AP EAMCET 2013 Chemistry Question Paper with Answer and Solution

199 QuestionsEnglishWith Solutions

ChemistryQ51100 of 199 questions

Page 2 of 4 · English

51
ChemistryMCQAP EAMCET · 2013
If the circle $x^2+y^2+4x-6y+c=0$ bisects the circumference of the circle $x^2+y^2-6x+4y-12=0$,then $c$ is equal to
A
$16$
B
$24$
C
$-42$
D
$-62$

Solution

(D) The common chord of the two circles $S_1 = x^2+y^2+4x-6y+c=0$ and $S_2 = x^2+y^2-6x+4y-12=0$ is given by $S_1 - S_2 = 0$.
$(x^2+y^2+4x-6y+c) - (x^2+y^2-6x+4y-12) = 0$
$10x - 10y + c + 12 = 0$
Since the first circle bisects the circumference of the second circle,the common chord must pass through the center of the second circle.
The center of the second circle $x^2+y^2-6x+4y-12=0$ is $(-g, -f) = (3, -2)$.
Substituting $(3, -2)$ into the equation of the common chord:
$10(3) - 10(-2) + c + 12 = 0$
$30 + 20 + c + 12 = 0$
$62 + c = 0$
$c = -62$
52
ChemistryMCQAP EAMCET · 2013
For the circle $C$ with the equation $x^2+y^2-16x-12y+64=0$,match the List-$I$ with the List-$II$ given below.
List-$I$List-$II$
$(i)$ The equation of the polar of $(-5, 1)$ with respect to $C$$(A)$ $y = 0$
$(ii)$ The equation of the tangent at $(8, 0)$ to $C$$(B)$ $y = 6$
$(iii)$ The equation of the normal at $(2, 6)$ to $C$$(C)$ $x + y = 7$
$(iv)$ The equation of the diameter of $C$ through $(8, 12)$$(D)$ $13x + 5y = 98$
$(E)$ $x = 8$
A
$(D), (A), (B), (E)$
B
$(D), (A), (B), (E)$
C
$(C), (D), (A), (B)$
D
$(C), (E), (B), (A)$

Solution

(A) The given equation of the circle is $x^2+y^2-16x-12y+64=0$. The center is $(8, 6)$ and the radius is $r = \sqrt{8^2+6^2-64} = \sqrt{64+36-64} = 6$.
$(i)$ The equation of the polar of $(x_1, y_1)$ w.r.t. $x^2+y^2+2gx+2fy+c=0$ is $xx_1+yy_1+g(x+x_1)+f(y+y_1)+c=0$.
For $(-5, 1)$,it is $x(-5)+y(1)-8(x-5)-6(y+1)+64=0$ $\Rightarrow -5x+y-8x+40-6y-6+64=0$ $\Rightarrow -13x-5y+98=0$ $\Rightarrow 13x+5y=98$. This matches $(D)$.
$(ii)$ The equation of the tangent at $(x_1, y_1)$ is $xx_1+yy_1-8(x+x_1)-6(y+y_1)+64=0$.
For $(8, 0)$,it is $x(8)+y(0)-8(x+8)-6(y+0)+64=0$ $\Rightarrow 8x-8x-64-6y+64=0$ $\Rightarrow -6y=0$ $\Rightarrow y=0$. This matches $(A)$.
$(iii)$ The normal at any point on a circle passes through the center $(8, 6)$. The normal at $(2, 6)$ passes through $(2, 6)$ and $(8, 6)$. Since the $y$-coordinates are the same,the equation is $y=6$. This matches $(B)$.
$(iv)$ The diameter passes through the center $(8, 6)$ and the point $(8, 12)$. Since the $x$-coordinates are the same,the equation is $x=8$. This matches $(E)$.
Thus,the correct match is $(i)-(D), (ii)-(A), (iii)-(B), (iv)-(E)$.
53
ChemistryMCQAP EAMCET · 2013
$A$ circle of radius $4$,drawn on a chord of the parabola $y^2 = 8x$ as diameter,touches the axis of the parabola. Then,the slope of the chord is
A
$1/2$
B
$3/4$
C
$1$
D
$2$

Solution

(C) The equation of the parabola is $y^2 = 8x$,so $4a = 8$,which gives $a = 2$.
Let the chord be $y = mx + c$.
The points of intersection of the line $y = mx + c$ and the parabola $y^2 = 8x$ are obtained by substituting $x = (y - c)/m$ into the parabola equation: $y^2 = 8(y - c)/m \Rightarrow my^2 - 8y + 8c = 0$.
Let the points be $P(x_1, y_1)$ and $Q(x_2, y_2)$. Then $y_1 + y_2 = 8/m$ and $y_1y_2 = 8c/m$.
The midpoint of the chord is $M = (\frac{x_1+x_2}{2}, \frac{y_1+y_2}{2})$.
The circle with the chord as diameter has radius $R = 4$.
The distance from the center of the circle to the axis of the parabola $(y = 0)$ is equal to the radius $4$,so the $y$-coordinate of the center is $4$ (or $-4$).
Thus,$\frac{y_1+y_2}{2} = 4 \Rightarrow y_1 + y_2 = 8$.
Since $y_1 + y_2 = 8/m$,we have $8/m = 8$,which implies $m = 1$.
54
ChemistryMCQAP EAMCET · 2013
If $x$ is small,so that $x^2$ and higher powers can be neglected,then the approximate value for $\frac{(1-2 x)^{-1}(1-3 x)^{-2}}{(1-4 x)^{-3}}$ is
A
$1-2 x$
B
$1-3 x$
C
$1-4 x$
D
$1-5 x$

Solution

(C) Given expression is $E = \frac{(1-2 x)^{-1}(1-3 x)^{-2}}{(1-4 x)^{-3}}$.
Using the binomial expansion $(1+ax)^n \approx 1+nax$ for small $x$:
$(1-2 x)^{-1} \approx 1 + (-1)(-2x) = 1 + 2x$.
$(1-3 x)^{-2} \approx 1 + (-2)(-3x) = 1 + 6x$.
$(1-4 x)^{-3} \approx 1 + (-3)(-4x) = 1 + 12x$.
Substituting these into the expression:
$E \approx \frac{(1+2x)(1+6x)}{1+12x} = \frac{1 + 6x + 2x + 12x^2}{1+12x}$.
Neglecting $x^2$ and higher powers:
$E \approx \frac{1+8x}{1+12x} = (1+8x)(1+12x)^{-1}$.
Using the binomial expansion again:
$E \approx (1+8x)(1-12x) = 1 - 12x + 8x - 96x^2$.
Neglecting $x^2$:
$E \approx 1 - 4x$.
55
ChemistryMCQAP EAMCET · 2013
The mid-point of a chord of the ellipse $x^2+4y^2-2x+20y=0$ is $(2, -4)$. The equation of the chord is
A
$x-6y=26$
B
$x+6y=26$
C
$6x-y=26$
D
$6x+y=26$

Solution

(A) The equation of a chord of a conic $S=0$ with mid-point $(x_1, y_1)$ is given by $T=S_1$.
Given ellipse: $S: x^2+4y^2-2x+20y=0$.
Mid-point $(x_1, y_1) = (2, -4)$.
$T = x(x_1) + 4y(y_1) - (x+x_1) + 10(y+y_1) = x(2) + 4y(-4) - (x+2) + 10(y-4) = 2x - 16y - x - 2 + 10y - 40 = x - 6y - 42$.
$S_1 = (x_1)^2 + 4(y_1)^2 - 2(x_1) + 20(y_1) = (2)^2 + 4(-4)^2 - 2(2) + 20(-4) = 4 + 64 - 4 - 80 = -16$.
Equating $T=S_1$:
$x - 6y - 42 = -16$.
$x - 6y = 42 - 16$.
$x - 6y = 26$.
56
ChemistryMCQAP EAMCET · 2013
If the foci of the ellipse $\frac{x^2}{25}+\frac{y^2}{16}=1$ and the hyperbola $\frac{x^2}{4}-\frac{y^2}{b^2}=1$ coincide,then $b^2$ is equal to
A
$4$
B
$5$
C
$8$
D
$9$

Solution

(B) The equation of the ellipse is $\frac{x^2}{25}+\frac{y^2}{16}=1$. Here $a^2=25$ and $b^2=16$.
For an ellipse,$b^2=a^2(1-e^2)$,so $16=25(1-e^2)$,which gives $e^2=1-\frac{16}{25}=\frac{9}{25}$,so $e=\frac{3}{5}$.
The foci of the ellipse are $(\pm ae, 0) = (\pm 5 \times \frac{3}{5}, 0) = (\pm 3, 0)$.
The equation of the hyperbola is $\frac{x^2}{4}-\frac{y^2}{b^2}=1$. Here $a^2=4$,so $a=2$.
Since the foci of the hyperbola coincide with the foci of the ellipse,the foci of the hyperbola are $(\pm 3, 0)$.
For a hyperbola,the foci are $(\pm ae_1, 0)$,so $ae_1=3$. Since $a=2$,we have $2e_1=3$,which means $e_1=\frac{3}{2}$.
For a hyperbola,$b^2=a^2(e_1^2-1)$.
Substituting the values,$b^2=4((\frac{3}{2})^2-1) = 4(\frac{9}{4}-1) = 4(\frac{5}{4}) = 5$.
Thus,$b^2=5$.
57
ChemistryMCQAP EAMCET · 2013
If $x=9$ is a chord of contact of the hyperbola $x^2-y^2=9$,then the equation of the tangent at one of the points of contact is
A
$x+\sqrt{3} y+2=0$
B
$3 x+2 \sqrt{2} y-3=0$
C
$3 x-\sqrt{2} y+6=0$
D
$x-\sqrt{3} y+2=0$

