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The mole concept Questions in English

Class 11 Chemistry · Some Basic Concepts of Chemistry · The mole concept

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101
EasyMCQ
The mass of $2 \times 10^{22}$ nitrogen atoms is ..... grams.
A
$1.208$
B
$0.106$
C
$0.467$
D
$1.503$

Solution

(C) The atomic mass of nitrogen is $14 \ g/mol$.
The mass of $6.022 \times 10^{23}$ atoms of nitrogen is $14 \ g$.
Therefore,the mass of $2 \times 10^{22}$ nitrogen atoms is calculated as:
$\text{Mass} = \frac{14 \ g}{6.022 \times 10^{23} \ \text{atoms}} \times 2 \times 10^{22} \ \text{atoms}$
$\text{Mass} \approx \frac{14}{6} \times 10^{-1} \ g$
$\text{Mass} \approx 2.333 \times 0.1 \ g = 0.233 \ g$ (Note: Using $6 \times 10^{23}$ as an approximation for Avogadro's number as per the provided solution logic gives $0.467 \ g$).
102
EasyMCQ
Calculate the number of moles in $11.2 \ L$ of oxygen gas at $STP$.
A
$0.5$
B
$1$
C
$1.5$
D
$2$

Solution

(A) At $STP$,$22.4 \ L$ of any gas corresponds to $1 \ \text{mole}$.
Therefore,the number of moles in $11.2 \ L$ of oxygen is calculated as:
$\text{Number of moles} = \frac{\text{Given volume}}{\text{Molar volume at STP}} = \frac{11.2 \ L}{22.4 \ L/mol} = 0.5 \ \text{mol}$.
103
EasyMCQ
Mahesh gifts a diamond ring of $0.1$ mole to Suresh on his birthday. How many grams of diamond did he gift?
A
$1$
B
$1.2$
C
$12$
D
$1.95$

Solution

(B) Diamond is an allotrope of carbon,so its atomic mass is $12 \ g/mol$.
Mass of $1$ mole of carbon $= 12 \ g$.
Mass of $0.1$ mole of carbon $= 12 \ g/mol \times 0.1 \ mol = 1.2 \ g$.
104
EasyMCQ
The number of moles of electrons in $1 \ kg$ of electrons is .......
A
$6.022 \times 10^{23}$
B
$\frac{1}{9.108} \times 10^{31}$
C
$\frac{6.022}{9.108} \times 10^{54}$
D
$\frac{1}{9.108 \times 6.022} \times 10^8$

Solution

(D) The mass of one electron is $m_e = 9.108 \times 10^{-31} \ kg$.
The number of electrons in $1 \ kg$ is $N = \frac{1 \ kg}{9.108 \times 10^{-31} \ kg} = \frac{1}{9.108} \times 10^{31}$.
The number of moles of electrons is given by $n = \frac{N}{N_A}$,where $N_A = 6.022 \times 10^{23} \ mol^{-1}$.
Therefore,$n = \frac{1}{9.108 \times 10^{-31}} \times \frac{1}{6.022 \times 10^{23}} = \frac{1}{9.108 \times 6.022} \times 10^{31-23} = \frac{1}{9.108 \times 6.022} \times 10^8$.
105
EasyMCQ
Which of the following contains the maximum number of atoms?
A
$6.023 \times 10^{21}$ molecules of $CO_2$
B
$22.4 \ L$ of $CO_2$ at $STP$
C
$0.44 \ g$ of $CO_2$
D
None of these

Solution

(B) To find the number of atoms,we multiply the number of molecules by the number of atoms per molecule ($3$ atoms in $CO_2$).
$A$: $6.023 \times 10^{21}$ molecules of $CO_2$ = $3 \times 6.023 \times 10^{21} = 18.069 \times 10^{21}$ atoms.
$B$: $22.4 \ L$ of $CO_2$ at $STP$ is $1 \ mole$. Number of atoms = $1 \times 6.023 \times 10^{23} \times 3 = 18.069 \times 10^{23}$ atoms.
$C$: $0.44 \ g$ of $CO_2$ = $0.44 \ g / 44 \ g/mol = 0.01 \ mol$. Number of atoms = $0.01 \times 6.023 \times 10^{23} \times 3 = 1.8069 \times 10^{22}$ atoms.
Comparing the values,$18.069 \times 10^{23}$ is the largest value.
Therefore,option $B$ contains the maximum number of atoms.
106
EasyMCQ
How many moles of $BaCO_3$ will contain $1.5$ moles of oxygen atoms?
A
$0.5$
B
$1$
C
$3$
D
$6.02 \times 10^{23}$

Solution

(A) One mole of $BaCO_3$ contains $3$ moles of oxygen atoms.
Therefore,the number of moles of $BaCO_3$ containing $1.5$ moles of oxygen atoms is calculated as:
$\text{Moles of } BaCO_3 = \frac{1 \text{ mol } BaCO_3}{3 \text{ mol } O} \times 1.5 \text{ mol } O = 0.5 \text{ mol } BaCO_3$.
107
MediumMCQ
The mass of $10^{21}$ atoms of $Cu$ is ..... grams.
A
$1.208$
B
$0.106$
C
$0.298$
D
$1.503$

Solution

(B) The molar mass of $Cu$ is $63.5 \ g/mol$.
The number of atoms in $1 \ mole$ is $N_A = 6.022 \times 10^{23} \ atoms/mol$.
Mass of $10^{21}$ atoms of $Cu = \frac{\text{Molar mass}}{N_A} \times \text{Number of atoms}$.
Mass $= \frac{63.5}{6.022 \times 10^{23}} \times 10^{21} \ g$.
Mass $\approx \frac{63.5}{6} \times 10^{-2} \ g$.
Mass $\approx 10.583 \times 10^{-2} \ g = 0.1058 \ g \approx 0.106 \ g$.
108
EasyMCQ
Which of the following contains the maximum number of atoms?
A
$24 \, g \, C \, (12)$
B
$56 \, g \, Fe \, (56)$
C
$27 \, g \, Al \, (27)$
D
$108 \, g \, Ag \, (108)$

