TS EAMCET 2008 Chemistry Question Paper with Answer and Solution

(B) Since the axes are rotated through an angle $\theta = 45^{\circ}$,we replace $(x, y)$ by $(x \cos 45^{\circ} - y \sin 45^{\circ}, x \sin 45^{\circ} + y \cos 45^{\circ})$,which is $(\frac{x-y}{\sqrt{2}}, \frac{x+y}{\sqrt{2}})$. Substituting these into the equation $3x^2 + 3y^2 + 2xy = 2$:
$3(\frac{x-y}{\sqrt{2}})^2 + 3(\frac{x+y}{\sqrt{2}})^2 + 2(\frac{x-y}{\sqrt{2}})(\frac{x+y}{\sqrt{2}}) = 2$
$\frac{3}{2}(x^2 + y^2 - 2xy) + \frac{3}{2}(x^2 + y^2 + 2xy) + \frac{2}{2}(x^2 - y^2) = 2$
$\frac{3}{2}(2x^2 + 2y^2) + (x^2 - y^2) = 2$
$3x^2 + 3y^2 + x^2 - y^2 = 2$
$4x^2 + 2y^2 = 2$
Dividing by $2$,we get $2x^2 + y^2 = 1$.

(B) Since the lines $2x - 3y + k = 0$,$3x - 4y - 13 = 0$,and $8x - 11y - 33 = 0$ are concurrent,the determinant of their coefficients must be zero:
$\begin{vmatrix} 2 & -3 & k \\ 3 & -4 & -13 \\ 8 & -11 & -33 \end{vmatrix} = 0$
Expanding along the first row:
$2((-4)(-33) - (-13)(-11)) - (-3)((3)(-33) - (-13)(8)) + k((3)(-11) - (-4)(8)) = 0$
$2(132 - 143) + 3(-99 + 104) + k(-33 + 32) = 0$
$2(-11) + 3(5) + k(-1) = 0$
$-22 + 15 - k = 0$
$-7 - k = 0$
$k = -7$

(A) To make the given curves $x^2+y^2=4$ and $x+y=a$ homogeneous,we write the equation of the pair of lines passing through the origin as:
$x^2+y^2-4\left(\frac{x+y}{a}\right)^2=0$
Multiplying by $a^2$,we get:
$a^2(x^2+y^2)-4(x^2+y^2+2xy)=0$
$(a^2-4)x^2-8xy+(a^2-4)y^2=0$
Since the pair of lines is perpendicular,the sum of the coefficients of $x^2$ and $y^2$ must be zero:
$(a^2-4)+(a^2-4)=0$
$2(a^2-4)=0$
$a^2=4$
$a=\pm 2$
Hence,the required set of $a$ is $\{-2, 2\}$.

(C) The general equation of a second-degree curve is $ax^2 + 2hxy + by^2 + 2gx + 2fy + c = 0$.
Comparing the given equation $\lambda x^2 - 10xy + 12y^2 + 5x - 16y - 3 = 0$ with the general form,we get:
$a = \lambda, h = -5, b = 12, g = \frac{5}{2}, f = -8, c = -3$.
The condition for the equation to represent a pair of straight lines is $\Delta = abc + 2fgh - af^2 - bg^2 - ch^2 = 0$.
Substituting the values:
$\lambda(12)(-3) + 2(-8)(\frac{5}{2})(-5) - \lambda(-8)^2 - 12(\frac{5}{2})^2 - (-3)(-5)^2 = 0$.
$-36\lambda + 200 - 64\lambda - 75 + 75 = 0$.
$-100\lambda + 200 = 0$.
$100\lambda = 200$.
$\lambda = 2$.

(C) Since the lines $2x - 3y = 5$ and $3x - 4y = 7$ are diameters of the circle,their point of intersection is the center $(h, k)$ of the circle.
Solving the system of equations:
$2x - 3y = 5$ $(i)$
$3x - 4y = 7$ $(ii)$
Multiplying $(i)$ by $3$ and $(ii)$ by $2$:
$6x - 9y = 15$
$6x - 8y = 14$
Subtracting the equations: $-y = 1 \Rightarrow y = -1$.
Substituting $y = -1$ into $(i)$: $2x - 3(-1) = 5$ $\Rightarrow 2x + 3 = 5$ $\Rightarrow 2x = 2$ $\Rightarrow x = 1$.
Thus,the center is $(1, -1)$ and the radius $r = 7$.
The equation of the circle is $(x - h)^2 + (y - k)^2 = r^2$.
$(x - 1)^2 + (y + 1)^2 = 7^2$
$x^2 - 2x + 1 + y^2 + 2y + 1 = 49$
$x^2 + y^2 - 2x + 2y + 2 = 49$
$x^2 + y^2 - 2x + 2y - 47 = 0$.

(A) The angle $\theta$ between the two tangents from a point $P(x_1, y_1)$ to a circle $S=0$ is given by $\tan\left(\frac{\theta}{2}\right) = \frac{r}{\sqrt{S_1}}$,where $r$ is the radius and $S_1$ is the power of the point.
Given the circle equation $x^2+y^2-5x+4y-2=0$,the center is $(\frac{5}{2}, -2)$ and the radius $r = \sqrt{(\frac{5}{2})^2 + (-2)^2 - (-2)} = \sqrt{\frac{25}{4} + 4 + 2} = \sqrt{\frac{49}{4}} = \frac{7}{2}$.
The power of the point $(-1, 0)$ is $S_1 = (-1)^2 + (0)^2 - 5(-1) + 4(0) - 2 = 1 + 5 - 2 = 4$.
Thus,$\tan\left(\frac{\theta}{2}\right) = \frac{7/2}{\sqrt{4}} = \frac{7/2}{2} = \frac{7}{4}$.
Therefore,$\frac{\theta}{2} = \tan^{-1}\left(\frac{7}{4}\right)$,which implies $\theta = 2 \tan^{-1}\left(\frac{7}{4}\right)$.

(C) The equation of the polar of the point $(x_1, y_1) = (1, 2)$ with respect to the circle $x^2 + y^2 - 4x - 6y + 9 = 0$ is given by $T = 0$:
$x(1) + y(2) - 2(x + 1) - 3(y + 2) + 9 = 0$
$x + 2y - 2x - 2 - 3y - 6 + 9 = 0$
$-x - y + 1 = 0 \Rightarrow x + y - 1 = 0$.
The inverse point $(\alpha, \beta)$ is the foot of the perpendicular from the point $(1, 2)$ to the line $x + y - 1 = 0$.
Using the formula $\frac{\alpha - x_1}{a} = \frac{\beta - y_1}{b} = -\frac{ax_1 + by_1 + c}{a^2 + b^2}$:
$\frac{\alpha - 1}{1} = \frac{\beta - 2}{1} = -\frac{1(1) + 1(2) - 1}{1^2 + 1^2}$
$\frac{\alpha - 1}{1} = \frac{\beta - 2}{1} = -\frac{2}{2} = -1$.
Thus,$\alpha - 1 = -1 \Rightarrow \alpha = 0$ and $\beta - 2 = -1 \Rightarrow \beta = 1$.
The inverse point is $(0, 1)$.

