AIPMT 1987 Chemistry Question Paper with Answer and Solution

1 QuestionsEnglishWith Solutions

ChemistryQ11 of 1 questions

Page 1 of 1 · English

1
ChemistryMediumMCQAIPMT · 1987
Of the following hydrides,which has the lowest boiling point?
A
$NH_3$
B
$PH_3$
C
$SbH_3$
D
$AsH_3$

Solution

(B) The boiling point of hydrides of group $15$ elements generally increases down the group due to an increase in molecular mass and van der Waals forces.
However,$NH_3$ has an anomalously high boiling point due to intermolecular hydrogen bonding.
Among the remaining hydrides ($PH_3$,$AsH_3$,$SbH_3$),$PH_3$ has the lowest molecular mass and thus the weakest van der Waals forces.
Therefore,$PH_3$ has the lowest boiling point.

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