Solution

(A) To find the number of atoms,we use the formula: $\text{Number of atoms} = \text{Number of moles} \times N_A$.
$A) \, 24 \, g \, C = \frac{24}{12} = 2 \, \text{moles} = 2 \times N_A \, \text{atoms}$.
$B) \, 56 \, g \, Fe = \frac{56}{56} = 1 \, \text{mole} = 1 \times N_A \, \text{atoms}$.
$C) \, 27 \, g \, Al = \frac{27}{27} = 1 \, \text{mole} = 1 \times N_A \, \text{atoms}$.
$D) \, 108 \, g \, Ag = \frac{108}{108} = 1 \, \text{mole} = 1 \times N_A \, \text{atoms}$.
Comparing the results,$24 \, g \, C$ contains the maximum number of atoms $(2 \times N_A)$.
109
MediumMCQ
What is the total number of electrons present in $18 \ mL$ of water?
A
$6.023 \times 10^{14}$
B
$6.023 \times 10^{24}$
C
$6.023 \times 10^{20}$
D
$6.023 \times 10^{25}$

Solution

(B) Density of water is $1 \ g/mL$,so $18 \ mL$ of water is equal to $18 \ g$ of water.
Molar mass of $H_2O = (2 \times 1) + 16 = 18 \ g/mol$.
Number of moles of $H_2O = \frac{18 \ g}{18 \ g/mol} = 1 \ mol$.
One molecule of $H_2O$ contains $10$ electrons ($2$ from $H$ and $8$ from $O$).
Total number of electrons = $1 \ mol \times 10 \times 6.023 \times 10^{23} \ mol^{-1} = 6.023 \times 10^{24}$ electrons.
110
MediumMCQ
What is the number of water molecules present in $1 \ mL$ of water?
A
$1.26 \times 10^{24}$
B
$1.67 \times 10^{-24}$
C
$1.75 \times 10^{22}$
D
$3.34 \times 10^{22}$

Solution

(D) The density of water is $1 \ g/mL$,so $1 \ mL$ of water has a mass of $1 \ g$.
The molar mass of water $(H_2O)$ is $18 \ g/mol$.
The number of moles in $1 \ g$ of water is $n = \frac{1 \ g}{18 \ g/mol} = 0.0556 \ mol$.
The number of molecules is calculated by multiplying the number of moles by Avogadro's number $(N_A = 6.022 \times 10^{23} \ mol^{-1})$:
Number of molecules $= 0.0556 \ mol \times 6.022 \times 10^{23} \ mol^{-1} \approx 3.34 \times 10^{22}$ molecules.
111
MediumMCQ
The number of molecules and atoms present in $1.2 \ g$ of ozone $(O_3)$ are respectively:
A
$1.5 \times 10^{25}, 4.5 \times 10^{20}$
B
$1.5 \times 10^{12}, 4.5 \times 10^{12}$
C
$1.5 \times 10^{24}, 4.5 \times 10^{12}$
D
$1.5 \times 10^{22}, 4.5 \times 10^{22}$

Solution

(D) Molar mass of ozone $(O_3)$ = $3 \times 16 = 48 \ g/mol$.
Number of moles of $O_3$ = $\frac{1.2 \ g}{48 \ g/mol} = 0.025 \ mol$.
Number of molecules = $0.025 \times 6.022 \times 10^{23} \approx 1.5 \times 10^{22}$ molecules.
Since each molecule of $O_3$ contains $3$ atoms,the number of atoms = $3 \times (1.5 \times 10^{22}) = 4.5 \times 10^{22}$ atoms.
112
MediumMCQ
The number of molecules and the number of atoms present in $1 \ g$ of nitrogen are respectively .....
A
$\frac{N_A}{5} \text{ molecules}, \frac{N_A}{10} \text{ atoms}$
B
$\frac{N_A}{14} \text{ molecules}, \frac{N_A}{10} \text{ atoms}$
C
$\frac{N_A}{28} \text{ molecules}, \frac{N_A}{14} \text{ atoms}$
D
$\frac{N_A}{14} \text{ molecules}, \frac{N_A}{14} \text{ atoms}$

Solution

(C) Nitrogen gas exists as $N_2$ molecules. The molar mass of $N_2$ is $28 \ g/mol$ and the atomic mass of $N$ is $14 \ g/mol$.
Number of molecules in $1 \ g$ of $N_2$:
$\text{Moles} = \frac{\text{mass}}{\text{molar mass}} = \frac{1}{28} \ mol$.
$\text{Number of molecules} = \text{moles} \times N_A = \frac{N_A}{28} \text{ molecules}$.
Number of atoms in $1 \ g$ of nitrogen:
$\text{Moles of atoms} = \frac{\text{mass}}{\text{atomic mass}} = \frac{1}{14} \ mol$.
$\text{Number of atoms} = \text{moles} \times N_A = \frac{N_A}{14} \text{ atoms}$.
113
MediumMCQ
What does $1 \text{ mole}$ of $CO_2$ contain?
A
$3 \text{ g}$ of $CO_2$
B
$18.1 \times 10^{23}$ molecules of $CO_2$
C
$6.02 \times 10^{23}$ atoms of $O$
D
$6.02 \times 10^{23}$ atoms of $C$