Solution

(B) Given that $x=9$ is a chord of contact of the hyperbola $x^2-y^2=9$.
Substituting $x=9$ into the hyperbola equation:
$81-y^2=9$
$y^2=72$
$y = \pm 6\sqrt{2}$.
Thus,the points of contact are $(9, 6\sqrt{2})$ and $(9, -6\sqrt{2})$.
Differentiating $x^2-y^2=9$ with respect to $x$:
$2x - 2y \frac{dy}{dx} = 0 \implies \frac{dy}{dx} = \frac{x}{y}$.
At point $(9, 6\sqrt{2})$,the slope $m = \frac{9}{6\sqrt{2}} = \frac{3}{2\sqrt{2}}$.
The equation of the tangent at $(9, 6\sqrt{2})$ is:
$y - 6\sqrt{2} = \frac{3}{2\sqrt{2}}(x-9)$
$2\sqrt{2}y - 24 = 3x - 27$
$3x - 2\sqrt{2}y - 3 = 0$.
At point $(9, -6\sqrt{2})$,the slope $m = \frac{9}{-6\sqrt{2}} = -\frac{3}{2\sqrt{2}}$.
The equation of the tangent at $(9, -6\sqrt{2})$ is:
$y + 6\sqrt{2} = -\frac{3}{2\sqrt{2}}(x-9)$
$2\sqrt{2}y + 24 = -3x + 27$
$3x + 2\sqrt{2}y - 3 = 0$.
Comparing with the options,$3x + 2\sqrt{2}y - 3 = 0$ is option $B$.
58
ChemistryMCQAP EAMCET · 2013
$\lim _{x \rightarrow 0} \frac{\tan ^3 x-\sin ^3 x}{x^5}$ is equal to
A
$\frac{5}{2}$
B
$\frac{3}{2}$
C
$\frac{3}{5}$
D
$\frac{2}{5}$

Solution

(B) We have the limit $L = \lim _{x \rightarrow 0} \frac{\tan ^3 x-\sin ^3 x}{x^5}$.
Using the Taylor series expansions: $\tan x = x + \frac{x^3}{3} + \frac{2x^5}{15} + O(x^7)$ and $\sin x = x - \frac{x^3}{6} + \frac{x^5}{120} + O(x^7)$.
Factorizing the numerator: $\tan^3 x - \sin^3 x = (\tan x - \sin x)(\tan^2 x + \tan x \sin x + \sin^2 x)$.
Now,$\tan x - \sin x = \sin x (\sec x - 1) = \sin x \left(\frac{1-\cos x}{\cos x}\right) = \sin x \cdot \frac{2 \sin^2(x/2)}{\cos x}$.
As $x \rightarrow 0$,$\sin x \approx x$,$\sin(x/2) \approx x/2$,and $\cos x \approx 1$.
So,$\tan x - \sin x \approx x \cdot \frac{2(x/2)^2}{1} = \frac{x^3}{2}$.
Substituting this into the limit expression:
$L = \lim _{x \rightarrow 0} \frac{(\frac{x^3}{2})(\tan^2 x + \tan x \sin x + \sin^2 x)}{x^5}$.
$L = \lim _{x \rightarrow 0} \frac{1}{2} \cdot \frac{\tan^2 x + \tan x \sin x + \sin^2 x}{x^2}$.
Since $\lim _{x \rightarrow 0} \frac{\tan x}{x} = 1$ and $\lim _{x \rightarrow 0} \frac{\sin x}{x} = 1$,we have:
$L = \frac{1}{2} (1^2 + 1 \cdot 1 + 1^2) = \frac{1}{2} (3) = \frac{3}{2}$.
59
ChemistryMCQAP EAMCET · 2013
Example of a biodegradable polymer pair is
A
nylon-$6,6$ and terylene
B
$PHBV$ and $Dextron$
C
bakelite and $PVC$
D
$PET$ and polyethylene

Solution

(B) $PHBV$ and $Dextron$ are examples of biodegradable polymers.
Biodegradable polymers are those that disintegrate over time through enzymatic hydrolysis and oxidation.
$PHBV$ (Poly-$\beta$-hydroxybutyrate-co-$\beta$-hydroxyvalerate) is used in orthopaedic devices and controlled drug release.
$Dextron$ (a copolymer of glycolic acid and lactic acid) is used for stitching wounds after surgery.
Thus,the correct pair is $PHBV$ and $Dextron$.
60
ChemistryMCQAP EAMCET · 2013
The random variable $X$ takes the values $1, 2, 3, \ldots, m$. If $P(X=n) = \frac{1}{m}$ for each $n$,then the variance of $X$ is
A
$\frac{(m+1)(2m+1)}{6}$
B
$\frac{m^2-1}{12}$
C
$\frac{m+1}{2}$
D
$\frac{m^2+1}{12}$

Solution

(B) The random variable $X$ follows a discrete uniform distribution on the set $\{1, 2, \ldots, m\}$.
The mean $\bar{X} = E[X] = \sum_{n=1}^{m} n \cdot P(X=n) = \frac{1}{m} \sum_{n=1}^{m} n = \frac{1}{m} \cdot \frac{m(m+1)}{2} = \frac{m+1}{2}$.
The variance is given by $\operatorname{Var}(X) = E[X^2] - (E[X])^2$.
$E[X^2] = \sum_{n=1}^{m} n^2 \cdot P(X=n) = \frac{1}{m} \sum_{n=1}^{m} n^2 = \frac{1}{m} \cdot \frac{m(m+1)(2m+1)}{6} = \frac{(m+1)(2m+1)}{6}$.
Therefore,$\operatorname{Var}(X) = \frac{(m+1)(2m+1)}{6} - \left(\frac{m+1}{2}\right)^2$.
$\operatorname{Var}(X) = \frac{m+1}{2} \left[ \frac{2(2m+1)}{3} - \frac{m+1}{2} \right] = \frac{m+1}{2} \left[ \frac{8m+4-3m-3}{6} \right] = \frac{m+1}{2} \cdot \frac{5m+1}{6}$ (Wait,let's re-calculate).
$\operatorname{Var}(X) = \frac{(m+1)(2m+1)}{6} - \frac{(m+1)^2}{4} = \frac{m+1}{2} \left[ \frac{2(2m+1) - 3(m+1)}{6} \right] = \frac{m+1}{2} \left[ \frac{4m+2-3m-3}{6} \right] = \frac{m+1}{2} \cdot \frac{m-1}{6} = \frac{m^2-1}{12}$.
61
ChemistryMCQAP EAMCET · 2013
If in a $\triangle ABC$,$\frac{1}{a+c} + \frac{1}{b+c} = \frac{3}{a+b+c}$,then $\angle C$ is equal to (in $^{\circ}$)
A
$30$
B
$45$
C
$60$
D
$90$

Solution

(C) Given the equation: $\frac{1}{a+c} + \frac{1}{b+c} = \frac{3}{a+b+c}$.
Taking $LCM$ on the left side: $\frac{(b+c) + (a+c)}{(a+c)(b+c)} = \frac{3}{a+b+c}$.
$\frac{a+b+2c}{ab+ac+bc+c^2} = \frac{3}{a+b+c}$.
Cross-multiplying: $(a+b+2c)(a+b+c) = 3(ab+ac+bc+c^2)$.
$(a+b)^2 + c(a+b) + 2c(a+b) + 2c^2 = 3ab + 3ac + 3bc + 3c^2$.
$a^2 + b^2 + 2ab + 3ac + 3bc + 2c^2 = 3ab + 3ac + 3bc + 3c^2$.
$a^2 + b^2 - ab = c^2$.
Using the Law of Cosines: $c^2 = a^2 + b^2 - 2ab \cos C$.
Comparing the two equations: $a^2 + b^2 - ab = a^2 + b^2 - 2ab \cos C$.
$-ab = -2ab \cos C$.
$\cos C = \frac{1}{2}$.
Therefore,$\angle C = 60^{\circ}$.
62
ChemistryMCQAP EAMCET · 2013
In $\triangle ABC$,if $\frac{1}{b+c} + \frac{1}{c+a} = \frac{3}{a+b+c}$,then $C$ is equal to (in $^{\circ}$)
A
$90$
B
$60$
C
$45$
D
$30$

