AIIMS 1984 Chemistry Question Paper with Answer and Solution

4 QuestionsEnglishWith Solutions

ChemistryQ14 of 4 questions

Page 1 of 1 · English

1
ChemistryEasyMCQAIIMS · 1984
If the electron pair forming a bond between two atoms $A$ and $B$ is not in the centre,then the bond is
A
Single bond
B
Polar bond
C
Non-polar bond
D
$\pi$ bond

Solution

(B) When there is a difference in electronegativity between two bonded atoms,the shared electron pair is attracted more towards the more electronegative atom.
As a result,the electron pair does not remain in the centre,leading to the formation of a polar bond.
2
ChemistryMediumMCQAIIMS · 1984
The decomposition of $N_2O_4$ to $NO_2$ is carried out at $280 \ K$ in chloroform. When equilibrium has been established,$0.2 \ mol$ of $N_2O_4$ and $2 \times 10^{-3} \ mol$ of $NO_2$ are present in $2 \ L$ solution. The equilibrium constant for the reaction $N_2O_4 \rightleftharpoons 2NO_2$ is:
A
$1 \times 10^{-2}$
B
$2 \times 10^{-3}$
C
$1 \times 10^{-5}$
D
$2 \times 10^{-5}$

Solution

(C) The reaction is $N_2O_4 \rightleftharpoons 2NO_2$.
First,calculate the molar concentrations of the species at equilibrium:
$[N_2O_4] = \frac{0.2 \ mol}{2 \ L} = 0.1 \ M$.
$[NO_2] = \frac{2 \times 10^{-3} \ mol}{2 \ L} = 10^{-3} \ M$.
The equilibrium constant expression is $K_c = \frac{[NO_2]^2}{[N_2O_4]}$.
Substituting the values: $K_c = \frac{(10^{-3})^2}{0.1} = \frac{10^{-6}}{10^{-1}} = 10^{-5}$.
3
ChemistryEasyMCQAIIMS · 1984
What is the oxidation number of nickel in $Ni(CO)_4$?
A
$0$
B
$+4$
C
$-4$
D
$+2$

Solution

(A) In the coordination compound $Ni(CO)_4$,the ligand is carbonyl $(CO)$,which is a neutral ligand with an oxidation state of $0$.
Let the oxidation state of $Ni$ be $x$.
The sum of oxidation states of all atoms in a neutral complex is $0$.
$x + 4 \times (0) = 0$
$x = 0$.
Therefore,the oxidation number of nickel in $Ni(CO)_4$ is $0$.
4
ChemistryDifficultMCQAIIMS · 1984
Which one of the following is not a property of hydrophilic sols?
A
High concentrations of dispersed phase can be easily attained
B
Coagulation is reversible
C
Viscosity and surface tension are about the same as for water
D
The charge of the particle depends on the $pH$ values of the medium; it may be positive,negative or even zero

Solution

(C) The correct answer is $(C)$.
Hydrophilic sols (lyophilic colloids) have a strong affinity between the dispersed phase and the dispersion medium.
Due to this interaction,the viscosity of these sols is significantly higher than that of the dispersion medium (water),and their surface tension is generally lower than that of water.
Therefore,the statement that viscosity and surface tension are about the same as for water is incorrect.

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