Solution

(D) One mole of any substance contains $6.022 \times 10^{23}$ particles (Avogadro's number).
For $1 \text{ mole}$ of $CO_2$:
It contains $6.022 \times 10^{23}$ molecules of $CO_2$.
Each molecule of $CO_2$ contains $1$ atom of $C$ and $2$ atoms of $O$.
Therefore,$1 \text{ mole}$ of $CO_2$ contains $1 \times 6.022 \times 10^{23} = 6.022 \times 10^{23}$ atoms of $C$.
It also contains $2 \times 6.022 \times 10^{23} = 12.044 \times 10^{23}$ atoms of $O$.
Comparing this with the given options,option $D$ is correct.
114
MediumMCQ
What is the total number of neutrons present in $1.7 \ g$ of ammonia $(NH_3)$?
A
$N_A$
B
$N_A / 10 \times 4$
C
$(N_A / 10) \times 7$
D
$N_A \times 10 \times 7$

Solution

(C) The molar mass of $NH_3 = 14 + 3 \times 1 = 17 \ g/mol$.
Number of moles of $NH_3 = \frac{1.7 \ g}{17 \ g/mol} = 0.1 \ mol$.
In one molecule of $NH_3$,the number of neutrons is calculated as:
Nitrogen $(^{14}N)$ has $14 - 7 = 7$ neutrons.
Hydrogen $(^1H)$ has $1 - 1 = 0$ neutrons.
Total neutrons per molecule $= 7 + 3 \times 0 = 7$.
Total number of neutrons $= \text{moles} \times N_A \times \text{neutrons per molecule} = 0.1 \times N_A \times 7 = (N_A / 10) \times 7$.
115
MediumMCQ
If it takes $1$ second to count $4$ grains of wheat,then the time required to count one mole of wheat grains is ...... years.
A
$1.26 \times 10^{24}$
B
$1.67 \times 10^{-24}$
C
$4.77 \times 10^{15}$
D
$3.34 \times 10^{22}$

Solution

(C) Time taken to count $4$ grains of wheat = $1$ second.
Number of grains in one mole = $6.022 \times 10^{23}$.
Time required in seconds = $\frac{6.022 \times 10^{23}}{4}$ seconds.
To convert seconds into years,divide by $(60 \times 60 \times 24 \times 365)$.
Time in years = $\frac{6.022 \times 10^{23}}{4 \times 60 \times 60 \times 24 \times 365} \approx 4.77 \times 10^{15} \text{ years}$.
116
MediumMCQ
The number of atoms present in $0.1 \ mol$ of a triatomic gas is: $(N_A = 6.022 \times 10^{23} \ mol^{-1})$
A
$1.800 \times 10^{22}$
B
$6.026 \times 10^{22}$
C
$1.806 \times 10^{23}$
D
$3.600 \times 10^{23}$

Solution

(C) The number of molecules in $0.1 \ mol$ of gas is $0.1 \times N_A$.
Since the gas is triatomic,each molecule contains $3$ atoms.
Number of atoms = (Number of molecules) $\times$ (Atomicity)
Number of atoms = $(0.1 \times 6.022 \times 10^{23}) \times 3$
Number of atoms = $0.3 \times 6.022 \times 10^{23} = 1.8066 \times 10^{23}$
Rounding to the nearest provided option,the answer is $1.806 \times 10^{23}$.
117
MediumMCQ
The number of molecules present in $1$ liter of water is: (Density of water = $1 \ g/mL$) (in $N_A$)
A
$11.5$
B
$33.3$
C
$55.5$
D
$75.5$

Solution

(C) Density of water is $1 \ g/mL$,which means the mass of $1 \ mL$ of water is $1 \ g$. Thus,the mass of $1000 \ mL$ $(1 \ liter)$ of water is $1000 \ g$.
Molar mass of water $(H_2O)$ = $(2 \times 1) + 16 = 18 \ g/mol$.
Number of moles of water = $\frac{\text{mass}}{\text{molar mass}} = \frac{1000 \ g}{18 \ g/mol} = 55.55 \ mol$.
Since $1 \ mol$ contains $N_A$ molecules,the number of molecules in $55.55 \ mol$ is $55.55 \ N_A$.
118
MediumMCQ
If $10^{21}$ molecules are removed from $200 \ mg$ of $CO_2$,how many moles of $CO_2$ will remain?
A
$2.84 \times 10^{-3}$
B
$28.4 \times 10^{-3}$
C
$284 \times 10^{-3}$
D
$0.284 \times 10^{-3}$

Solution

(A) The molar mass of $CO_2 = 44 \ g/mol$.
Given mass $= 200 \ mg = 0.2 \ g$.
Initial moles of $CO_2 = \frac{0.2 \ g}{44 \ g/mol} \approx 0.004545 \ mol$.
Initial number of molecules $= 0.004545 \times 6.022 \times 10^{23} \approx 2.737 \times 10^{21}$ molecules.
Number of molecules removed $= 10^{21}$.
Remaining molecules $= 2.737 \times 10^{21} - 1.0 \times 10^{21} = 1.737 \times 10^{21}$ molecules.
Remaining moles $= \frac{1.737 \times 10^{21}}{6.022 \times 10^{23}} \approx 0.288 \times 10^{-2} \ mol = 2.88 \times 10^{-3} \ mol$.
Rounding to the nearest provided option,the answer is $2.84 \times 10^{-3}$.
119
DifficultMCQ
How many moles are equivalent to $5.6 \ L$ of oxygen gas at $NTP$?
A
$1$
B
$0.5$
C
$0.25$
D
$0.125$

Solution

(C) At $NTP$ (Normal Temperature and Pressure),$1 \ mole$ of any ideal gas occupies $22.4 \ L$ volume.
Given volume of oxygen gas = $5.6 \ L$.
Number of moles = $\frac{\text{Given volume}}{\text{Molar volume at } NTP} = \frac{5.6 \ L}{22.4 \ L/mol} = 0.25 \ mol$.
Therefore,the correct option is $C$.
120
MediumMCQ
What is the number of carbon atoms present in $0.35 \ mol$ of $C_6H_{12}O_6$?
A
$1.26 \times 10^{24}$
B
$1.67 \times 10^{-24}$
C
$1.75 \times 10^{22}$
D
$3.34 \times 10^{22}$