Solution

(B) Given that,$\frac{1}{b+c} + \frac{1}{c+a} = \frac{3}{a+b+c}$.
Taking common denominators on the left side:
$\frac{(c+a) + (b+c)}{(b+c)(c+a)} = \frac{3}{a+b+c}$
$\frac{a+b+2c}{bc + ab + c^2 + ac} = \frac{3}{a+b+c}$
Cross-multiplying:
$(a+b+2c)(a+b+c) = 3(bc + ab + c^2 + ac)$
$(a+b)^2 + c(a+b) + 2c(a+b) + 2c^2 = 3bc + 3ab + 3c^2 + 3ac$
$a^2 + b^2 + 2ab + 3ac + 3bc + 2c^2 = 3bc + 3ab + 3c^2 + 3ac$
Subtracting $3ac + 3bc$ from both sides:
$a^2 + b^2 + 2ab + 2c^2 = 3ab + 3c^2$
$a^2 + b^2 - c^2 = ab$
Using the Law of Cosines,$\cos C = \frac{a^2 + b^2 - c^2}{2ab}$:
$\cos C = \frac{ab}{2ab} = \frac{1}{2}$
Since $\cos C = \frac{1}{2}$,we have $C = 60^{\circ}$.
63
ChemistryMCQAP EAMCET · 2013
In any $\triangle ABC$,$r_1 r_2 + r_2 r_3 + r_3 r_1$ is equal to
A
$\frac{\Delta^2}{r^2}$
B
$\frac{\Delta}{r}$
C
$\frac{2 \Delta}{r}$
D
$\Delta^2$

Solution

(A) We know that the exradii are given by $r_1 = \frac{\Delta}{s-a}$,$r_2 = \frac{\Delta}{s-b}$,and $r_3 = \frac{\Delta}{s-c}$.
Substituting these into the expression $r_1 r_2 + r_2 r_3 + r_3 r_1$:
$= \frac{\Delta^2}{(s-a)(s-b)} + \frac{\Delta^2}{(s-b)(s-c)} + \frac{\Delta^2}{(s-c)(s-a)}$
$= \frac{\Delta^2(s-c + s-a + s-b)}{(s-a)(s-b)(s-c)}$
Since $2s = a+b+c$,we have $s-a+s-b+s-c = 3s - (a+b+c) = 3s - 2s = s$.
Also,we know that $\Delta^2 = s(s-a)(s-b)(s-c)$,so $(s-a)(s-b)(s-c) = \frac{\Delta^2}{s}$.
Substituting these values:
$= \frac{\Delta^2 \cdot s}{\frac{\Delta^2}{s}} = s^2$
Since $r = \frac{\Delta}{s}$,we have $s = \frac{\Delta}{r}$,so $s^2 = \frac{\Delta^2}{r^2}$.
64
ChemistryMCQAP EAMCET · 2013
If $A = \begin{bmatrix} -8 & 5 \\ 2 & 4 \end{bmatrix}$ satisfies the equation $x^2 + 4x - p = 0$,then $p$ is equal to
A
$64$
B
$42$
C
$36$
D
$24$

Solution

(B) Given the matrix $A = \begin{bmatrix} -8 & 5 \\ 2 & 4 \end{bmatrix}$.
Since $A$ satisfies the equation $x^2 + 4x - p = 0$,we have $A^2 + 4A - pI = 0$,where $I$ is the identity matrix $\begin{bmatrix} 1 & 0 \\ 0 & 1 \end{bmatrix}$.
First,calculate $A^2$:
$A^2 = \begin{bmatrix} -8 & 5 \\ 2 & 4 \end{bmatrix} \begin{bmatrix} -8 & 5 \\ 2 & 4 \end{bmatrix} = \begin{bmatrix} (-8)(-8) + (5)(2) & (-8)(5) + (5)(4) \\ (2)(-8) + (4)(2) & (2)(5) + (4)(4) \end{bmatrix} = \begin{bmatrix} 64 + 10 & -40 + 20 \\ -16 + 8 & 10 + 16 \end{bmatrix} = \begin{bmatrix} 74 & -20 \\ -8 & 26 \end{bmatrix}$.
Next,calculate $4A$:
$4A = 4 \begin{bmatrix} -8 & 5 \\ 2 & 4 \end{bmatrix} = \begin{bmatrix} -32 & 20 \\ 8 & 16 \end{bmatrix}$.
Now,substitute these into the equation $A^2 + 4A - pI = 0$:
$\begin{bmatrix} 74 & -20 \\ -8 & 26 \end{bmatrix} + \begin{bmatrix} -32 & 20 \\ 8 & 16 \end{bmatrix} - \begin{bmatrix} p & 0 \\ 0 & p \end{bmatrix} = \begin{bmatrix} 0 & 0 \\ 0 & 0 \end{bmatrix}$.
Performing the matrix addition and subtraction:
$\begin{bmatrix} 74 - 32 - p & -20 + 20 - 0 \\ -8 + 8 - 0 & 26 + 16 - p \end{bmatrix} = \begin{bmatrix} 0 & 0 \\ 0 & 0 \end{bmatrix}$.
$\begin{bmatrix} 42 - p & 0 \\ 0 & 42 - p \end{bmatrix} = \begin{bmatrix} 0 & 0 \\ 0 & 0 \end{bmatrix}$.
Comparing the elements,we get $42 - p = 0$,which implies $p = 42$.
65
ChemistryMCQAP EAMCET · 2013
If $I$ is the identity matrix of order $2$ and $A = \begin{bmatrix} 1 & 1 \\ 0 & 1 \end{bmatrix}$,then for $n \geq 1$,mathematical induction gives
A
$A^n = nA - (n-1)I$
B
$A^n = nA + (n-1)I$
C
$A^n = 2^n A - (n+1)I$
D
$A^n = 2^{n-1} A - (n-1)I$

Solution

(A) Given $A = \begin{bmatrix} 1 & 1 \\ 0 & 1 \end{bmatrix}$.
We calculate the powers of $A$:
$A^2 = \begin{bmatrix} 1 & 1 \\ 0 & 1 \end{bmatrix} \begin{bmatrix} 1 & 1 \\ 0 & 1 \end{bmatrix} = \begin{bmatrix} 1 & 2 \\ 0 & 1 \end{bmatrix}$.
$A^3 = A^2 \cdot A = \begin{bmatrix} 1 & 2 \\ 0 & 1 \end{bmatrix} \begin{bmatrix} 1 & 1 \\ 0 & 1 \end{bmatrix} = \begin{bmatrix} 1 & 3 \\ 0 & 1 \end{bmatrix}$.
By observation,$A^n = \begin{bmatrix} 1 & n \\ 0 & 1 \end{bmatrix}$.
Now,check option $A$: $nA - (n-1)I = n \begin{bmatrix} 1 & 1 \\ 0 & 1 \end{bmatrix} - (n-1) \begin{bmatrix} 1 & 0 \\ 0 & 1 \end{bmatrix}$
$= \begin{bmatrix} n & n \\ 0 & n \end{bmatrix} - \begin{bmatrix} n-1 & 0 \\ 0 & n-1 \end{bmatrix} = \begin{bmatrix} n-(n-1) & n-0 \\ 0-0 & n-(n-1) \end{bmatrix} = \begin{bmatrix} 1 & n \\ 0 & 1 \end{bmatrix} = A^n$.
Thus,the correct relation is $A^n = nA - (n-1)I$.
66
ChemistryMCQAP EAMCET · 2013
$\left|\begin{array}{ccc}x+2 & x+3 & x+5 \\ x+4 & x+6 & x+9 \\ x+8 & x+11 & x+15\end{array}\right|$ is equal to
A
$3x^2+4x+5$
B
$x^3+8x+2$
C
$0$
D
$-2$

Solution

(D) Let $\Delta = \left|\begin{array}{ccc}x+2 & x+3 & x+5 \\ x+4 & x+6 & x+9 \\ x+8 & x+11 & x+15\end{array}\right|$.
Apply operations $R_2 \rightarrow R_2 - R_1$ and $R_3 \rightarrow R_3 - R_1$:
$\Delta = \left|\begin{array}{ccc}x+2 & x+3 & x+5 \\ 2 & 3 & 4 \\ 6 & 8 & 10\end{array}\right|$.
Now,apply $C_2 \rightarrow C_2 - C_1$ and $C_3 \rightarrow C_3 - C_1$:
$\Delta = \left|\begin{array}{ccc}x+2 & 1 & 3 \\ 2 & 1 & 2 \\ 6 & 2 & 4\end{array}\right|$.
Expanding along $R_1$:
$\Delta = (x+2)(4-4) - 1(8-12) + 3(4-6)$
$\Delta = (x+2)(0) - 1(-4) + 3(-2)$
$\Delta = 0 + 4 - 6 = -2$.
67
ChemistryMCQAP EAMCET · 2013
The system of equations $3x + 2y + z = 6$,$3x + 4y + 3z = 14$ and $6x + 10y + 8z = a$ has an infinite number of solutions if $a$ is equal to
A
$8$
B
$12$
C
$24$
D
$36$