(B) The given polar equation of the circle is $r^2-8r(\sqrt{3}\cos\theta+\sin\theta)+15=0$.
Using the relations $x=r\cos\theta$ and $y=r\sin\theta$,and $r^2=x^2+y^2$,we convert this to Cartesian form:
$x^2+y^2-8(\sqrt{3}x+y)+15=0$
$x^2+y^2-8\sqrt{3}x-8y+15=0$
Comparing this with the standard form $x^2+y^2+2gx+2fy+c=0$,we get $g=-4\sqrt{3}$,$f=-4$,and $c=15$.
The radius $R$ is given by $\sqrt{g^2+f^2-c}$:
$R = \sqrt{(-4\sqrt{3})^2+(-4)^2-15}$
$R = \sqrt{48+16-15}$
$R = \sqrt{49} = 7$.

(D) The condition for two lines $l_1x + m_1y + n_1 = 0$ and $l_2x + m_2y + n_2 = 0$ to be conjugate with respect to the parabola $y^2 = 4ax$ is given by $l_1n_2 + l_2n_1 = 2am_1m_2$.
Given the lines $2x + 3y + 12 = 0$ and $x - y + 4\lambda = 0$ and the parabola $y^2 = 8x$,we have $4a = 8$,so $a = 2$.
Here,$l_1 = 2, m_1 = 3, n_1 = 12$ and $l_2 = 1, m_2 = -1, n_2 = 4\lambda$.
Substituting these values into the condition:
$2(4\lambda) + 1(12) = 2(2)(3)(-1)$
$8\lambda + 12 = -12$
$8\lambda = -24$
$\lambda = -3$.

(C) Given,$(1+x+x^2+x^3)^5 = \sum_{k=0}^{15} a_k x^k$.
We can factor the expression as $(1+x)(1+x^2)^5 = (1+x)^5(1+x^2)^5$.
Alternatively,$(1+x+x^2+x^3)^5 = [(1+x)(1+x^2)]^5 = (1+x)^5(1+x^2)^5$.
Let $f(x) = (1+x)^5(1+x^2)^5 = \sum_{k=0}^{15} a_k x^k$.
We want to find $\sum_{k=0}^7 a_{2k} = a_0 + a_2 + a_4 + a_6 + a_8 + a_{10} + a_{12} + a_{14}$.
Note that $f(1) = \sum_{k=0}^{15} a_k = (1+1)^5(1+1^2)^5 = 2^5 \times 2^5 = 2^{10} = 1024$.
And $f(-1) = \sum_{k=0}^{15} a_k (-1)^k = (1-1)^5(1+(-1)^2)^5 = 0^5 \times 2^5 = 0$.
Thus,$f(1) + f(-1) = 2(a_0 + a_2 + a_4 + \dots + a_{14}) = 1024 + 0 = 1024$.
Therefore,$a_0 + a_2 + a_4 + a_6 + a_8 + a_{10} + a_{12} + a_{14} = \frac{1024}{2} = 512$.

(B) Given the series $\alpha = \frac{5}{2! 3} + \frac{5 \cdot 7}{3! 3^2} + \frac{5 \cdot 7 \cdot 9}{4! 3^3} + \ldots$.
We use the binomial expansion $(1-x)^{-n} = 1 + nx + \frac{n(n+1)}{2!}x^2 + \frac{n(n+1)(n+2)}{3!}x^3 + \ldots$.
Let $n = -5/2$ and $x = -1/3$. Then $(1 - (-1/3))^{-5/2} = (4/3)^{-5/2} = (3/4)^{5/2} = \frac{3^{5/2}}{32}$.
Alternatively,consider $(1-x)^{-n} = 1 + nx + \frac{n(n+1)}{2!}x^2 + \ldots$.
Comparing terms,we find $\alpha = (1 - 1/3)^{-5/2} - 1 - (5/2)(1/3) = (2/3)^{-5/2} - 1 - 5/6 = (3/2)^{5/2} - 11/6$.
Actually,the series is $\alpha = \sum_{k=2}^{\infty} \frac{(2k+1)!!}{k! 3^{k-1} 2^{k-1}}$.
Using the expansion $(1-x)^{-n} = 1 + nx + \frac{n(n+1)}{2!}x^2 + \dots$,for $n=5/2$ and $x=1/3$,we get $(1-1/3)^{-5/2} = 1 + (5/2)(1/3) + \frac{(5/2)(7/2)}{2!}(1/3)^2 + \dots = 1 + 5/6 + \frac{35}{8 \cdot 9} + \dots = 1 + 5/6 + \frac{35}{72} + \dots$.
The given series is $\alpha = (1-1/3)^{-5/2} - 1 - 5/6 = (2/3)^{-5/2} - 11/6 = (3/2)^{5/2} - 11/6$.
Evaluating $\alpha^2 + 4\alpha = (\alpha+2)^2 - 4$.
With $\alpha = 3^{3/2} - 2$,we have $\alpha + 2 = 3^{3/2} = 3\sqrt{3}$.
Then $(\alpha+2)^2 - 4 = (3\sqrt{3})^2 - 4 = 27 - 4 = 23$.

(B) Given that,eccentricity $e = \frac{1}{2}$ and the equation of the directrix is $\frac{a}{e} = 4$.
Since $e = \frac{1}{2}$,we have $\frac{a}{1/2} = 4$,which implies $a = 2$.
Using the relation $b^2 = a^2(1 - e^2)$,we get:
$b^2 = 4(1 - (\frac{1}{2})^2) = 4(1 - \frac{1}{4}) = 4(\frac{3}{4}) = 3$.
Therefore,the equation of the ellipse is $\frac{x^2}{a^2} + \frac{y^2}{b^2} = 1$.
Substituting the values,we get $\frac{x^2}{4} + \frac{y^2}{3} = 1$.
Multiplying by $12$,we get $3x^2 + 4y^2 = 12$.

(C) Given the equation of the hyperbola is $x^2 - 3y^2 - 4x - 6y - 11 = 0$.
Rearranging the terms,we get $(x^2 - 4x) - 3(y^2 + 2y) = 11$.
Completing the square,we have $(x^2 - 4x + 4) - 3(y^2 + 2y + 1) = 11 + 4 - 3$.
This simplifies to $(x - 2)^2 - 3(y + 1)^2 = 12$.
Dividing by $12$,we get $\frac{(x - 2)^2}{12} - \frac{(y + 1)^2}{4} = 1$.
Here,$a^2 = 12$ and $b^2 = 4$.
The eccentricity $e$ is given by $e = \sqrt{1 + \frac{b^2}{a^2}} = \sqrt{1 + \frac{4}{12}} = \sqrt{1 + \frac{1}{3}} = \sqrt{\frac{4}{3}} = \frac{2}{\sqrt{3}}$.
The distance between the foci is $2ae = 2 \times \sqrt{12} \times \frac{2}{\sqrt{3}} = 2 \times 2\sqrt{3} \times \frac{2}{\sqrt{3}} = 8$.