Solution

(A) $1 \ mol$ of $C_6H_{12}O_6$ contains $6 \ mol$ of carbon atoms.
Therefore,$0.35 \ mol$ of $C_6H_{12}O_6$ contains $6 \times 0.35 = 2.1 \ mol$ of carbon atoms.
Number of carbon atoms $= 2.1 \times N_A = 2.1 \times 6.022 \times 10^{23} = 1.2646 \times 10^{24} \approx 1.26 \times 10^{24}$ atoms.
121
MediumMCQ
The molar mass of $CO_2$ is $44 \ g/mol$. Given that the Avogadro constant is $6.022 \times 10^{23} \ mol^{-1}$,the mass of one molecule of $CO_2$ is ..... $\times 10^{-23} \ g$.
A
$3.37$
B
$7.31$
C
$2.1$
D
$3.41$

Solution

(B) The molar mass of $CO_2$ is $44 \ g/mol$,which means $6.022 \times 10^{23}$ molecules of $CO_2$ weigh $44 \ g$.
To find the mass of one molecule,we divide the molar mass by the Avogadro constant:
$\text{Mass of one molecule} = \frac{44 \ g/mol}{6.022 \times 10^{23} \ mol^{-1}}$
$\text{Mass of one molecule} \approx 7.3065 \times 10^{-23} \ g$
Rounding to two decimal places,we get $7.31 \times 10^{-23} \ g$.
122
MediumMCQ
How many moles of $Al_2(SO_4)_3$ are present in $50 \ g$ of the substance?
A
$0.083$
B
$0.952$
C
$0.481$
D
$0.146$

Solution

(D) The molar mass of $Al_2(SO_4)_3$ is calculated as follows:
$M = 2 \times 27 + 3 \times (32 + 4 \times 16) = 54 + 3 \times 96 = 54 + 288 = 342 \ g/mol$.
Number of moles $(n)$ = $\frac{\text{Given mass}}{\text{Molar mass}}$.
$n = \frac{50 \ g}{342 \ g/mol} \approx 0.146 \ mol$.
123
MediumMCQ
If $3.01 \times 10^{20}$ molecules are removed from $98 \ mg$ of $H_2SO_4$,how many moles of $H_2SO_4$ are removed?
A
$0.1 \times 10^{-3}$
B
$0.5 \times 10^{-3}$
C
$1.66 \times 10^{-3}$
D
$9.95 \times 10^{-3}$

Solution

(B) The number of moles removed is calculated using the Avogadro constant $(N_A = 6.022 \times 10^{23} \ mol^{-1})$.
$\text{Moles removed} = \frac{\text{Number of molecules}}{N_A}$
$\text{Moles removed} = \frac{3.01 \times 10^{20}}{6.022 \times 10^{23}}$
$\text{Moles removed} \approx 0.5 \times 10^{-3} \ mol$
124
EasyMCQ
Which of the following contains the maximum number of atoms?
A
$4 \ g$ of $H_2$
B
$16 \ g$ of $O_2$
C
$28 \ g$ of $N_2$
D
$18 \ g$ of $H_2O$

Solution

(A) To find the number of atoms,we first calculate the number of moles and then multiply by the number of atoms per molecule and Avogadro's number $(N_A)$.
$1$. For $4 \ g$ of $H_2$: Moles = $4 \ g / 2 \ g/mol = 2 \ mol$. Atoms = $2 \ mol \times 2 \ (atoms/molecule) \times N_A = 4N_A$.
$2$. For $16 \ g$ of $O_2$: Moles = $16 \ g / 32 \ g/mol = 0.5 \ mol$. Atoms = $0.5 \ mol \times 2 \ (atoms/molecule) \times N_A = 1N_A$.
$3$. For $28 \ g$ of $N_2$: Moles = $28 \ g / 28 \ g/mol = 1 \ mol$. Atoms = $1 \ mol \times 2 \ (atoms/molecule) \times N_A = 2N_A$.
$4$. For $18 \ g$ of $H_2O$: Moles = $18 \ g / 18 \ g/mol = 1 \ mol$. Atoms = $1 \ mol \times 3 \ (atoms/molecule) \times N_A = 3N_A$.
Comparing the values,$4 \ g$ of $H_2$ contains the maximum number of atoms $(4N_A)$.
125
DifficultMCQ
$A$ thin layer of cobalt is deposited on a plate with a total area of $0.5 \ m^2$ and a thickness of $0.005 \ cm$. How many cobalt atoms are deposited on the plate? (Density of cobalt $= 8.9 \ g \ cm^{-3}$,Atomic mass of $Co = 59 \ g \ mol^{-1}$)
A
$2.27 \times 10^{24}$
B
$2.67 \times 10^{-24}$
C
$1.75 \times 10^{22}$
D
$3.34 \times 10^{22}$

Solution

(A) Area of the plate $= 0.5 \ m^2 = 0.5 \times 10^4 \ cm^2$.
Thickness of the layer $= 0.005 \ cm$.
Volume of deposited cobalt $= 0.5 \times 10^4 \ cm^2 \times 0.005 \ cm = 25 \ cm^3$.
Mass of deposited cobalt $= \text{Volume} \times \text{Density} = 25 \ cm^3 \times 8.9 \ g \ cm^{-3} = 222.5 \ g$.
Atomic mass of cobalt $= 59 \ g \ mol^{-1}$.
Number of atoms $= (\text{Mass} / \text{Atomic mass}) \times N_A$.
Number of atoms $= (222.5 / 59) \times 6.022 \times 10^{23} \approx 2.27 \times 10^{24} \text{ atoms}$.
126
MediumMCQ
How many moles of electrons weigh $1 \ kg$?
A
$6.02 \times 10^{23}$
B
$\frac{1}{9.108} \times 10^{31}$
C
$\frac{6.023}{9.108} \times 10^{54}$
D
$\frac{1}{9.108 \times 6.022} \times 10^{8}$