Solution

(D) The given system of equations is:
$3x + 2y + z = 6$
$3x + 4y + 3z = 14$
$6x + 10y + 8z = a$
Let $A = \begin{bmatrix} 3 & 2 & 1 \\ 3 & 4 & 3 \\ 6 & 10 & 8 \end{bmatrix}$ and $B = \begin{bmatrix} 6 \\ 14 \\ a \end{bmatrix}$.
First,we calculate the determinant of $A$:
$|A| = 3(32 - 30) - 2(24 - 18) + 1(30 - 24) = 3(2) - 2(6) + 6 = 6 - 12 + 6 = 0$.
Since $|A| = 0$,the system has either no solution or infinite solutions.
For infinite solutions,we must have $(\text{adj } A) \cdot B = 0$.
The cofactor matrix of $A$ is:
$C_{11} = 2, C_{12} = -6, C_{13} = 6$
$C_{21} = -6, C_{22} = 18, C_{23} = -18$
$C_{31} = 2, C_{32} = -6, C_{33} = 6$
Thus,$\text{adj } A = \begin{bmatrix} 2 & -6 & 2 \\ -6 & 18 & -6 \\ 6 & -18 & 6 \end{bmatrix}$.
Now,$(\text{adj } A) \cdot B = \begin{bmatrix} 2 & -6 & 2 \\ -6 & 18 & -6 \\ 6 & -18 & 6 \end{bmatrix} \begin{bmatrix} 6 \\ 14 \\ a \end{bmatrix} = \begin{bmatrix} 12 - 84 + 2a \\ -36 + 252 - 6a \\ 36 - 252 + 6a \end{bmatrix} = \begin{bmatrix} 2a - 72 \\ 216 - 6a \\ 6a - 216 \end{bmatrix}$.
Setting this to zero vector,we get $2a - 72 = 0$,which implies $a = 36$.
68
ChemistryMCQAP EAMCET · 2013
If $\cos ^{-1}\left(\frac{5}{13}\right)+\cos ^{-1}\left(\frac{3}{5}\right)=\cos ^{-1} x$,then $x$ is equal to
A
$\frac{3}{65}$
B
$\frac{-36}{65}$
C
$\frac{-33}{65}$
D
$-1$

Solution

(C) We use the formula $\cos ^{-1} A + \cos ^{-1} B = \cos ^{-1} (AB - \sqrt{1-A^2} \sqrt{1-B^2})$.
Given $\cos ^{-1}\left(\frac{5}{13}\right)+\cos ^{-1}\left(\frac{3}{5}\right)=\cos ^{-1} x$.
Here $A = \frac{5}{13}$ and $B = \frac{3}{5}$.
Then $\sqrt{1-A^2} = \sqrt{1-\left(\frac{5}{13}\right)^2} = \sqrt{1-\frac{25}{169}} = \sqrt{\frac{144}{169}} = \frac{12}{13}$.
And $\sqrt{1-B^2} = \sqrt{1-\left(\frac{3}{5}\right)^2} = \sqrt{1-\frac{9}{25}} = \sqrt{\frac{16}{25}} = \frac{4}{5}$.
Substituting these values into the formula:
$\cos ^{-1} x = \cos ^{-1} \left( \frac{5}{13} \cdot \frac{3}{5} - \frac{12}{13} \cdot \frac{4}{5} \right)$.
$\cos ^{-1} x = \cos ^{-1} \left( \frac{15}{65} - \frac{48}{65} \right)$.
$\cos ^{-1} x = \cos ^{-1} \left( \frac{-33}{65} \right)$.
Therefore,$x = \frac{-33}{65}$.
69
ChemistryMCQAP EAMCET · 2013
$\tanh ^{-1}\left(\frac{1}{2}\right)+\operatorname{coth}^{-1}(2)$ is equal to
A
$\frac{1}{2} \log 3$
B
$\frac{1}{2} \log 6$
C
$\frac{1}{2} \log 12$
D
$\log 3$

Solution

(D) We know that $\operatorname{coth}^{-1}(x) = \tanh^{-1}\left(\frac{1}{x}\right)$ for $|x| > 1$.
Therefore,$\operatorname{coth}^{-1}(2) = \tanh^{-1}\left(\frac{1}{2}\right)$.
Substituting this into the expression,we get:
$\tanh ^{-1}\left(\frac{1}{2}\right)+\operatorname{coth}^{-1}(2) = \tanh ^{-1}\left(\frac{1}{2}\right)+\tanh ^{-1}\left(\frac{1}{2}\right) = 2 \tanh ^{-1}\left(\frac{1}{2}\right)$.
Using the formula $\tanh ^{-1}(x) = \frac{1}{2} \log \left(\frac{1+x}{1-x}\right)$,we have:
$2 \tanh ^{-1}\left(\frac{1}{2}\right) = 2 \cdot \frac{1}{2} \log \left(\frac{1+\frac{1}{2}}{1-\frac{1}{2}}\right)$.
$= \log \left(\frac{\frac{3}{2}}{\frac{1}{2}}\right) = \log 3$.
70
ChemistryMCQAP EAMCET · 2013
The value of $\{x \in R \mid \log_{10} ((1.6)^{1-x^2} - (0.625)^{6(1+x)}) \in R\}$ is
A
$(-\infty, -1) \cup (7, \infty)$
B
$(-1, 5)$
C
$(1, 7)$
D
$(-1, 7)$

Solution

(D) For the expression $\log_{10} ((1.6)^{1-x^2} - (0.625)^{6(1+x)})$ to be defined in $R$,the argument of the logarithm must be strictly greater than $0$.
$(1.6)^{1-x^2} - (0.625)^{6(1+x)} > 0$
$(1.6)^{1-x^2} > (0.625)^{6(1+x)}$
Since $1.6 = \frac{8}{5}$ and $0.625 = \frac{5}{8} = (\frac{8}{5})^{-1}$,we have:
$(\frac{8}{5})^{1-x^2} > ((\frac{8}{5})^{-1})^{6(1+x)}$
$(\frac{8}{5})^{1-x^2} > (\frac{8}{5})^{-6(1+x)}$
Since the base $\frac{8}{5} > 1$,the inequality direction remains the same:
$1 - x^2 > -6(1 + x)$
$1 - x^2 > -6 - 6x$
$x^2 - 6x - 7 < 0$
$(x - 7)(x + 1) < 0$
Thus,$x \in (-1, 7)$.
71
ChemistryMCQAP EAMCET · 2013
The period of $f(x)=\cos \left(\frac{x}{3}\right)+\sin \left(\frac{x}{2}\right)$ is (in $pi$)
A
$2$
B
$4$
C
$8$
D
$12$

Solution

(D) Given,$f(x)=\cos \left(\frac{x}{3}\right)+\sin \left(\frac{x}{2}\right)$.
We know that the period of $\cos(ax)$ and $\sin(ax)$ is $\frac{2\pi}{|a|}$.
For the term $\cos \left(\frac{x}{3}\right)$,the period $T_1 = \frac{2\pi}{1/3} = 6\pi$.
For the term $\sin \left(\frac{x}{2}\right)$,the period $T_2 = \frac{2\pi}{1/2} = 4\pi$.
The period of the sum of two periodic functions is the Least Common Multiple $(LCM)$ of their individual periods.
Therefore,the period of $f(x) = \text{LCM}(6\pi, 4\pi)$.
Since $6\pi = 2 \times 3\pi$ and $4\pi = 2 \times 2\pi$,the $\text{LCM}(6\pi, 4\pi) = 12\pi$.
Thus,the period of $f(x)$ is $12\pi$.
72
ChemistryMCQAP EAMCET · 2013
If $f(x) = (p - x^n)^{1/n}$,$p > 0$ and $n$ is a positive integer,then $f[f(x)]$ is equal to
A
$x$
B
$x^n$
C
$p^{1/n}$
D
$p - x^n$

Solution

(A) Given,$f(x) = (p - x^n)^{1/n}$,where $p > 0$.
To find $f[f(x)]$,we substitute $f(x)$ into the function $f$:
$f[f(x)] = f((p - x^n)^{1/n})$
$= (p - ((p - x^n)^{1/n})^n)^{1/n}$
$= (p - (p - x^n))^{1/n}$
$= (p - p + x^n)^{1/n}$
$= (x^n)^{1/n}$
$= x$
73
ChemistryMCQAP EAMCET · 2013
Let $f$ be a non-zero real-valued continuous function satisfying $f(x+y)=f(x) \cdot f(y)$ for all $x, y \in R$. If $f(2)=9$,then $f(6)$ is equal to
A
$3^2$
B
$3^6$
C
$3^4$
D
$3^3$

Solution

(B) Given the functional equation $f(x+y)=f(x) \cdot f(y)$ for all $x, y \in R$.
We know that the continuous function satisfying this property is of the form $f(x) = a^x$.
Given $f(2) = 9$,we have $a^2 = 9$.
Since $f$ is a non-zero function,$a^2 = 3^2$,which implies $a = 3$ (as $a$ must be positive for $f(x) = a^x$ to be defined for all real $x$).
Thus,$f(x) = 3^x$.
Now,we need to find $f(6)$.
$f(6) = 3^6$.
74
ChemistryMCQAP EAMCET · 2013
If $f(x) = \frac{1}{1+\frac{1}{x}}$ and $g(x) = \frac{1}{1+\frac{1}{f(x)}}$,then $g^{\prime}(2)$ is equal to
A
$\frac{1}{5}$
B
$\frac{1}{25}$
C
$5$
D
$\frac{1}{16}$