(C) Given that $f(2)=4$ and $f^{\prime}(2)=1$.
We need to evaluate the limit:
$L = \lim _{x \rightarrow 2} \frac{x f(2)-2 f(x)}{x-2}$
Adding and subtracting $2f(2)$ in the numerator:
$L = \lim _{x \rightarrow 2} \frac{x f(2)-2 f(2)+2 f(2)-2 f(x)}{x-2}$
$L = \lim _{x \rightarrow 2} \frac{f(2)(x-2) - 2(f(x)-f(2))}{x-2}$
$L = \lim _{x \rightarrow 2} f(2) - 2 \lim _{x \rightarrow 2} \frac{f(x)-f(2)}{x-2}$
$L = f(2) - 2 f^{\prime}(2)$
Substituting the given values:
$L = 4 - 2(1) = 2$.

(C) Given that $f(x) = [x-3] + |x-4|$.
To find the left-hand limit as $x \rightarrow 3^{-}$,we substitute $x = 3 - h$ where $h > 0$ and $h \rightarrow 0$.
$\lim_{x \rightarrow 3^{-}} f(x) = \lim_{h \rightarrow 0} ([3 - h - 3] + |3 - h - 4|)$
$= \lim_{h \rightarrow 0} ([-h] + |-1 - h|)$
Since $h$ is a very small positive number,$-h$ is a small negative number,so $[-h] = -1$.
Also,$|-1 - h| = |-(1 + h)| = 1 + h$.
Thus,$\lim_{h \rightarrow 0} (-1 + 1 + h) = -1 + 1 + 0 = 0$.

(A) We need to evaluate the limit: $\lim _{x \rightarrow 0} \frac{(1-e^x) \sin x}{x^2+x^3}$
Factor out $x^2$ from the denominator: $\lim _{x \rightarrow 0} \frac{(1-e^x) \sin x}{x^2(1+x)}$
Rewrite the expression as: $\lim _{x}$ ${\rightarrow 0} \left( \frac{1-e^x}{x} \right) \times \left( \frac{\sin x}{x} \right) \times \left( \frac{1}{1+x} \right)$
Using standard limits $\lim _{x \rightarrow 0} \frac{e^x-1}{x} = 1$ and $\lim _{x \rightarrow 0} \frac{\sin x}{x} = 1$:
The expression becomes: $(-1) \times (1) \times \left( \frac{1}{1+0} \right) = -1 \times 1 \times 1 = -1$

(C) Given the equation: $\frac{1}{a+c} + \frac{1}{b+c} = \frac{3}{a+b+c}$.
Taking $LCM$ on the left side: $\frac{(b+c) + (a+c)}{(a+c)(b+c)} = \frac{3}{a+b+c}$.
$\frac{a+b+2c}{ab+ac+bc+c^2} = \frac{3}{a+b+c}$.
Cross-multiplying: $(a+b+2c)(a+b+c) = 3(ab+ac+bc+c^2)$.
$(a+b)^2 + c(a+b) + 2c(a+b) + 2c^2 = 3ab + 3ac + 3bc + 3c^2$.
$a^2 + b^2 + 2ab + 3ac + 3bc + 2c^2 = 3ab + 3ac + 3bc + 3c^2$.
$a^2 + b^2 - ab = c^2$.
Using the Law of Cosines: $c^2 = a^2 + b^2 - 2ab \cos C$.
Comparing the two equations: $a^2 + b^2 - ab = a^2 + b^2 - 2ab \cos C$.
$-ab = -2ab \cos C$.
$\cos C = \frac{1}{2}$.
Therefore,$\angle C = 60^{\circ}$.

(B) Given that,$\frac{1}{b+c} + \frac{1}{c+a} = \frac{3}{a+b+c}$.
Taking common denominators on the left side:
$\frac{(c+a) + (b+c)}{(b+c)(c+a)} = \frac{3}{a+b+c}$
$\frac{a+b+2c}{bc + ab + c^2 + ac} = \frac{3}{a+b+c}$
Cross-multiplying:
$(a+b+2c)(a+b+c) = 3(bc + ab + c^2 + ac)$
$(a+b)^2 + c(a+b) + 2c(a+b) + 2c^2 = 3bc + 3ab + 3c^2 + 3ac$
$a^2 + b^2 + 2ab + 3ac + 3bc + 2c^2 = 3bc + 3ab + 3c^2 + 3ac$
Subtracting $3ac + 3bc$ from both sides:
$a^2 + b^2 + 2ab + 2c^2 = 3ab + 3c^2$
$a^2 + b^2 - c^2 = ab$
Using the Law of Cosines,$\cos C = \frac{a^2 + b^2 - c^2}{2ab}$:
$\cos C = \frac{ab}{2ab} = \frac{1}{2}$
Since $\cos C = \frac{1}{2}$,we have $C = 60^{\circ}$.

(B) For statement $(I)$:
$b \cos^2 \frac{C}{2} + c \cos^2 \frac{B}{2} = b \cdot \frac{s(s-c)}{ab} + c \cdot \frac{s(s-b)}{ac}$
$= \frac{s}{a}(s-c) + \frac{s}{a}(s-b) = \frac{s}{a}(2s - b - c)$
Since $2s = a+b+c$,we have $2s - (b+c) = a$.
So,$\frac{s}{a} \cdot a = s$. Thus,statement $(I)$ is true.
For statement $(II)$:
Given $\cot \frac{A}{2} = \frac{b+c}{a}$. Using sine rule,$\frac{b+c}{a} = \frac{\sin B + \sin C}{\sin A}$.
$\frac{\cos(A/2)}{\sin(A/2)} = \frac{2 \sin((B+C)/2) \cos((B-C)/2)}{2 \sin(A/2) \cos(A/2)}$.
Since $\sin((B+C)/2) = \cos(A/2)$,we get $\cos(A/2) = \cos((B-C)/2)$.
This implies $A = B-C$ or $A = C-B$.
If $A = B-C$,then $A+C = B$. Since $A+B+C = 180^{\circ}$,$2B = 180^{\circ} \Rightarrow B = 90^{\circ}$.
The statement in the question is $\cot \frac{A}{2} = \frac{b+c}{2}$,which is dimensionally incorrect and does not lead to $B=90^{\circ}$ as written. Thus,statement $(II)$ is false.

