The given plots represent the variation of the concentration of a reactant $R$ with time for two different reactions $(i)$ and $(ii).$ The respective orders of the reactions are
$1,1$
$0,2$
$0,1$
$1,0$
Define following term / Give definition :
$(1)$ Rate law / Rate equation / Rate expression
$(2)$ Unimolecular reaction
For the reaction $C{H_3}COOC{H_3} + {H_2}O\xrightarrow{{{H^ + }}}$ $C{H_3}COOH + C{H_3}OH$ The progress of the process of reaction is followed by
Select the rate law that corresponds to the data shown for the following reaction $A+ B\to C$
Expt. No. | $(A)$ | $(B)$ | Initial Rate |
$1$ | $0.012$ | $0.035$ | $0.10$ |
$2$ | $0.024$ | $0.070$ | $0.80$ |
$3$ |
$0.024$ |
$0.035$ | $0.10$ |
$4$ | $0.012$ | $0.070$ | $0.80$ |
For the following reaction scheme (homogeneous), the rate constant has units
$A+B\xrightarrow{K}C$:
Rate of reaction is given by following rate law $ - \frac{{d\left[ c \right]}}{{dt}} = \frac{{{k_1}\,\left[ c \right]}}{{1 + {k_2}\,\left[ c \right]}}$ order of reaction when concentration is verh high