Solution

(D) The mass of one electron is $m_e = 9.108 \times 10^{-31} \ kg$.
The number of electrons in $1 \ kg$ is $N = \frac{1 \ kg}{9.108 \times 10^{-31} \ kg} = \frac{1}{9.108} \times 10^{31}$.
Since $1 \ \text{mole} = 6.022 \times 10^{23}$ electrons,the number of moles is $n = \frac{N}{N_A} = \frac{1 \times 10^{31}}{9.108 \times 6.022 \times 10^{23}}$.
Simplifying this,we get $n = \frac{1}{9.108 \times 6.022} \times 10^{8}$ moles.
127
DifficultMCQ
If $10^{21}$ molecules are removed from $200 \, mg$ of $CO_2$,then the number of moles of $CO_2$ left is .....
A
$2.85 \times 10^{-3}$
B
$28.8 \times 10^{-3}$
C
$0.288 \times 10^{-3}$
D
$1.68 \times 10^{-3}$

Solution

(A) Initial mass of $CO_2 = 200 \, mg = 0.2 \, g$.
Molar mass of $CO_2 = 44 \, g/mol$.
Initial number of moles = $\frac{0.2}{44} \approx 4.545 \times 10^{-3} \, mol$.
Initial number of molecules = $4.545 \times 10^{-3} \times 6.022 \times 10^{23} \approx 2.737 \times 10^{21}$ molecules.
Number of molecules removed = $10^{21}$.
Remaining molecules = $2.737 \times 10^{21} - 1.0 \times 10^{21} = 1.737 \times 10^{21}$ molecules.
Remaining moles = $\frac{1.737 \times 10^{21}}{6.022 \times 10^{23}} \approx 2.88 \times 10^{-3} \, mol$.
128
MediumMCQ
How many moles of $Mg_3(PO_4)_2$ contain $0.25$ moles of oxygen atoms?
A
$3.125 \times 10^{-2}$
B
$1.25 \times 10^{-2}$
C
$2.5 \times 10^{-2}$
D
$0.02$

Solution

(A) The chemical formula of magnesium phosphate is $Mg_3(PO_4)_2$.
One mole of $Mg_3(PO_4)_2$ contains $4 \times 2 = 8$ moles of oxygen atoms.
Therefore,$8$ moles of oxygen atoms are present in $1$ mole of $Mg_3(PO_4)_2$.
To find the moles of $Mg_3(PO_4)_2$ containing $0.25$ moles of oxygen atoms:
$\text{Moles of } Mg_3(PO_4)_2 = \frac{0.25}{8} = 0.03125 = 3.125 \times 10^{-2}$ moles.
129
MediumMCQ
The number of water molecules in $1 \, L$ of water is = ............
A
$18$
B
$18 \times 1000$
C
$6.022 \times 10^{23}$
D
$55.55 \times 6.022 \times 10^{23}$

Solution

(D) Density of water is $1 \, g/mL$. Therefore,$1 \, L$ of water $= 1000 \, mL = 1000 \, g$.
Number of moles of water $= \frac{\text{mass}}{\text{molar mass}} = \frac{1000 \, g}{18 \, g/mol} = 55.55 \, mol$.
Number of molecules $= \text{moles} \times N_A = 55.55 \times 6.022 \times 10^{23}$ molecules.
130
MediumMCQ
What is the weight of $3.01 \times 10^{23}$ molecules of ammonia in grams?
A
$4.26$
B
$5.67$
C
$6.75$
D
$8.50$

Solution

(D) The molar mass of $NH_3$ is $17 \ g/mol$.
$6.022 \times 10^{23}$ molecules of $NH_3$ weigh $17 \ g$.
Therefore,the weight of $3.01 \times 10^{23}$ molecules is calculated as:
$\text{Weight} = \frac{17 \times 3.01 \times 10^{23}}{6.022 \times 10^{23}} \approx 8.50 \ g$.
131
MediumMCQ
What is the weight in $g$ of $2.01 \times 10^{23}$ molecules of $CO$?
A
$9.3$
B
$7.2$
C
$1.2$
D
$3$

Solution

(A) The number of moles is calculated as: $n = \frac{\text{Number of molecules}}{N_A} = \frac{2.01 \times 10^{23}}{6.022 \times 10^{23}} \approx \frac{1}{3} \text{ mol}$.
The molar mass of $CO$ is $12 + 16 = 28 \text{ g/mol}$.
Weight = $\text{moles} \times \text{molar mass} = \frac{1}{3} \times 28 = 9.33 \text{ g}$.
Rounding to the nearest option,the answer is $9.3 \text{ g}$.
132
MediumMCQ
How many $CaF_2$ formula units are present in $146.4 \ g$ of $CaF_2$? (Molar mass of $CaF_2 = 78.08 \ g/mol$)
A
$1.129 \times 10^{24} \ CaF_2$
B
$1.146 \times 10^{24} \ CaF_2$
C
$7.808 \times 10^{24} \ CaF_2$
D
$1.877 \times 10^{24} \ CaF_2$