(D) Given that $r_1 = 2r_2 = 3r_3$.
Since $r_1 = \frac{\Delta}{s-a}$,$r_2 = \frac{\Delta}{s-b}$,and $r_3 = \frac{\Delta}{s-c}$,we have:
$\frac{\Delta}{s-a} = \frac{2\Delta}{s-b} = \frac{3\Delta}{s-c} = \frac{\Delta}{k}$
This implies $s-a = k$,$s-b = \frac{k}{2}$,and $s-c = \frac{k}{3}$.
Adding these: $3s - (a+b+c) = k(1 + \frac{1}{2} + \frac{1}{3}) = k(\frac{6+3+2}{6}) = \frac{11k}{6}$.
Since $3s - (a+b+c) = 3s - 2s = s$,we have $s = \frac{11k}{6}$.
Now,$a = s - k = \frac{11k}{6} - k = \frac{5k}{6}$,$b = s - \frac{k}{2} = \frac{11k}{6} - \frac{3k}{6} = \frac{8k}{6}$,and $c = s - \frac{k}{3} = \frac{11k}{6} - \frac{2k}{6} = \frac{9k}{6}$.
Thus,$a:b:c = 5:8:9$.
Then $\frac{a}{b} + \frac{b}{c} + \frac{c}{a} = \frac{5}{8} + \frac{8}{9} + \frac{9}{5} = \frac{225 + 320 + 648}{360} = \frac{1193}{360}$.
Wait,re-evaluating the original problem statement: If $r_1 = 2r_2 = 3r_3$,then $s-a = k, s-b = k/2, s-c = k/3$.
$a = s-k, b = s-k/2, c = s-k/3$.
$s = (s-k) + (s-k/2) + (s-k/3) = 3s - 11k/6$ $\Rightarrow 2s = 11k/6$ $\Rightarrow s = 11k/12$.
$a = 11k/12 - k = -k/12$ (Impossible).
Correction: The condition $r_1 = 2r_2 = 3r_3$ implies $\frac{1}{s-a} = \frac{2}{s-b} = \frac{3}{s-c} = \lambda$.
$s-a = 1/\lambda, s-b = 1/(2\lambda), s-c = 1/(3\lambda)$.
$s = (s-a) + (s-b) + (s-c) = 3s - (a+b+c) = 3s - 2s = s$.
$s = \lambda^{-1}(1 + 1/2 + 1/3) = \lambda^{-1}(11/6) \Rightarrow \lambda^{-1} = 6s/11$.
$s-a = 6s/11 \Rightarrow a = 5s/11$.
$s-b = 3s/11 \Rightarrow b = 8s/11$.
$s-c = 2s/11 \Rightarrow c = 9s/11$.
Ratio $a:b:c = 5:8:9$.
$\frac{a}{b} + \frac{b}{c} + \frac{c}{a} = \frac{5}{8} + \frac{8}{9} + \frac{9}{5} = \frac{225 + 320 + 648}{360} = \frac{1193}{360}$.
Given the provided options,the original logic in the prompt assumed $s-a=k, s-b=k/2, s-c=k/3$ was incorrect. The provided solution in the prompt used $s-a=k, s-b=2k, s-c=3k$. Let's follow that: $s-a=k, s-b=2k, s-c=3k \Rightarrow s=6k$. $a=5k, b=4k, c=3k$. $\frac{5}{4} + \frac{4}{3} + \frac{3}{5} = \frac{75+80+36}{60} = \frac{191}{60}$.

(B) Given that,$A=\begin{bmatrix} 1 & -2 \\ 4 & 5 \end{bmatrix}$ and $f(t)=t^2-3t+7$.
First,calculate $A^2$:
$A^2 = \begin{bmatrix} 1 & -2 \\ 4 & 5 \end{bmatrix} \begin{bmatrix} 1 & -2 \\ 4 & 5 \end{bmatrix} = \begin{bmatrix} 1(1)+(-2)(4) & 1(-2)+(-2)(5) \\ 4(1)+5(4) & 4(-2)+5(5) \end{bmatrix} = \begin{bmatrix} -7 & -12 \\ 24 & 17 \end{bmatrix}$.
Now,calculate $f(A) = A^2 - 3A + 7I$:
$f(A) = \begin{bmatrix} -7 & -12 \\ 24 & 17 \end{bmatrix} - 3 \begin{bmatrix} 1 & -2 \\ 4 & 5 \end{bmatrix} + 7 \begin{bmatrix} 1 & 0 \\ 0 & 1 \end{bmatrix}$
$f(A) = \begin{bmatrix} -7 & -12 \\ 24 & 17 \end{bmatrix} - \begin{bmatrix} 3 & -6 \\ 12 & 15 \end{bmatrix} + \begin{bmatrix} 7 & 0 \\ 0 & 7 \end{bmatrix}$
$f(A) = \begin{bmatrix} -7-3+7 & -12-(-6)+0 \\ 24-12+0 & 17-15+7 \end{bmatrix} = \begin{bmatrix} -3 & -6 \\ 12 & 9 \end{bmatrix}$.
Finally,add the given matrix:
$f(A) + \begin{bmatrix} 3 & 6 \\ -12 & -9 \end{bmatrix} = \begin{bmatrix} -3 & -6 \\ 12 & 9 \end{bmatrix} + \begin{bmatrix} 3 & 6 \\ -12 & -9 \end{bmatrix} = \begin{bmatrix} 0 & 0 \\ 0 & 0 \end{bmatrix}$.

(D) Let $A = \left[\begin{array}{ccc}7 & -3 & -3 \\ -1 & 1 & 0 \\ -1 & 0 & 1\end{array}\right]$.
First,calculate the determinant $|A|$:
$|A| = 7(1 - 0) - (-3)(-1 - 0) + (-3)(0 - (-1)) = 7(1) + 3(-1) - 3(1) = 7 - 3 - 3 = 1$.
Since $|A| \neq 0$,the inverse exists.
Next,find the cofactors $C_{ij}$ of matrix $A$:
$C_{11} = +\begin{vmatrix} 1 & 0 \\ 0 & 1 \end{vmatrix} = 1, C_{12} = -\begin{vmatrix} -1 & 0 \\ -1 & 1 \end{vmatrix} = 1, C_{13} = +\begin{vmatrix} -1 & 1 \\ -1 & 0 \end{vmatrix} = 1$.
$C_{21} = -\begin{vmatrix} -3 & -3 \\ 0 & 1 \end{vmatrix} = 3, C_{22} = +\begin{vmatrix} 7 & -3 \\ -1 & 1 \end{vmatrix} = 4, C_{23} = -\begin{vmatrix} 7 & -3 \\ -1 & 0 \end{vmatrix} = 3$.
$C_{31} = +\begin{vmatrix} -3 & -3 \\ 1 & 0 \end{vmatrix} = 3, C_{32} = -\begin{vmatrix} 7 & -3 \\ -1 & 0 \end{vmatrix} = 3, C_{33} = +\begin{vmatrix} 7 & -3 \\ -1 & 1 \end{vmatrix} = 4$.
The adjoint matrix $\operatorname{adj}(A)$ is the transpose of the cofactor matrix:
$\operatorname{adj}(A) = \left[\begin{array}{ccc} 1 & 1 & 1 \\ 3 & 4 & 3 \\ 3 & 3 & 4 \end{array}\right]^T = \left[\begin{array}{ccc} 1 & 3 & 3 \\ 1 & 4 & 3 \\ 1 & 3 & 4 \end{array}\right]$.
Finally,$A^{-1} = \frac{1}{|A|} \operatorname{adj}(A) = \frac{1}{1} \left[\begin{array}{ccc} 1 & 3 & 3 \\ 1 & 4 & 3 \\ 1 & 3 & 4 \end{array}\right] = \left[\begin{array}{ccc} 1 & 3 & 3 \\ 1 & 4 & 3 \\ 1 & 3 & 4 \end{array}\right]$.

