlar \ Catalyst]{Pd/BaSO_4} CH_2 = CH_2$
Thus,acetylene is reduced to ethylene $(CH_2 = CH_2)$.
8
ChemistryMediumMCQAIIMS · 1987
Which one of the following combines with $Fe(II)$ ions to form a brown complex?
A
$N_2O$
B
$NO$
C
$N_2O_3$
D
$N_2O_5$

Solution

(B) The brown ring test is used to detect the presence of nitrate ions $(NO_3^-)$ in a solution.
In this test,$Fe(II)$ ions react with $NO$ (nitric oxide) to form a brown-colored coordination complex.
The reaction is: $[Fe(H_2O)_6]^{2+} + NO \to [Fe(H_2O)_5(NO)]^{2+} + H_2O$.
This complex,$[Fe(H_2O)_5(NO)]^{2+}$,is responsible for the brown ring observed at the junction of the two layers.
9
ChemistryEasyMCQAIIMS · 1987
$Fluorine$ does not form positive oxidation states because
A
It is the most electronegative element
B
It forms only anions in ionic compounds
C
It cannot form multiple bonding
D
It shows non-bonded electron pair repulsion due to small size

Solution

(A) $Fluorine$ is the most electronegative element in the periodic table.
Due to its very high electronegativity,it cannot lose electrons to form positive oxidation states and always exhibits a $-1$ oxidation state in its compounds.
10
ChemistryMediumMCQAIIMS · 1987
Which of the following combines with $Fe(II)$ ions to form a brown complex?
A
$N_2O$
B
$NO$
C
$N_2O_3$
D
$N_2O_5$

Solution

(B) The brown ring test is used to detect the presence of nitrate ions $(NO_3^-)$ in a solution.
When a freshly prepared ferrous sulfate solution is added to the nitrate solution followed by the careful addition of concentrated sulfuric acid along the sides of the test tube,a brown ring is formed at the junction of the two layers.
The reaction involves the reduction of nitrate to nitric oxide $(NO)$,which then reacts with the $Fe(II)$ ions to form the brown complex $[Fe(H_2O)_5(NO)]SO_4$.
11
ChemistryMediumMCQAIIMS · 1987
Which reagent gives an orange-coloured precipitate with acetaldehyde?
A
$2,4-DNP$
B
$NH_2OH$
C
Iodine
D
$NaHSO_3$

Solution

(A) $2,4-Dinitrophenylhydrazine$ $(2,4-DNP)$,also known as Brady's reagent,reacts with aldehydes and ketones to form $2,4-dinitrophenylhydrazones$.
These derivatives typically appear as orange,yellow,or red crystalline precipitates.
Acetaldehyde $(CH_3CHO)$ reacts with $2,4-DNP$ to form an orange crystalline solid,which is acetaldehyde $2,4-dinitrophenylhydrazone$.

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