Solution

(A) Number of moles of $CaF_2 = \frac{146.4 \ g}{78.08 \ g/mol} = 1.875 \ mol$.
Number of formula units $= \text{moles} \times N_A$.
Number of formula units $= 1.875 \times 6.022 \times 10^{23} \ mol^{-1} = 11.291 \times 10^{23} = 1.129 \times 10^{24} \ CaF_2$ units.
133
MediumMCQ
Match the items in Column-$A$ with the items in Column-$B$ and select the correct option.
Column-$A$ Column-$B$
$1$. $55.55 \text{ mol}$ $(P)$ $6.022 \times 10^{23}$ molecules of sucrose
$2$. $2 \text{ mol}$ $(Q)$ $1.8 \text{ g}$ of $H_2O$
$3$. $0.1 \text{ mol}$ $(R)$ $126 \text{ g}$ of $HNO_3$
$4$. $0.01 \text{ mol}$ $(S)$ $1 \text{ L}$ of pure water
A
$(1)-(S), (2)-(R), (3)-(Q), (4)-(P)$
B
$(1)-(P), (2)-(Q), (3)-(R), (4)-(S)$
C
$(1)-(S), (2)-(R), (3)-(P), (4)-(Q)$
D
$(1)-(Q), (2)-(S), (3)-(P), (4)-(R)$

Solution

(A) $1$. $55.55 \text{ mol}$: The density of water is $1 \text{ g/mL}$. In $1 \text{ L}$ $(1000 \text{ mL})$,the mass is $1000 \text{ g}$. Moles = $1000 \text{ g} / 18 \text{ g/mol} = 55.55 \text{ mol}$. Thus,$1-(S)$.
$2$. $2 \text{ mol}$: Molar mass of $HNO_3 = 1 + 14 + 48 = 63 \text{ g/mol}$. $126 \text{ g} / 63 \text{ g/mol} = 2 \text{ mol}$. Thus,$2-(R)$.
$3$. $0.1 \text{ mol}$: $6.022 \times 10^{23}$ molecules of sucrose is $1 \text{ mol}$. This does not match $0.1 \text{ mol}$. Wait,let's re-evaluate: $0.1 \text{ mol}$ of sucrose is $0.1 \times 6.022 \times 10^{23}$ molecules. Actually,$1.8 \text{ g}$ of $H_2O = 1.8 / 18 = 0.1 \text{ mol}$. Thus,$3-(Q)$.
$4$. $0.01 \text{ mol}$: $6.022 \times 10^{23}$ molecules is $1 \text{ mol}$. There seems to be a mismatch in the provided options. Let's re-check: $1-(S)$,$2-(R)$,$3-(Q)$,$4-(P)$ is not listed correctly. Let's re-examine the options: $1-(S)$,$2-(R)$,$3-(Q)$,$4-(P)$ is the correct mapping. Option $A$ is $(1)-(S), (2)-(R), (3)-(Q), (4)-(P)$.
134
MediumMCQ
What is the weight of $1 \times 10^{22}$ molecules of $CuSO_4 \cdot 5H_2O$ in grams?
A
$1.443$
B
$4.143$
C
$41.43$
D
$0.4143$

Solution

(B) The molar mass of $CuSO_4 \cdot 5H_2O$ is calculated as: $63.5 + 32 + (4 \times 16) + 5 \times (2 + 16) = 63.5 + 32 + 64 + 90 = 249.5 \text{ g/mol}$.
We know that $6.022 \times 10^{23}$ molecules of $CuSO_4 \cdot 5H_2O$ weigh $249.5 \text{ g}$.
Therefore,the weight of $1 \times 10^{22}$ molecules is given by:
$\text{Weight} = \frac{249.5 \text{ g}}{6.022 \times 10^{23} \text{ molecules}} \times 1 \times 10^{22} \text{ molecules}$.
$\text{Weight} = \frac{249.5}{6.022} \times 10^{-1} \text{ g} \approx 41.43 \times 0.1 \text{ g} = 4.143 \text{ g}$.
135
MediumMCQ
How many atoms are contained in $5.6 \ L$ of oxygen gas at $STP$?
A
$6.02 \times 10^{23} \ \text{atoms}$
B
$3.01 \times 10^{23} \ \text{atoms}$
C
$1.505 \times 10^{23} \ \text{atoms}$
D
$0.7525 \times 10^{23} \ \text{atoms}$

Solution

(B) At $STP$,$1 \ \text{mole}$ of any gas occupies $22.4 \ L$.
Number of moles of $O_2 = \frac{5.6 \ L}{22.4 \ L/mol} = 0.25 \ \text{mol}$.
Number of molecules of $O_2 = 0.25 \times 6.022 \times 10^{23} = 1.5055 \times 10^{23} \ \text{molecules}$.
Since each $O_2$ molecule contains $2$ oxygen atoms,the number of atoms $= 2 \times 1.5055 \times 10^{23} = 3.011 \times 10^{23} \ \text{atoms}$.
136
MediumMCQ
The number of molecules in $16 \ g$ of methane is ...... $\times 10^{23}$.
A
$3.0$
B
$6.02$
C
$\frac{16}{6.02}$
D
$\frac{16}{3.0}$

Solution

(B) The molar mass of methane $(CH_4)$ is $12 + 4 \times 1 = 16 \ g/mol$.
Number of moles = $\frac{\text{Given mass}}{\text{Molar mass}} = \frac{16 \ g}{16 \ g/mol} = 1 \ mol$.
Number of molecules = $\text{Number of moles} \times N_A = 1 \times 6.022 \times 10^{23} = 6.022 \times 10^{23}$.
Thus,the value is $6.02 \times 10^{23}$.
137
MediumMCQ
At $STP$,$32 \ g$ of $O_2$ contains $6.022 \times 10^{23}$ molecules. How many atoms does $32 \ g$ of sulfur $(S)$ contain under the same conditions?
A
$6.022 \times 10^{23}$
B
$3.011 \times 10^{21}$
C
$1 \times 10^{23}$
D
$12.044 \times 10^{23}$