(D) Let $\Delta = \left|\begin{array}{ccc}a-b-c & 2a & 2a \\ 2b & b-c-a & 2b \\ 2c & 2c & c-a-b\end{array}\right|$.
Applying $R_1 \rightarrow R_1 + R_2 + R_3$,we get:
$\Delta = \left|\begin{array}{ccc}a+b+c & a+b+c & a+b+c \\ 2b & b-c-a & 2b \\ 2c & 2c & c-a-b\end{array}\right|$.
Taking $(a+b+c)$ common from $R_1$:
$\Delta = (a+b+c) \left|\begin{array}{ccc}1 & 1 & 1 \\ 2b & b-c-a & 2b \\ 2c & 2c & c-a-b\end{array}\right|$.
Applying $C_2 \rightarrow C_2 - C_1$ and $C_3 \rightarrow C_3 - C_1$:
$\Delta = (a+b+c) \left|\begin{array}{ccc}1 & 0 & 0 \\ 2b & -(a+b+c) & 0 \\ 2c & 0 & -(a+b+c)\end{array}\right|$.
Expanding along $R_1$:
$\Delta = (a+b+c) [1 \cdot (-(a+b+c)) \cdot (-(a+b+c)) - 0]$
$\Delta = (a+b+c) (a+b+c)^2 = (a+b+c)^3$.

(B) We know that $\tanh \theta = \frac{\sinh \theta}{\cosh \theta} = \frac{e^{\theta} - e^{-\theta}}{e^{\theta} + e^{-\theta}}$.
Substituting $\theta = \frac{x}{2}$,we have $\tanh \frac{x}{2} = \frac{e^{x/2} - e^{-x/2}}{e^{x/2} + e^{-x/2}}$.
Now,consider the expression $\frac{1+\tanh \frac{x}{2}}{1-\tanh \frac{x}{2}}$:
$= \frac{1 + \frac{e^{x/2} - e^{-x/2}}{e^{x/2} + e^{-x/2}}}{1 - \frac{e^{x/2} - e^{-x/2}}{e^{x/2} + e^{-x/2}}}$
$= \frac{\frac{e^{x/2} + e^{-x/2} + e^{x/2} - e^{-x/2}}{e^{x/2} + e^{-x/2}}}{\frac{e^{x/2} + e^{-x/2} - (e^{x/2} - e^{-x/2})}{e^{x/2} + e^{-x/2}}}$
$= \frac{2e^{x/2}}{2e^{-x/2}}$
$= \frac{e^{x/2}}{e^{-x/2}} = e^{x/2 + x/2} = e^x$.

(B) Given that,$\sin ^{-1}\left(\frac{3}{x}\right)+\sin ^{-1}\left(\frac{4}{x}\right)=\frac{\pi}{2}$.
We know that $\sin ^{-1}(\theta) + \cos ^{-1}(\theta) = \frac{\pi}{2}$,so $\sin ^{-1}\left(\frac{3}{x}\right) = \frac{\pi}{2} - \sin ^{-1}\left(\frac{4}{x}\right) = \cos ^{-1}\left(\frac{4}{x}\right)$.
Let $\sin ^{-1}\left(\frac{3}{x}\right) = \theta$,then $\sin \theta = \frac{3}{x}$,which implies $\cos \theta = \sqrt{1 - \left(\frac{3}{x}\right)^2} = \frac{\sqrt{x^2 - 9}}{x}$.
Equating $\cos \theta = \frac{4}{x}$,we get $\frac{\sqrt{x^2 - 9}}{x} = \frac{4}{x}$.
Squaring both sides,$x^2 - 9 = 16$,which gives $x^2 = 25$.
Thus,$x = 5$ (since $x = -5$ does not satisfy the domain of the inverse sine function in the original equation).

(C) Given that,$f(x) = |x|$ and $g(x) = [x - 3]$.
For the interval $-\frac{8}{5} < x < \frac{8}{5}$,the range of $f(x) = |x|$ is $0 \leq f(x) < \frac{8}{5}$ (i.e.,$0 \leq f(x) < 1.6$).
We need to find the set of values for $g(f(x)) = [f(x) - 3]$.
Case $1$: If $0 \leq f(x) < 1$,then $-3 \leq f(x) - 3 < -2$. Therefore,$g(f(x)) = [f(x) - 3] = -3$.
Case $2$: If $1 \leq f(x) < 1.6$,then $-2 \leq f(x) - 3 < -1.4$. Therefore,$g(f(x)) = [f(x) - 3] = -2$.
Combining these cases,the set of values is $\{-3, -2\}$.

(A) Given,$f(x)=x^2-3$.
First,we calculate the values for each term:
For $x=-1$:
$f(-1) = (-1)^2-3 = -2$
$f(f(-1)) = f(-2) = (-2)^2-3 = 1$
$f(f(f(-1))) = f(1) = 1^2-3 = -2$
For $x=0$:
$f(0) = 0^2-3 = -3$
$f(f(0)) = f(-3) = (-3)^2-3 = 6$
$f(f(f(0))) = f(6) = 6^2-3 = 33$
For $x=1$:
$f(1) = 1^2-3 = -2$
$f(f(1)) = f(-2) = (-2)^2-3 = 1$
$f(f(f(1))) = f(1) = 1^2-3 = -2$
Now,summing these values:
$(f \circ f \circ f)(-1) + (f \circ f \circ f)(0) + (f \circ f \circ f)(1) = -2 + 33 - 2 = 29$.
Checking the options:
$f(4 \sqrt{2}) = (4 \sqrt{2})^2 - 3 = 32 - 3 = 29$.
Thus,the expression is equal to $f(4 \sqrt{2})$.

(C) Given that $\left(a+\frac{b}{10}\right)^x = \left(\frac{a}{10}+\frac{b}{100}\right)^y = 1000$.
We can rewrite the second term as $\left(\frac{1}{10}(a+\frac{b}{10})\right)^y = 1000$.
Let $K = a+\frac{b}{10}$. Then $K^x = 1000$ and $(\frac{K}{10})^y = 1000$.
From $K^x = 1000$,we have $K = 1000^{1/x} = 10^{3/x}$.
From $(\frac{K}{10})^y = 1000$,we have $\frac{K}{10} = 1000^{1/y} = 10^{3/y}$.
Thus,$K = 10 \times 10^{3/y} = 10^{1 + 3/y}$.
Equating the two expressions for $K$: $10^{3/x} = 10^{1 + 3/y}$.
Therefore,$\frac{3}{x} = 1 + \frac{3}{y}$.
Rearranging the terms,we get $\frac{3}{x} - \frac{3}{y} = 1$.
Dividing by $3$,we obtain $\frac{1}{x} - \frac{1}{y} = \frac{1}{3}$.

(B) Given that,$x=a\left(\cos \theta+\log \tan \left(\frac{\theta}{2}\right)\right)$ and $y=a \sin \theta$.
On differentiating $x$ and $y$ with respect to $\theta$,we get:
$\frac{dx}{d\theta} = a \left( -\sin \theta + \frac{1}{\tan(\theta/2)} \cdot \sec^2(\theta/2) \cdot \frac{1}{2} \right)$
Since $\frac{1}{\tan(\theta/2)} \cdot \sec^2(\theta/2) \cdot \frac{1}{2} = \frac{\cos(\theta/2)}{\sin(\theta/2)} \cdot \frac{1}{\cos^2(\theta/2)} \cdot \frac{1}{2} = \frac{1}{2 \sin(\theta/2) \cos(\theta/2)} = \frac{1}{\sin \theta}$.
So,$\frac{dx}{d\theta} = a \left( -\sin \theta + \frac{1}{\sin \theta} \right) = a \left( \frac{1 - \sin^2 \theta}{\sin \theta} \right) = \frac{a \cos^2 \theta}{\sin \theta}$.
Also,$\frac{dy}{d\theta} = a \cos \theta$.
Therefore,$\frac{dy}{dx} = \frac{dy/d\theta}{dx/d\theta} = \frac{a \cos \theta}{a \cos^2 \theta / \sin \theta} = \frac{\sin \theta}{\cos \theta} = \tan \theta$.