Solution

(B) Given $f(x) = \frac{1}{1+\frac{1}{x}} = \frac{x}{x+1}$.
Then $g(x) = \frac{1}{1+\frac{1}{f(x)}} = \frac{1}{1+\frac{x+1}{x}} = \frac{1}{\frac{x+x+1}{x}} = \frac{x}{2x+1}$.
To find $g^{\prime}(x)$,we use the quotient rule: $\frac{d}{dx} \left( \frac{u}{v} \right) = \frac{v u^{\prime} - u v^{\prime}}{v^2}$.
$g^{\prime}(x) = \frac{(2x+1)(1) - x(2)}{(2x+1)^2} = \frac{2x+1-2x}{(2x+1)^2} = \frac{1}{(2x+1)^2}$.
Substituting $x = 2$,we get $g^{\prime}(2) = \frac{1}{(2(2)+1)^2} = \frac{1}{5^2} = \frac{1}{25}$.
75
ChemistryMCQAP EAMCET · 2013
If $\sqrt{\frac{y}{x}}+\sqrt{\frac{x}{y}}=2$,then $\frac{d y}{d x}$ is equal to
A
$\frac{x^2+y^2}{x+y}$
B
$\frac{x^2-y^2}{x+y}$
C
$1$
D
$2$

Solution

(C) Given the equation: $\sqrt{\frac{y}{x}}+\sqrt{\frac{x}{y}}=2$
Multiplying by $\sqrt{xy}$,we get: $y+x=2\sqrt{xy}$
Squaring both sides: $(x+y)^2 = (2\sqrt{xy})^2$
$x^2+y^2+2xy = 4xy$
$x^2+y^2-2xy = 0$
$(x-y)^2 = 0$
This implies $x-y=0$,or $y=x$
Differentiating both sides with respect to $x$: $\frac{dy}{dx} = \frac{d}{dx}(x) = 1$
76
ChemistryMCQAP EAMCET · 2013
If $\frac{d}{d x}\left[(x+1)\left(x^2+1\right)\left(x^4+1\right)\left(x^8+1\right)\right] = \left(15 x^p-16 x^q+1\right)(x-1)^{-2}$,then $(p, q)$ is equal to
A
$(12, 11)$
B
$(15, 14)$
C
$(16, 14)$
D
$(16, 15)$

Solution

(D) Let $f(x) = (x+1)(x^2+1)(x^4+1)(x^8+1)$.
Multiply and divide by $(x-1)$:
$f(x) = \frac{(x-1)(x+1)(x^2+1)(x^4+1)(x^8+1)}{(x-1)} = \frac{(x^2-1)(x^2+1)(x^4+1)(x^8+1)}{(x-1)} = \frac{(x^4-1)(x^4+1)(x^8+1)}{(x-1)} = \frac{(x^8-1)(x^8+1)}{(x-1)} = \frac{x^{16}-1}{x-1}$.
Now,differentiate $f(x)$ with respect to $x$ using the quotient rule:
$\frac{d}{dx} \left[ \frac{x^{16}-1}{x-1} \right] = \frac{(x-1)(16x^{15}) - (x^{16}-1)(1)}{(x-1)^2} = \frac{16x^{16} - 16x^{15} - x^{16} + 1}{(x-1)^2} = \frac{15x^{16} - 16x^{15} + 1}{(x-1)^2}$.
Comparing this with the given expression $\left(15 x^p-16 x^q+1\right)(x-1)^{-2}$,we get $p=16$ and $q=15$.
Therefore,$(p, q) = (16, 15)$.
77
ChemistryMCQAP EAMCET · 2013
The relation between pressure $p$ and volume $V$ is given by $p V^{1/4} = \text{constant}$. If the percentage decrease in volume is $\frac{1}{2} \%$,then the percentage increase in pressure is:
A
$\frac{1}{8} \%$
B
$\frac{1}{16} \%$
C
$\frac{1}{4} \%$
D
$\frac{1}{2} \%$

Solution

(A) Given the relation $p V^{1/4} = C$,where $C$ is a constant.
Taking the natural logarithm on both sides: $\ln p + \frac{1}{4} \ln V = \ln C$.
Differentiating both sides with respect to $V$: $\frac{1}{p} \frac{dp}{dV} + \frac{1}{4V} = 0$.
This gives $\frac{dp}{p} = -\frac{1}{4} \frac{dV}{V}$.
We are given that the percentage decrease in volume is $\frac{dV}{V} \times 100 = -\frac{1}{2} \%$.
Substituting this into the differential relation: $\frac{dp}{p} \times 100 = -\frac{1}{4} \left( \frac{dV}{V} \times 100 \right)$.
$\frac{dp}{p} \times 100 = -\frac{1}{4} \left( -\frac{1}{2} \% \right) = \frac{1}{8} \%$.
Thus,the percentage increase in pressure is $\frac{1}{8} \%$.
78
ChemistryMCQAP EAMCET · 2013
The focal length of a mirror is given by $\frac{2}{f} = \frac{1}{v} - \frac{1}{u}$. In finding the values of $u$ and $v$,the errors are equal to $p$. Then,the relative error in $f$ is
A
$\frac{p}{2}\left(\frac{1}{u} + \frac{1}{v}\right)$
B
$p\left(\frac{1}{u} + \frac{1}{v}\right)$
C
$\frac{p}{2}\left(\frac{1}{u} - \frac{1}{v}\right)$
D
$p\left(\frac{1}{u} - \frac{1}{v}\right)$

Solution

(B) Given the equation: $\frac{2}{f} = \frac{1}{v} - \frac{1}{u}$ $(i)$
Taking the differential of both sides:
$-\frac{2}{f^2} df = -\frac{1}{v^2} dv + \frac{1}{u^2} du$
Given that the errors in $u$ and $v$ are $p$,we have $dv = p$ and $du = p$.
Substituting these into the differential equation:
$-\frac{2}{f^2} df = -\frac{1}{v^2} p + \frac{1}{u^2} p$
$-\frac{2}{f^2} df = p \left( \frac{1}{u^2} - \frac{1}{v^2} \right)$
Using the identity $a^2 - b^2 = (a - b)(a + b)$:
$-\frac{2}{f^2} df = p \left( \frac{1}{u} - \frac{1}{v} \right) \left( \frac{1}{u} + \frac{1}{v} \right)$
From equation $(i)$,$\frac{1}{u} - \frac{1}{v} = -\frac{2}{f}$. Substituting this:
$-\frac{2}{f^2} df = p \left( -\frac{2}{f} \right) \left( \frac{1}{u} + \frac{1}{v} \right)$
Dividing both sides by $-\frac{2}{f}$:
$\frac{df}{f} = p \left( \frac{1}{u} + \frac{1}{v} \right)$
Thus,the relative error in $f$ is $p \left( \frac{1}{u} + \frac{1}{v} \right)$.
79
ChemistryMCQAP EAMCET · 2013
$A$ person observes the top of a tower from a point $A$ on the ground. The angle of elevation of the tower from this point is $60^{\circ}$. He moves $60 \ m$ in the direction perpendicular to the line joining $A$ and the base of the tower. The angle of elevation of the tower from this new point is $45^{\circ}$. Then,the height of the tower (in metres) is
A
$60 \sqrt{\frac{3}{2}}$
B
$60 \sqrt{2}$
C
$60 \sqrt{3}$
D
$30 \sqrt{6}$

Solution

(D) Let the height of the tower be $h$ and the distance of point $A$ from the base of the tower $(B)$ be $x$.
In $\triangle ABD$,$\tan 60^{\circ} = \frac{h}{x}$ $\Rightarrow h = x \sqrt{3}$ $\Rightarrow x = \frac{h}{\sqrt{3}}$.
The person moves $60 \ m$ perpendicular to $AB$ to reach point $C$. Thus,$AC = 60 \ m$ and $\angle CAB = 90^{\circ}$.
In $\triangle ABC$,the distance from $C$ to the base $B$ is $CB = \sqrt{AC^2 + AB^2} = \sqrt{60^2 + x^2}$.
In $\triangle CBD$,the angle of elevation is $45^{\circ}$,so $\tan 45^{\circ} = \frac{h}{CB} = 1$.
Therefore,$h = CB = \sqrt{3600 + x^2} \Rightarrow h^2 = 3600 + x^2$.
Substituting $x^2 = \frac{h^2}{3}$ into the equation: $h^2 = 3600 + \frac{h^2}{3}$.
$\frac{2h^2}{3} = 3600 \Rightarrow h^2 = 1800 \times 3 = 5400$.
$h = \sqrt{5400} = \sqrt{900 \times 6} = 30 \sqrt{6} \ m$.
Solution diagram
80
ChemistryMCQAP EAMCET · 2013
If $\int \frac{d x}{x(\log x-2)(\log x-3)}=I+C$,then $I$ is equal to
A
$\frac{1}{x} \log \left|\frac{\log x-3}{\log x-2}\right|$
B
$\log \left|\frac{\log x-3}{\log x-2}\right|$
C
$\log \left|\frac{\log x-2}{\log x-3}\right|$
D
$\log |(\log x-3)(\log x-2)|$