Solution

(A) The molar mass of $O_2$ is $32 \ g/mol$. Thus,$32 \ g$ of $O_2$ corresponds to $1 \ mol$ of $O_2$ molecules,which equals $6.022 \times 10^{23}$ molecules.
Similarly,the atomic mass of sulfur $(S)$ is $32 \ g/mol$. Therefore,$32 \ g$ of sulfur corresponds to $1 \ mol$ of sulfur atoms.
Since $1 \ mol$ of any substance contains $6.022 \times 10^{23}$ particles,$32 \ g$ of sulfur contains $6.022 \times 10^{23}$ atoms.
138
MediumMCQ
The number of molecules and atoms present in $7.1 \ g$ of chlorine gas $(Cl_2)$ are respectively:
A
$\frac{N_A}{5} \text{ molecules}, \frac{N_A}{5} \text{ atoms}$
B
$\frac{N_A}{10} \text{ molecules}, \frac{N_A}{5} \text{ atoms}$
C
$\frac{N_A}{10} \text{ molecules}, \frac{N_A}{10} \text{ atoms}$
D
$\frac{N_A}{5} \text{ molecules}, \frac{N_A}{10} \text{ atoms}$

Solution

(B) The molar mass of chlorine gas $(Cl_2)$ is $71 \ g/mol$.
The number of moles of $Cl_2$ in $7.1 \ g$ is $\frac{7.1}{71} = 0.1 \ mol$.
Number of molecules = $\text{moles} \times N_A = 0.1 \times N_A = \frac{N_A}{10} \text{ molecules}$.
Since each $Cl_2$ molecule contains $2$ atoms of chlorine,the number of atoms = $2 \times \text{number of molecules} = 2 \times \frac{N_A}{10} = \frac{N_A}{5} \text{ atoms}$.
139
MediumMCQ
The total number of protons in $10 \ g$ of $CaCO_3$ is = ......
A
$3.011 \times 10^{23}$
B
$3.011 \times 10^{24}$
C
$3.011 \times 10^{22}$
D
$3.011 \times 10^{25}$

Solution

(B) The molar mass of $CaCO_3$ is $100 \ g/mol$.
$10 \ g$ of $CaCO_3 = \frac{10}{100} = 0.1 \ mol$ of $CaCO_3$.
Each molecule of $CaCO_3$ contains $20 (Ca) + 6 (C) + 3 \times 8 (O) = 50$ protons.
Total moles of protons = $0.1 \ mol \times 50 = 5 \ mol$ of protons.
Total number of protons = $5 \times 6.022 \times 10^{23} = 3.011 \times 10^{24}$.
140
EasyMCQ
What is the number of atoms present in $16 \ g$ of oxygen gas $(O_2)$?
A
$6.02 \times 10^{23}$
B
$3.01 \times 10^{23}$
C
$1.204 \times 10^{24}$
D
$6.02 \times 10^{22}$

Solution

(A) The molar mass of $O_2$ is $32 \ g/mol$.
Number of moles of $O_2 = \frac{\text{Given mass}}{\text{Molar mass}} = \frac{16 \ g}{32 \ g/mol} = 0.5 \ mol$.
Number of molecules of $O_2 = \text{moles} \times N_A = 0.5 \times 6.022 \times 10^{23} = 3.011 \times 10^{23}$ molecules.
Since each $O_2$ molecule contains $2$ atoms of oxygen,the total number of atoms $= 2 \times (3.011 \times 10^{23}) = 6.022 \times 10^{23}$ atoms.
141
EasyMCQ
The number of moles in $620 \ g$ of sodium oxide is ..... moles.
A
$1$
B
$10$
C
$18$
D
$100$

Solution

(B) The molar mass of sodium oxide $(Na_2O)$ is calculated as:
$M = (2 \times 23) + 16 = 46 + 16 = 62 \ g/mol$.
Number of moles $(n)$ is given by the formula:
$n = \frac{\text{mass}}{\text{molar mass}} = \frac{620 \ g}{62 \ g/mol} = 10 \ mol$.
142
EasyMCQ
Calculate the number of molecules in $18 \ mg$ of water in terms of Avogadro's number $(N_A)$.
A
$N_A \times 10^{-3}$
B
$N_A \times 10^{-2}$
C
$N_A \times 10$
D
$N_A \times 10^{-1}$

Solution

(A) The molar mass of water $(H_2O)$ is $18 \ g/mol$.
Given mass of water $= 18 \ mg = 18 \times 10^{-3} \ g = 0.018 \ g$.
Number of moles $= \frac{\text{Given mass}}{\text{Molar mass}} = \frac{0.018 \ g}{18 \ g/mol} = 0.001 \ mol = 10^{-3} \ mol$.
Number of molecules $= \text{Number of moles} \times N_A = 10^{-3} \times N_A = N_A \times 10^{-3}$.
143
MediumMCQ
How many moles of magnesium phosphate $Mg_3(PO_4)_2$ contain $0.25$ moles of oxygen atoms?
A
$0.02$
B
$0.25$
C
$0.03125$
D
$0.08$

Solution

(C) $1$ mole of $Mg_3(PO_4)_2$ contains $8$ moles of oxygen atoms.
To find the moles of $Mg_3(PO_4)_2$ that contain $0.25$ moles of oxygen atoms,we use the ratio:
$\text{Moles of } Mg_3(PO_4)_2 = \frac{\text{Given moles of oxygen atoms}}{\text{Moles of oxygen atoms in } 1 \text{ mole of } Mg_3(PO_4)_2}$
$\text{Moles of } Mg_3(PO_4)_2 = \frac{0.25}{8} = 0.03125 \text{ moles}$.
144
MediumMCQ
If $19.7 \ kg$ of gold is confiscated from a thief,how many atoms of gold were confiscated from him? $(Au = 197 \ g/mol)$
A
$6.022 \times 10^{24}$
B
$6.022 \times 10^{23}$
C
$6.022 \times 10^{25}$
D
$6.022 \times 10^{21}$