(B) Given $x=a[\cos \theta+\log (\tan (\theta/2))]$ and $y=a \sin \theta$.
First,differentiate $x$ with respect to $\theta$:
$\frac{dx}{d\theta} = a \left[ -\sin \theta + \frac{1}{\tan(\theta/2)} \cdot \sec^2(\theta/2) \cdot \frac{1}{2} \right]$
Using the identity $\tan(\theta/2) = \frac{\sin(\theta/2)}{\cos(\theta/2)}$ and $\sec^2(\theta/2) = \frac{1}{\cos^2(\theta/2)}$,we get:
$\frac{dx}{d\theta} = a \left[ -\sin \theta + \frac{\cos(\theta/2)}{\sin(\theta/2)} \cdot \frac{1}{\cos^2(\theta/2)} \cdot \frac{1}{2} \right]$
$\frac{dx}{d\theta} = a \left[ -\sin \theta + \frac{1}{2\sin(\theta/2)\cos(\theta/2)} \right]$
Since $2\sin(\theta/2)\cos(\theta/2) = \sin \theta$,we have:
$\frac{dx}{d\theta} = a \left[ -\sin \theta + \frac{1}{\sin \theta} \right] = a \left[ \frac{1-\sin^2 \theta}{\sin \theta} \right] = \frac{a \cos^2 \theta}{\sin \theta} \quad \dots(i)$
Now,differentiate $y$ with respect to $\theta$:
$\frac{dy}{d\theta} = a \cos \theta \quad \dots(ii)$
To find $\frac{dy}{dx}$,divide equation $(ii)$ by equation $(i)$:
$\frac{dy}{dx} = \frac{dy/d\theta}{dx/d\theta} = \frac{a \cos \theta}{a \cos^2 \theta / \sin \theta} = \frac{\sin \theta}{\cos \theta} = \tan \theta$.

(B) Let $u = \sec z = \frac{x^4+y^4-8x^2y^2}{x^2+y^2}$.
Here,$u$ is a homogeneous function of $x$ and $y$ with degree $n = \frac{4-2}{1} = 2$.
By Euler's Theorem for homogeneous functions,$x \frac{\partial u}{\partial x} + y \frac{\partial u}{\partial y} = n \cdot u$.
Since $u = \sec z$,we have $\frac{\partial u}{\partial x} = \sec z \tan z \frac{\partial z}{\partial x}$ and $\frac{\partial u}{\partial y} = \sec z \tan z \frac{\partial z}{\partial y}$.
Substituting these into Euler's theorem:
$x (\sec z \tan z \frac{\partial z}{\partial x}) + y (\sec z \tan z \frac{\partial z}{\partial y}) = 2 \sec z$.
Dividing both sides by $\sec z \tan z$:
$x \frac{\partial z}{\partial x} + y \frac{\partial z}{\partial y} = \frac{2 \sec z}{\sec z \tan z} = 2 \cot z$.

(D) Given that,$y=\sin (\log _e x)$ $(i)$.
On differentiating with respect to $x$,we get:
$\frac{d y}{d x} = \cos (\log _e x) \cdot \frac{1}{x} \implies x \frac{d y}{d x} = \cos (\log _e x)$.
Again differentiating with respect to $x$ using the product rule on the left side:
$x \frac{d^2 y}{d x^2} + \frac{d y}{d x} = -\sin (\log _e x) \cdot \frac{1}{x}$.
Multiplying both sides by $x$:
$x^2 \frac{d^2 y}{d x^2} + x \frac{d y}{d x} = -\sin (\log _e x)$.
Since $y = \sin (\log _e x)$,we have:
$x^2 \frac{d^2 y}{d x^2} + x \frac{d y}{d x} = -y$.

(B) Given the function $f(x) = (x-1)^2 + 3$ defined on the interval $x \in [-3, 1]$.
First,we find the critical points by differentiating $f(x)$ with respect to $x$:
$f'(x) = 2(x-1)$.
Setting $f'(x) = 0$ gives $2(x-1) = 0$,which implies $x = 1$.
Since $x = 1$ is an endpoint of the given interval $[-3, 1]$,we evaluate the function at the critical point and the boundaries of the interval:
At $x = 1$: $f(1) = (1-1)^2 + 3 = 3$.
At $x = -3$: $f(-3) = (-3-1)^2 + 3 = (-4)^2 + 3 = 16 + 3 = 19$.
Comparing these values,the minimum value $m = 3$ and the maximum value $M = 19$.
Therefore,the ordered pair $(m, M)$ is $(3, 19)$.

(A) Let $AB$ be a hill of height $h$ metres and $CD$ be a pillar of height $h'$ metres. Let $E$ be a point on $AB$ such that $ED$ is horizontal.
In $\triangle BED$,$\tan \alpha = \frac{BE}{ED} = \frac{h-h'}{ED} \implies ED = \frac{h-h'}{\tan \alpha}$.
In $\triangle BAC$,$\tan \beta = \frac{AB}{AC} = \frac{h}{ED} \implies ED = \frac{h}{\tan \beta}$.
Equating the two expressions for $ED$:
$\frac{h-h'}{\tan \alpha} = \frac{h}{\tan \beta}$
$h-h' = \frac{h \tan \alpha}{\tan \beta}$
$h' = h - \frac{h \tan \alpha}{\tan \beta} = h \left(1 - \frac{\tan \alpha}{\tan \beta}\right) = \frac{h(\tan \beta - \tan \alpha)}{\tan \beta}$.

(A) Given that,$I_n = \int x^n \cdot e^{cx} \, dx$.
Using integration by parts,let $u = x^n$ and $dv = e^{cx} \, dx$.
Then $du = n x^{n-1} \, dx$ and $v = \frac{e^{cx}}{c}$.
Applying the formula $\int u \, dv = uv - \int v \, du$:
$I_n = x^n \cdot \frac{e^{cx}}{c} - \int \frac{e^{cx}}{c} \cdot n x^{n-1} \, dx$.
$I_n = \frac{x^n e^{cx}}{c} - \frac{n}{c} \int x^{n-1} e^{cx} \, dx$.
Since $I_{n-1} = \int x^{n-1} e^{cx} \, dx$,we have:
$I_n = \frac{x^n e^{cx}}{c} - \frac{n}{c} I_{n-1}$.
Multiplying both sides by $c$:
$c I_n = x^n e^{cx} - n I_{n-1}$.
Rearranging the terms:
$c I_n + n I_{n-1} = x^n e^{cx}$.