Solution

(B) Let $I_1 = \int \frac{d x}{x(\log x-2)(\log x-3)}$.
Substitute $t = \log x$,then $d t = \frac{1}{x} d x$.
The integral becomes $I_1 = \int \frac{d t}{(t-2)(t-3)}$.
Using partial fractions,$\frac{1}{(t-2)(t-3)} = \frac{A}{t-2} + \frac{B}{t-3}$.
$1 = A(t-3) + B(t-2)$.
For $t=3$,$B=1$. For $t=2$,$A=-1$.
So,$I_1 = \int \left( \frac{1}{t-3} - \frac{1}{t-2} \right) d t$.
$I_1 = \log |t-3| - \log |t-2| + C = \log \left| \frac{t-3}{t-2} \right| + C$.
Substituting $t = \log x$ back,we get $I = \log \left| \frac{\log x - 3}{\log x - 2} \right|$.
81
ChemistryMCQAP EAMCET · 2013
$\int e^x \left( \frac{2+\sin 2x}{1+\cos 2x} \right) dx$ is equal to
A
$e^x \cot x + C$
B
$2 e^x \sec^2 x + C$
C
$e^x \cos 2x + C$
D
$e^x \tan x + C$

Solution

(D) Let $I = \int e^x \left( \frac{2+\sin 2x}{1+\cos 2x} \right) dx$.
Using the trigonometric identities $1+\cos 2x = 2\cos^2 x$ and $\sin 2x = 2\sin x \cos x$,we get:
$I = \int e^x \left( \frac{2 + 2\sin x \cos x}{2\cos^2 x} \right) dx$
$I = \int e^x \left( \frac{2}{2\cos^2 x} + \frac{2\sin x \cos x}{2\cos^2 x} \right) dx$
$I = \int e^x (\sec^2 x + \tan x) dx$.
We know the standard integral form $\int e^x (f(x) + f'(x)) dx = e^x f(x) + C$.
Here,let $f(x) = \tan x$,then $f'(x) = \sec^2 x$.
Therefore,$I = e^x \tan x + C$.
82
ChemistryMCQAP EAMCET · 2013
The approximate value of $\int_1^3 \frac{dx}{2+3x}$ using Simpson's rule and dividing the interval $[1, 3]$ into two equal parts is
A
$\frac{1}{3} \log \left(\frac{11}{5}\right)$
B
$\frac{107}{110}$
C
$\frac{29}{110}$
D
$\frac{119}{440}$

Solution

(C) Given the integral $I = \int_1^3 \frac{dx}{2+3x}$. Here,$n = 2$ and the interval $[1, 3]$ is divided into $n=2$ equal parts.
The step size $h = \frac{b-a}{n} = \frac{3-1}{2} = 1$.
The values of $x$ are $x_0 = 1, x_1 = 2, x_2 = 3$.
The corresponding values of $y = f(x) = \frac{1}{2+3x}$ are:
$y_0 = f(1) = \frac{1}{2+3(1)} = \frac{1}{5} = 0.2$
$y_1 = f(2) = \frac{1}{2+3(2)} = \frac{1}{8} = 0.125$
$y_2 = f(3) = \frac{1}{2+3(3)} = \frac{1}{11} \approx 0.0909$
According to Simpson's rule: $\int_a^b f(x) dx \approx \frac{h}{3} [y_0 + 4y_1 + y_2]$.
Substituting the values: $I \approx \frac{1}{3} [0.2 + 4(0.125) + 0.0909] = \frac{1}{3} [0.2 + 0.5 + 0.0909] = \frac{0.7909}{3} \approx 0.2636$.
Comparing with the options,$\frac{29}{110} \approx 0.2636$. Thus,the correct option is $C$.
83
ChemistryMCQAP EAMCET · 2013
The two surfaces of a concave lens,made of glass of refractive index $1.5$,have the same radii of curvature $R$. It is now immersed in a medium of refractive index $1.75$. Then the lens:
A
becomes a convergent lens of focal length $3.5 R$
B
becomes a convergent lens of focal length $3.0 R$
C
changes as a divergent lens of focal length $3.5 R$
D
changes as a divergent lens of focal length $3.0 R$

Solution

(A) From the lens maker's formula:
$\frac{1}{f} = \left( \frac{\mu_g}{\mu_m} - 1 \right) \left( \frac{1}{R_1} - \frac{1}{R_2} \right)$
Given that the refractive index of the glass lens is $\mu_g = 1.5$ and the refractive index of the medium is $\mu_m = 1.75$.
For a concave lens,the radii of curvature are $R_1 = -R$ and $R_2 = +R$.
Substituting these values into the formula:
$\frac{1}{f} = \left( \frac{1.5}{1.75} - 1 \right) \left( \frac{1}{-R} - \frac{1}{R} \right)$
$\frac{1}{f} = \left( \frac{1.5 - 1.75}{1.75} \right) \left( -\frac{2}{R} \right)$
$\frac{1}{f} = \left( \frac{-0.25}{1.75} \right) \left( -\frac{2}{R} \right)$
$\frac{1}{f} = \left( -\frac{1}{7} \right) \left( -\frac{2}{R} \right) = \frac{2}{7R}$
$f = +3.5 R$
The positive sign of the focal length indicates that the lens behaves as a convergent lens.
Solution diagram
84
ChemistryMCQAP EAMCET · 2013
$A$ microscope consists of an objective of focal length $1.9 \ cm$ and an eyepiece of focal length $5 \ cm$. The two lenses are kept at a distance of $10.5 \ cm$. If the image is to be formed at the least distance of distinct vision $(25 \ cm)$,the distance at which the object is to be placed before the objective is: (in $cm$)
A
$6.2$
B
$2.7$
C
$21.0$
D
$4.17$

Solution

(B) For the eyepiece,the image distance $v_e = -25 \ cm$ and focal length $f_e = 5 \ cm$. Using the lens formula $\frac{1}{v_e} - \frac{1}{u_e} = \frac{1}{f_e}$:
$\frac{1}{-25} - \frac{1}{u_e} = \frac{1}{5} \Rightarrow \frac{1}{u_e} = -\frac{1}{25} - \frac{1}{5} = -\frac{6}{25} \Rightarrow u_e = -\frac{25}{6} \ cm$.
The distance of the image formed by the objective from the objective is $v_0 = L - |u_e| = 10.5 - \frac{25}{6} = \frac{63-25}{6} = \frac{38}{6} \ cm$.
For the objective,$f_0 = 1.9 \ cm$ and $v_0 = \frac{38}{6} \ cm$. Using the lens formula $\frac{1}{v_0} - \frac{1}{u_0} = \frac{1}{f_0}$:
$\frac{1}{38/6} - \frac{1}{u_0} = \frac{1}{1.9} \Rightarrow \frac{6}{38} - \frac{1}{u_0} = \frac{10}{19} \Rightarrow \frac{3}{19} - \frac{10}{19} = \frac{1}{u_0}$.
$\frac{1}{u_0} = -\frac{7}{19} \Rightarrow u_0 = -\frac{19}{7} \approx -2.71 \ cm$.
Thus,the object should be placed at a distance of $2.7 \ cm$ from the objective.
85
ChemistryMCQAP EAMCET · 2013
Which one of the following is an example of a disproportionation reaction?
A
$3Cl_{2\text{(g)}} + 6OH^-{_{\text{(aq)}}} \rightarrow ClO_3^-{_{\text{(aq)}}} + 5Cl^-{_{\text{(aq)}}} + 3H_2O_{\text{(l)}}$
B
$Ag^{2+}_{(aq)} + Ag_{(s)} \longrightarrow 2 Ag^{+}_{(aq)}$
C
$Zn_{(s)} + CuSO_{4(aq)} \longrightarrow Cu_{(s)} + ZnSO_{4(aq)}$
D
$2 KClO_{3(s)} \longrightarrow 2 KCl_{(s)} + 3 O_{2(g)}$

Solution

(A) disproportionation reaction is a special type of redox reaction in which the same element in a given oxidation state is simultaneously oxidized and reduced.
In the reaction $3Cl_{2\text{(g)}} + 6OH^-{_{\text{(aq)}}} \rightarrow ClO_3^-{_{\text{(aq)}}} + 5Cl^-{_{\text{(aq)}}} + 3H_2O_{\text{(l)}}$,the oxidation state of chlorine changes from $0$ in $Cl_2$ to $-1$ in $Cl^-$ (reduction) and to $+5$ in $ClO_3^-$ (oxidation). Thus,it is a disproportionation reaction.
86
ChemistryMCQAP EAMCET · 2013
Heating chloroform with aqueous sodium hydroxide solution forms
A
sodium acetate
B
sodium oxalate
C
sodium formate
D
chloral