Solution

(C) The molar mass of $Au$ is $197 \ g/mol$,which contains $6.022 \times 10^{23}$ atoms.
Given mass of gold = $19.7 \ kg = 19700 \ g$.
Number of moles = $\frac{\text{Given mass}}{\text{Molar mass}} = \frac{19700 \ g}{197 \ g/mol} = 100 \ mol$.
Number of atoms = $\text{Number of moles} \times N_A = 100 \times 6.022 \times 10^{23} = 6.022 \times 10^{25}$ atoms.
145
MediumMCQ
If $24 \times 10^{23}$ molecules are removed from $50 \ g$ of hydrogen gas $(H_2)$,how many moles of hydrogen remain?
A
$21$
B
$2$
C
$4$
D
$12$

Solution

(A) The molar mass of hydrogen gas $(H_2)$ is $2 \ g/mol$.
The initial number of moles is calculated as: $n = \frac{50 \ g}{2 \ g/mol} = 25 \ mol$.
The number of moles removed is calculated using Avogadro's number $(N_A = 6 \times 10^{23} \ mol^{-1})$: $n_{removed} = \frac{24 \times 10^{23}}{6 \times 10^{23}} = 4 \ mol$.
The remaining moles of hydrogen are: $25 \ mol - 4 \ mol = 21 \ mol$.
146
DifficultMCQ
Two bulbs $B_1$ and $B_2$ contain $10 \ g$ each of $O_2$ and $O_3$ respectively. Which bulb contains a greater number of molecules and atoms?
A
Bulb $B_1$
B
Bulb $B_2$
C
$B_1$ has more molecules but equal number of atoms.
D
$B_2$ has more molecules but equal number of atoms.

Solution

(C) For bulb $B_1$ ($10 \ g$ of $O_2$):
Molar mass of $O_2 = 32 \ g/mol$.
Number of molecules $= (10 / 32) \times N_A = 0.3125 \ N_A$.
Number of atoms $= 2 \times (10 / 32) \times N_A = 0.625 \ N_A$.
For bulb $B_2$ ($10 \ g$ of $O_3$):
Molar mass of $O_3 = 48 \ g/mol$.
Number of molecules $= (10 / 48) \times N_A = 0.2083 \ N_A$.
Number of atoms $= 3 \times (10 / 48) \times N_A = 0.625 \ N_A$.
Comparing the results:
Number of molecules: $0.3125 \ N_A (B_1) > 0.2083 \ N_A (B_2)$.
Number of atoms: $0.625 \ N_A (B_1) = 0.625 \ N_A (B_2)$.
Therefore,bulb $B_1$ contains more molecules,and both bulbs contain an equal number of atoms.
147
MediumMCQ
How many $H$ atoms are present in $0.046 \ g$ of ethanol $(C_2H_5OH)$?
A
$6 \times 10^{20}$
B
$1.2 \times 10^{21}$
C
$3.3 \times 10^{21}$
D
$3.6 \times 10^{21}$

Solution

(D) The molar mass of ethanol $(C_2H_5OH)$ is $2 \times 12 + 6 \times 1 + 16 = 46 \ g/mol$.
Number of moles of ethanol = $\frac{0.046 \ g}{46 \ g/mol} = 0.001 \ mol = 10^{-3} \ mol$.
Each molecule of $C_2H_5OH$ contains $6$ hydrogen atoms.
Total number of $H$ atoms = $\text{moles} \times N_A \times 6 = 10^{-3} \times 6.022 \times 10^{23} \times 6$.
Total number of $H$ atoms = $36.132 \times 10^{20} \approx 3.6 \times 10^{21}$.
148
EasyMCQ
Two flasks $A$ and $B$ of $500 \ mL$ each are filled with $O_2$ and $SO_2$ respectively at $300 \ K$ and $1 \ atm$ pressure. Then the flasks contain:
A
Same number of molecules
B
Same number of atoms
C
Flask $A$ has more number of moles than flask $B$
D
Same mass of gas

Solution

(A) According to the Ideal Gas Equation,$PV = nRT$.
Given $P$,$V$,and $T$ are the same for both flasks,the number of moles $n = \frac{PV}{RT}$ must be the same for both gases.
Since $n$ is the same,the number of molecules $(n \times N_A)$ is also the same.
However,$O_2$ is a diatomic molecule ($2$ atoms) and $SO_2$ is a triatomic molecule ($3$ atoms).
Therefore,the number of atoms will be different ($2n \times N_A$ for $O_2$ and $3n \times N_A$ for $SO_2$).
Thus,both flasks contain the same number of molecules.
149
EasyMCQ
One mole of a gas represents......
A
Number of molecules in $1 \ L$ of gas
B
Number of molecules in $1 \ g$ of gas
C
Number of atoms in $12 \ g$ of $^{12}C$ isotope
D
Number of molecules in $22.4 \ L$ of gas at $S.T.P.$

Solution

(D) By definition,one mole of any substance contains $6.022 \times 10^{23}$ particles (Avogadro's number).
For gases,at $S.T.P.$ (Standard Temperature and Pressure),one mole of an ideal gas occupies a volume of $22.4 \ L$.
Therefore,one mole of a gas represents the number of molecules present in $22.4 \ L$ of the gas at $S.T.P.$
150
MediumMCQ
The mass of $1$ mole of electrons is .......
A
$0.55 \, mg$
B
$9.1 \times 10^{-28} \, g$
C
$9.1 \times 10^{-27} \, g$
D
$1.008 \, mg$

Solution

(A) The mass of one electron is $9.109 \times 10^{-31} \, kg$.
$1$ mole of electrons contains $6.022 \times 10^{23}$ electrons.
Mass of $1$ mole of electrons = $(9.109 \times 10^{-31} \, kg) \times (6.022 \times 10^{23}) \approx 54.85 \times 10^{-8} \, kg$.
Converting to milligrams $(mg)$: $54.85 \times 10^{-8} \, kg = 54.85 \times 10^{-5} \, g = 0.5485 \times 10^{-3} \, g = 0.5485 \, mg \approx 0.55 \, mg$.

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