(C) We have the integral $I = \int e^x \left( \frac{1-\sin x}{1-\cos x} \right) dx$.
Using trigonometric identities $\sin x = 2 \sin \frac{x}{2} \cos \frac{x}{2}$ and $1-\cos x = 2 \sin^2 \frac{x}{2}$,we get:
$I = \int e^x \left( \frac{1 - 2 \sin \frac{x}{2} \cos \frac{x}{2}}{2 \sin^2 \frac{x}{2}} \right) dx$
$I = \int e^x \left( \frac{1}{2 \sin^2 \frac{x}{2}} - \frac{2 \sin \frac{x}{2} \cos \frac{x}{2}}{2 \sin^2 \frac{x}{2}} \right) dx$
$I = \int e^x \left( \frac{1}{2} \operatorname{cosec}^2 \frac{x}{2} - \cot \frac{x}{2} \right) dx$
Let $g(x) = -\cot \frac{x}{2}$. Then $g'(x) = -(-\operatorname{cosec}^2 \frac{x}{2} \cdot \frac{1}{2}) = \frac{1}{2} \operatorname{cosec}^2 \frac{x}{2}$.
Since the integral is of the form $\int e^x (g(x) + g'(x)) dx = e^x g(x) + c$,we have:
$I = e^x \left( -\cot \frac{x}{2} \right) + c = -e^x \cot \frac{x}{2} + c$.
Thus,$f(x) = -e^x \cot \left( \frac{x}{2} \right)$.

(B) The given curve is $2x = y^2 - 1$,which can be rewritten as $x = \frac{y^2 - 1}{2}$.
The curve $x = 0$ represents the $y$-axis.
The intersection points of the curve $x = \frac{y^2 - 1}{2}$ and $x = 0$ are found by setting $\frac{y^2 - 1}{2} = 0$,which gives $y^2 = 1$,so $y = \pm 1$.
The area bounded by the curve and the $y$-axis is given by the integral of $|x|$ with respect to $y$ from $y = -1$ to $y = 1$.
$\text{Area} = \int_{-1}^{1} |x| \, dy = \int_{-1}^{1} \left| \frac{y^2 - 1}{2} \right| \, dy$.
Since the region is symmetric about the $x$-axis,the area is $2 \int_{0}^{1} \left| \frac{y^2 - 1}{2} \right| \, dy$.
In the interval $[0, 1]$,$y^2 - 1 \leq 0$,so $|\frac{y^2 - 1}{2}| = -\frac{y^2 - 1}{2} = \frac{1 - y^2}{2}$.
$\text{Area} = 2 \int_{0}^{1} \frac{1 - y^2}{2} \, dy = \int_{0}^{1} (1 - y^2) \, dy$.
$= [y - \frac{y^3}{3}]_{0}^{1} = (1 - \frac{1}{3}) - (0 - 0) = \frac{2}{3} \text{ sq unit}$.

(C) The image of an object in white light formed by a lens is usually coloured and blurred. This defect is called chromatic aberration and arises because the focal length of a lens varies with the wavelength of light (dispersion).
An achromatic combination of lenses is designed to minimize or eliminate this chromatic aberration.
By combining two lenses of different materials (e.g.,crown glass and flint glass) such that their dispersive powers compensate for each other,the resulting image is free from color fringing.
Therefore,the images produced by an achromatic combination are unaffected by the variation of the refractive index with wavelength.

(A) For a plano-concave lens,one surface is plane $(R_1 = \infty)$ and the other is concave $(R_2 = 0.3 ~m)$. According to the sign convention,for a concave surface,$R_2 = +0.3 ~m$ (if light enters from the plane side) or $R_1 = -0.3 ~m$ (if light enters from the curved side).
Using the Lens Maker's formula: $\frac{1}{f} = (\mu - 1) \left( \frac{1}{R_1} - \frac{1}{R_2} \right)$.
For a plano-concave lens,$R_1 = \infty$ and $R_2 = 0.3 ~m$.
Substituting the values: $\frac{1}{f} = (\frac{5}{3} - 1) \left( \frac{1}{\infty} - \frac{1}{0.3} \right)$.
$\frac{1}{f} = (\frac{2}{3}) \times (0 - \frac{1}{0.3}) = -\frac{2}{3 \times 0.3} = -\frac{2}{0.9} = -\frac{20}{9}$.
$f = -\frac{9}{20} ~m = -0.45 ~m$.

(B) $(i)$ The alkali metal superoxides contain $O_2^{-}$ ion,which has an unpaired electron,hence they are paramagnetic in nature. This statement is correct.
$(ii)$ The basic character of alkali metal hydroxides increases on moving down the group due to the increase in electropositive character. This statement is correct.
$(iii)$ The conductivity of alkali metal chlorides in their aqueous solution increases on moving down the group. As the size of the alkali metal ion increases,the degree of hydration decreases,which increases the ionic mobility. This statement is incorrect.
$(iv)$ The basic nature of carbonates in aqueous solution is due to anionic hydrolysis of the $CO_3^{2-}$ ion: $CO_3^{2-} + H_2O \rightleftharpoons HCO_3^{-} + OH^{-}$. This statement is incorrect.

(D) When a junction diode is forward biased,the positive terminal of the battery is connected to the $p$-side and the negative terminal to the $n$-side. This causes the majority charge carriers (holes in the $p$-region and electrons in the $n$-region) to be pushed towards the junction. As a result,the width of the depletion region decreases,and the potential barrier is lowered. Therefore,the statement that electrons and holes move away from the junction is incorrect.

(D) Given differential equation is $\frac{dy}{dx} = \frac{xy+y}{xy+x}$.
Separating the variables,we get $\frac{dy}{dx} = \frac{y(x+1)}{x(y+1)}$.
Rearranging the terms,we have $\frac{1+y}{y} dy = \frac{1+x}{x} dx$.
Integrating both sides,we get $\int (\frac{1}{y} + 1) dy = \int (\frac{1}{x} + 1) dx$.
This results in $\log |y| + y = \log |x| + x + C$.
Rearranging the terms,$y - x = \log |x| - \log |y| + C$.
$y - x = \log \left|\frac{x}{y}\right| + C$.
Let $C = \log c$,then $y - x = \log \left|\frac{cx}{y}\right|$.

(A) Given the differential equation: $\frac{dy}{dx} = \frac{x-2y+1}{2(x-2y)}$
Let $z = x-2y$. Then,differentiating with respect to $x$,we get $\frac{dz}{dx} = 1 - 2\frac{dy}{dx}$,which implies $\frac{dy}{dx} = \frac{1}{2}(1 - \frac{dz}{dx})$.
Substituting these into the original equation:
$\frac{1}{2}(1 - \frac{dz}{dx}) = \frac{z+1}{2z}$
$1 - \frac{dz}{dx} = \frac{z+1}{z}$
$1 - \frac{dz}{dx} = 1 + \frac{1}{z}$
$-\frac{dz}{dx} = \frac{1}{z}$
$z dz = -dx$
Integrating both sides:
$\int z dz = \int -dx$
$\frac{z^2}{2} = -x + C_1$
$z^2 = -2x + 2C_1$
Substituting $z = x-2y$ back:
$(x-2y)^2 = -2x + C$
$(x-2y)^2 + 2x = C$
Thus,the correct option is $A$.