Solution

(C) When chloroform $(CHCl_3)$ is heated with aqueous sodium hydroxide $(NaOH)$,it undergoes hydrolysis to form an unstable intermediate,methanetriol $(HC(OH)_3)$.
This intermediate loses a water molecule to form formic acid $(HCOOH)$.
Formic acid then reacts with the remaining $NaOH$ to produce sodium formate $(HCOONa)$.
The overall reaction is: $CHCl_3 + 4NaOH \rightarrow HCOONa + 3NaCl + 2H_2O$.
87
ChemistryMCQAP EAMCET · 2013
The base current in a transistor circuit changes from $45 \mu A$ to $140 \mu A$. Accordingly,the collector current changes from $0.2 \text{ mA}$ to $4.0 \text{ mA}$. The current gain is
A
$9.5$
B
$1$
C
$40$
D
$20$

Solution

(C) The current gain $\beta$ of a transistor is defined as the ratio of the change in collector current to the change in base current: $\beta = \frac{\Delta I_C}{\Delta I_B}$.
Given:
Change in base current $\Delta I_B = 140 \mu A - 45 \mu A = 95 \mu A = 95 \times 10^{-6} \text{ A}$.
Change in collector current $\Delta I_C = 4.0 \text{ mA} - 0.2 \text{ mA} = 3.8 \text{ mA} = 3.8 \times 10^{-3} \text{ A}$.
Substituting these values into the formula:
$\beta = \frac{3.8 \times 10^{-3}}{95 \times 10^{-6}} = \frac{3800 \times 10^{-6}}{95 \times 10^{-6}} = 40$.
Therefore,the current gain is $40$.
88
ChemistryMCQAP EAMCET · 2013
The points whose position vectors are $2i+3j+4k$,$3i+4j+2k$,and $4i+2j+3k$ are the vertices of
A
an isosceles triangle
B
a right-angled triangle
C
an equilateral triangle
D
a right-angled isosceles triangle

Solution

(C) Let the position vectors of the vertices be $\vec{a} = 2i+3j+4k$,$\vec{b} = 3i+4j+2k$,and $\vec{c} = 4i+2j+3k$.
The side vectors are:
$\vec{AB} = \vec{b} - \vec{a} = (3-2)i + (4-3)j + (2-4)k = i + j - 2k$.
$\vec{BC} = \vec{c} - \vec{b} = (4-3)i + (2-4)j + (3-2)k = i - 2j + k$.
$\vec{CA} = \vec{a} - \vec{c} = (2-4)i + (3-2)j + (4-3)k = -2i + j + k$.
The lengths of the sides are:
$|\vec{AB}| = \sqrt{1^2 + 1^2 + (-2)^2} = \sqrt{1+1+4} = \sqrt{6}$.
$|\vec{BC}| = \sqrt{1^2 + (-2)^2 + 1^2} = \sqrt{1+4+1} = \sqrt{6}$.
$|\vec{CA}| = \sqrt{(-2)^2 + 1^2 + 1^2} = \sqrt{4+1+1} = \sqrt{6}$.
Since $|\vec{AB}| = |\vec{BC}| = |\vec{CA}| = \sqrt{6}$,all three sides are equal in length.
Therefore,the triangle is an equilateral triangle.
89
ChemistryMCQAP EAMCET · 2013
The direction ratios of the two lines $AB$ and $AC$ are $1, -1, -1$ and $2, -1, 1$. The direction ratios of the normal to the plane $ABC$ are
A
$2, 3, -1$
B
$2, 2, 1$
C
$3, 2, -1$
D
$-1, 2, 3$

Solution

(A) Let the direction ratios of the two lines $AB$ and $AC$ be $\vec{v_1} = \langle 1, -1, -1 \rangle$ and $\vec{v_2} = \langle 2, -1, 1 \rangle$ respectively.
Since the lines $AB$ and $AC$ lie in the plane $ABC$,the normal vector $\vec{n}$ to the plane is given by the cross product of the vectors along these lines:
$\vec{n} = \vec{v_1} \times \vec{v_2} = \begin{vmatrix} \hat{i} & \hat{j} & \hat{k} \\ 1 & -1 & -1 \\ 2 & -1 & 1 \end{vmatrix}$
$\vec{n} = \hat{i}(-1 - 1) - \hat{j}(1 - (-2)) + \hat{k}(-1 - (-2))$
$\vec{n} = \hat{i}(-2) - \hat{j}(3) + \hat{k}(1)$
$\vec{n} = -2\hat{i} - 3\hat{j} + \hat{k}$
Thus,the direction ratios of the normal are $\langle -2, -3, 1 \rangle$. Multiplying by $-1$,we get $\langle 2, 3, -1 \rangle$.
Therefore,the correct option is $A$.
Solution diagram
90
ChemistryMCQAP EAMCET · 2013
$A$ plane passing through $(-1, 2, 3)$ and whose normal makes equal angles with the coordinate axes is
A
$x+y+z+4=0$
B
$x-y+z+4=0$
C
$x+y+z-4=0$
D
$x+y+z=0$

Solution

(C) The equation of a plane passing through the point $(x_0, y_0, z_0)$ with normal vector $\vec{n} = \langle a, b, c \rangle$ is given by $a(x-x_0) + b(y-y_0) + c(z-z_0) = 0$.
Given the point is $(-1, 2, 3)$,the equation is $a(x+1) + b(y-2) + c(z-3) = 0$.
The normal makes equal angles $\alpha$ with the coordinate axes,so the direction cosines are $\cos \alpha, \cos \alpha, \cos \alpha$.
Since $\cos^2 \alpha + \cos^2 \alpha + \cos^2 \alpha = 1$,we have $3 \cos^2 \alpha = 1$,which implies $\cos \alpha = \pm \frac{1}{\sqrt{3}}$.
Thus,the direction ratios $\langle a, b, c \rangle$ can be taken as $\langle 1, 1, 1 \rangle$.
Substituting these into the plane equation: $1(x+1) + 1(y-2) + 1(z-3) = 0$.
Simplifying,we get $x + 1 + y - 2 + z - 3 = 0$,which results in $x + y + z - 4 = 0$.
91
ChemistryMCQAP EAMCET · 2013
$A$ variable plane passes through a fixed point $(1, 2, 3)$. The foot of the perpendicular from the origin to the plane lies on:
A
a circle
B
a sphere
C
an ellipse
D
a parabola

Solution

(B) Let the equation of the variable plane be $a(x - 1) + b(y - 2) + c(z - 3) = 0$,where $(a, b, c)$ are the direction ratios of the normal to the plane.
Let $P(x_0, y_0, z_0)$ be the foot of the perpendicular from the origin $(0, 0, 0)$ to the plane.
The vector $\vec{OP} = (x_0, y_0, z_0)$ is perpendicular to the plane,so it is parallel to the normal vector $(a, b, c)$.
Thus,we can write $(a, b, c) = k(x_0, y_0, z_0)$ for some constant $k$.
Since $P$ lies on the plane,it satisfies the equation: $x_0(x_0 - 1) + y_0(y_0 - 2) + z_0(z_0 - 3) = 0$.
This simplifies to $x_0^2 - x_0 + y_0^2 - 2y_0 + z_0^2 - 3z_0 = 0$.
Rearranging the terms,we get $(x_0^2 - x_0 + \frac{1}{4}) + (y_0^2 - 2y_0 + 1) + (z_0^2 - 3z_0 + \frac{9}{4}) = \frac{1}{4} + 1 + \frac{9}{4} = \frac{14}{4} = 3.5$.
This is the equation of a sphere with center $(\frac{1}{2}, 1, \frac{3}{2})$ and radius $\sqrt{3.5}$.
92
ChemistryMCQAP EAMCET · 2013
Two numbers are chosen at random from $\{1, 2, 3, 4, 5, 6, 7, 8\}$ at a time. The probability that the smaller of the two numbers is less than $4$ is
A
$\frac{7}{14}$
B
$\frac{8}{14}$
C
$\frac{9}{14}$
D
$\frac{10}{14}$

Solution

(C) Total number of ways to choose $2$ numbers from $8$ is ${}^8C_2 = \frac{8 \times 7}{2} = 28$.
Let the two numbers be $x$ and $y$ such that $x < y$. We want the smaller number $x$ to be less than $4$,i.e.,$x \in \{1, 2, 3\}$.
Case $I$: If $x = 1$,then $y$ can be any of the remaining $7$ numbers $\{2, 3, 4, 5, 6, 7, 8\}$. Number of ways $= 7$.
Case $II$: If $x = 2$,then $y$ can be any of the remaining $6$ numbers $\{3, 4, 5, 6, 7, 8\}$. Number of ways $= 6$.
Case $III$: If $x = 3$,then $y$ can be any of the remaining $5$ numbers $\{4, 5, 6, 7, 8\}$. Number of ways $= 5$.
Total favorable cases $= 7 + 6 + 5 = 18$.
Required probability $= \frac{18}{28} = \frac{9}{14}$.
93
ChemistryMCQAP EAMCET · 2013
Two fair dice are rolled. The probability of the sum of digits on their faces being greater than or equal to $10$ is
A
$\frac{1}{5}$
B
$\frac{1}{4}$
C
$\frac{1}{8}$
D
$\frac{1}{6}$