(C) Given the direction cosines of the two lines as $(l_1, m_1, n_1) = \left(\frac{\sqrt{3}}{4}, \frac{1}{4}, \frac{\sqrt{3}}{2}\right)$ and $(l_2, m_2, n_2) = \left(\frac{\sqrt{3}}{4}, \frac{1}{4}, \frac{-\sqrt{3}}{2}\right)$.
The cosine of the angle $\theta$ between two lines with direction cosines $(l_1, m_1, n_1)$ and $(l_2, m_2, n_2)$ is given by $\cos \theta = |l_1 l_2 + m_1 m_2 + n_1 n_2|$.
Substituting the values:
$\cos \theta = \left| \left(\frac{\sqrt{3}}{4}\right)\left(\frac{\sqrt{3}}{4}\right) + \left(\frac{1}{4}\right)\left(\frac{1}{4}\right) + \left(\frac{\sqrt{3}}{2}\right)\left(-\frac{\sqrt{3}}{2}\right) \right|$
$\cos \theta = \left| \frac{3}{16} + \frac{1}{16} - \frac{3}{4} \right|$
$\cos \theta = \left| \frac{4}{16} - \frac{12}{16} \right| = \left| -\frac{8}{16} \right| = \left| -\frac{1}{2} \right| = \frac{1}{2}$.
Since $\cos \theta = \frac{1}{2}$,we have $\theta = \frac{\pi}{3}$.

(B) Let $R$ be the event that a red ball is drawn. The contents of the boxes are:
$B_1: 1R, 2W \implies P(R|B_1) = \frac{1}{3}$
$B_2: 2R, 3W \implies P(R|B_2) = \frac{2}{5}$
$B_3: 3R, 4W \implies P(R|B_3) = \frac{3}{7}$
Given $P(B_1) = \frac{1}{2}$,$P(B_2) = \frac{1}{3}$,$P(B_3) = \frac{1}{6}$.
Using Bayes' Theorem,the probability that the ball came from $B_2$ given it is red is:
$P(B_2|R) = \frac{P(B_2)P(R|B_2)}{P(B_1)P(R|B_1) + P(B_2)P(R|B_2) + P(B_3)P(R|B_3)}$
$P(B_2|R) = \frac{\frac{1}{3} \times \frac{2}{5}}{\frac{1}{2} \times \frac{1}{3} + \frac{1}{3} \times \frac{2}{5} + \frac{1}{6} \times \frac{3}{7}}$
$P(B_2|R) = \frac{\frac{2}{15}}{\frac{1}{6} + \frac{2}{15} + \frac{1}{14}}$
Finding the common denominator for the denominator: $LCM(6, 15, 14) = 210$.
$P(B_2|R) = \frac{\frac{2}{15}}{\frac{35 + 28 + 15}{210}} = \frac{2}{15} \times \frac{210}{78} = \frac{2 \times 14}{78} = \frac{28}{78} = \frac{14}{39}$.

(A) Given: Angle of diffraction $(2 \theta) = 90^{\circ}$,so $\theta = 45^{\circ}$.
Distance between two planes,$d = 2.28 \ \mathring{A}$.
Order of diffraction,$n = 2$.
Bragg's equation is given by $n \lambda = 2 d \sin \theta$.
Substituting the values: $2 \times \lambda = 2 \times 2.28 \times \sin 45^{\circ}$.
Since $\sin 45^{\circ} = \frac{1}{\sqrt{2}} \approx 0.707$,we have $2 \lambda = 2 \times 2.28 \times 0.707$.
$\lambda = 2.28 \times 0.707 = 1.612 \ \mathring{A}$.

(C) Given:
Weight of non-volatile solute,$w = 25 \ g$
Weight of solvent,$W = 100 \ g$
Lowering of vapour pressure,$p^{\circ} - p_s = 0.225 \ mm$
Vapour pressure of pure solvent,$p^{\circ} = 17.5 \ mm$
Molar mass of solvent $(H_2O)$,$M = 18 \ g/mol$
Molar mass of solute,$m = ?$
According to Raoult's law for lowering of vapour pressure:
$\frac{p^{\circ} - p_s}{p^{\circ}} = \frac{w \times M}{m \times W}$
Substituting the values:
$\frac{0.225}{17.5} = \frac{25 \times 18}{m \times 100}$
$m = \frac{25 \times 18 \times 17.5}{0.225 \times 100}$
$m = \frac{25 \times 18 \times 17.5}{22.5}$
$m = 350 \ g/mol$

(B) The ratio of weight average molecular weight to the number average molecular weight is defined as the poly dispersity index $(PDI)$.
$PDI = \frac{\bar{M}_w}{\bar{M}_n}$
where,
$\bar{M}_w = \text{weight average molecular weight}$
$\bar{M}_n = \text{number average molecular weight}$
$PDI$ is unity $(1)$ for natural monodispersed polymers,whereas for synthetic polymers,it is always greater than unity.

(A) $CaCO_3 \xrightarrow{\Delta} CaO + CO_2$. $100 \ g \ CaCO_3$ gives $22.4 \ L \ CO_2$ at $STP$. So,$10 \ g \ CaCO_3$ gives $\frac{22.4 \times 10}{100} = 2.24 \ L \ CO_2$ $(iv)$.
$(B)$ $Na_2CO_3 + 2HCl \rightarrow 2NaCl + H_2O + CO_2$. $106 \ g \ Na_2CO_3$ gives $22.4 \ L \ CO_2$. So,$1.06 \ g \ Na_2CO_3$ gives $\frac{22.4 \times 1.06}{106} = 0.224 \ L \ CO_2$ $(i)$.
$(C)$ $C + O_2 \rightarrow CO_2$. $12 \ g \ C$ gives $22.4 \ L \ CO_2$. So,$2.4 \ g \ C$ gives $\frac{22.4 \times 2.4}{12} = 4.48 \ L \ CO_2$ $(ii)$.
$(D)$ $2CO + O_2 \rightarrow 2CO_2$. $56 \ g \ CO$ gives $2 \times 22.4 \ L \ CO_2 = 44.8 \ L \ CO_2$. So,$0.56 \ g \ CO$ gives $\frac{44.8 \times 0.56}{56} = 0.448 \ L \ CO_2$ $(iii)$.
Thus,the correct match is $A-iv, B-i, C-ii, D-iii$.

(C) The kinetic energy $(KE)$ of an ideal gas is given by the formula $KE = nRT$,where $n$ is the number of moles,$R$ is the universal gas constant,and $T$ is the temperature in Kelvin.
For helium: $n_1 = 0.3 \ mol$,$T_1 = T$.
$KE_{He} = 0.3 \times R \times T$.
For argon: $n_2 = 0.4 \ mol$,$T_2 = 400 \ K$.
$KE_{Ar} = 0.4 \times R \times 400$.
According to the problem,$KE_{He} = KE_{Ar}$.
$0.3 \times R \times T = 0.4 \times R \times 400$.
Dividing both sides by $R$:
$0.3 \times T = 160$.
$T = \frac{160}{0.3} = 533.33 \ K \approx 533 \ K$.