Solution

(D) Total sample points,$n(S) = 6 \times 6 = 36$.
Favourable events for sum $\ge 10$ are:
$E = [(4,6), (5,5), (5,6), (6,4), (6,5), (6,6)]$.
Total number of favourable events,$n(E) = 6$.
Required probability $P(E) = \frac{n(E)}{n(S)} = \frac{6}{36} = \frac{1}{6}$.
94
ChemistryMCQAP EAMCET · 2013
$A$ bag contains $2n+1$ coins. It is known that $n$ of these coins have a head on both sides,whereas the remaining $n+1$ coins are fair. $A$ coin is picked up at random from the bag and tossed. If the probability that the toss results in a head is $\frac{31}{42}$,then $n$ is equal to
A
$10$
B
$11$
C
$12$
D
$13$

Solution

(A) Let $H$ be the event that the toss results in a head. The bag contains $2n+1$ coins in total.
There are $n$ coins with heads on both sides (biased) and $n+1$ fair coins.
The probability of picking a biased coin is $P(B) = \frac{n}{2n+1}$ and the probability of picking a fair coin is $P(F) = \frac{n+1}{2n+1}$.
If a biased coin is picked,the probability of getting a head is $1$.
If a fair coin is picked,the probability of getting a head is $\frac{1}{2}$.
Using the law of total probability:
$P(H) = P(H|B)P(B) + P(H|F)P(F)$
$\frac{31}{42} = (1) \times \frac{n}{2n+1} + \left(\frac{1}{2}\right) \times \frac{n+1}{2n+1}$
$\frac{31}{42} = \frac{2n + n + 1}{2(2n+1)} = \frac{3n+1}{4n+2}$
$31(4n+2) = 42(3n+1)$
$124n + 62 = 126n + 42$
$20 = 2n$
$n = 10$
95
ChemistryMCQAP EAMCET · 2013
The number of octahedral and tetrahedral holes respectively present in a hexagonal close packed $(hcp)$ crystal of '$X$' atoms are
A
$X, 2X$
B
$X, X$
C
$2X, X$
D
$2X, 2X$

Solution

(A) In a close packed structure ($hcp$ or $ccp$):
$(i)$ The number of octahedral voids is equal to the number of particles $(N)$ present in the close packing.
(ii) The number of tetrahedral voids is equal to $2 \times N$,where $N$ is the number of particles.
Given that there are '$X$' atoms,the number of octahedral voids is '$X$' and the number of tetrahedral voids is '$2X$'.
Therefore,the correct option is $A$.
96
ChemistryMCQAP EAMCET · 2013
The vapour pressure in $mm$ of $Hg$,of an aqueous solution obtained by adding $18 \ g$ of glucose $(C_6H_{12}O_6)$ to $180 \ g$ of water at $100^{\circ} C$ is
A
$7.60$
B
$76.0$
C
$759$
D
$752.4$

Solution

(D) According to Raoult's law,the relative lowering of vapour pressure is given by: $\frac{p^{\circ} - p_s}{p^{\circ}} = \frac{n_2}{n_1 + n_2}$
where,$p^{\circ} = \text{vapour pressure of pure water at } 100^{\circ} C = 760 \ mmHg$.
$p_s = \text{vapour pressure of solution at } 100^{\circ} C$.
$n_2 = \text{moles of glucose} = \frac{18}{180} = 0.1 \ mol$.
$n_1 = \text{moles of water} = \frac{180}{18} = 10 \ mol$.
Substituting these values: $\frac{760 - p_s}{760} = \frac{0.1}{10 + 0.1} = \frac{0.1}{10.1}$.
$760 - p_s = 760 \times \frac{0.1}{10.1} = \frac{76}{10.1} \approx 7.524 \ mmHg$.
$p_s = 760 - 7.524 = 752.476 \ mmHg \approx 752.4 \ mmHg$.
97
ChemistryMCQAP EAMCET · 2013
The degree of ionization of $0.10 \ M$ lactic acid is $4.0 \ \%$. The value of $K_a$ is
Question diagram
A
$1.66 \times 10^{-5}$
B
$1.66 \times 10^{-4}$
C
$1.66 \times 10^{-3}$
D
$1.66 \times 10^{-2}$

Solution

(B) Given: Concentration $(C) = 0.10 \ M$,Degree of ionization $(\alpha) = 4.0 \ \% = 0.04$.
For the dissociation of lactic acid: $CH_3CH(OH)COOH \rightleftharpoons CH_3CH(OH)COO^{-} + H^{+}$.
The equilibrium constant $K_a$ is given by the expression: $K_a = \frac{C\alpha^2}{1-\alpha}$.
Substituting the values: $K_a = \frac{0.1 \times (0.04)^2}{1 - 0.04}$.
$K_a = \frac{0.1 \times 0.0016}{0.96} = \frac{0.00016}{0.96} = \frac{1.6 \times 10^{-4}}{0.96} \approx 1.66 \times 10^{-4}$.
98
ChemistryMCQAP EAMCET · 2013
Which one of the following is an isotonic pair of solutions?
A
$0.15 \ M \ NaCl$ and $0.1 \ M \ Na_2SO_4$
B
$0.2 \ M$ Urea and $0.1 \ M$ Sugar
C
$0.1 \ M \ BaCl_2$ and $0.2 \ M$ Urea
D
$0.4 \ M \ MgSO_4$ and $0.1 \ M \ NH_4Cl$

Solution

(A) Two solutions are isotonic if they have the same molar concentration of particles (osmolarity).
For $0.15 \ M \ NaCl$: $NaCl$ dissociates into $2$ ions ($Na^+$ and $Cl^-$). The concentration of particles $= 0.15 \times 2 = 0.30 \ M$.
For $0.1 \ M \ Na_2SO_4$: $Na_2SO_4$ dissociates into $3$ ions ($2Na^+$ and $SO_4^{2-}$). The concentration of particles $= 0.1 \times 3 = 0.30 \ M$.
Since both solutions have the same concentration of particles,they are isotonic.
99
ChemistryMCQAP EAMCET · 2013
At $T \text{ K}$,the ratio of kinetic energies of $4 \text{ g}$ of $H_{2(g)}$ and $8 \text{ g}$ of $O_{2(g)}$ is
A
$1: 4$
B
$4: 1$
C
$2: 1$
D
$8: 1$

Solution

(D) The kinetic energy $(KE)$ of $n$ moles of an ideal gas at temperature $T$ is given by $KE = n \times \frac{3}{2} RT$.
For $4 \text{ g}$ of $H_2$: Moles $n_1 = \frac{4 \text{ g}}{2 \text{ g/mol}} = 2 \text{ mol}$.
$KE_{H_2} = 2 \times \frac{3}{2} RT = 3RT$.
For $8 \text{ g}$ of $O_2$: Moles $n_2 = \frac{8 \text{ g}}{32 \text{ g/mol}} = 0.25 \text{ mol} = \frac{1}{4} \text{ mol}$.
$KE_{O_2} = \frac{1}{4} \times \frac{3}{2} RT = \frac{3}{8} RT$.
Ratio $KE_{H_2} : KE_{O_2} = 3RT : \frac{3}{8} RT = 1 : \frac{1}{8} = 8 : 1$.
100
ChemistryMCQAP EAMCET · 2013
The basis of the quantum mechanical model of an atom is
A
angular momentum of electron
B
quantum numbers
C
dual nature of electron
D
black body radiation

Solution

(C) The quantum or wave mechanical model of an atom is based upon the dual nature of the electron,i.e.,the electron exhibits both particle and wave-like properties.
This model incorporates the de Broglie hypothesis regarding the wave nature of matter and the Heisenberg uncertainty principle.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real AP EAMCET style covering Chemistry with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D Chemistry papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Run live AP EAMCET mock exams with unlimited students, 360° analytics & white-label branding.

See Demo

Frequently Asked Questions

How many Chemistry questions are in AP EAMCET 2013?

There are 199 Chemistry questions from the AP EAMCET 2013 paper on Vedclass, each with a detailed step-by-step solution in English.

Are AP EAMCET 2013 Chemistry solutions available in English?

Yes. All solutions on this page are in English. You can also switch to English or Hindi using the language buttons above the questions.

Can I practice AP EAMCET 2013 Chemistry as a timed test?

Yes. Use the Vedclass Test Series to attempt a full AP EAMCET mock test covering Chemistry with time limits and instant score analysis.

Can teachers create Chemistry papers from AP EAMCET previous year questions?

Yes. The Vedclass Exam Paper Generator lets teachers mix AP EAMCET Chemistry questions and generate Set A/B/C/D papers in minutes.

For Teachers & Institutes

Build a Custom Chemistry Paper

Pick AP EAMCET 2013 Chemistry questions, set difficulty, and generate Set A/B/C/D in 2 minutes.