Define following term / Give definition :
$(1)$ Rate law / Rate equation / Rate expression
$(2)$ Unimolecular reaction
The value of $\frac{{{t_{0.875}}}}{{{t_{0.50}}}}$ for $n^{th}$ order reaction is
During the kinetic study of the reaction, $2A + B \rightarrow C + D,$ following results were obtained
Run | $[A]/mol\,L^{-1}$ | $[B]/mol\,L^{-1}$ | Initial rate of formation of $D/mol\,L^{-1}\,min^{-1}$ |
$I.$ | $0.1$ | $0.1$ | $6.0 \times 10^{-3}$ |
$II.$ | $0.3$ | $0.2$ | $7.2 \times 10^{-2}$ |
$III.$ | $0.3$ | $0.4$ | $2.88 \times 10^{-1}$ |
$IV.$ | $0.4$ | $0.1$ | $2.40 \times 10^{-2}$ |
Based on the above data which one of the following is correct?
Explain order of reaction of complex reaction by giving examples.
units of rate constant of first and zero order reactions in terms of molarity $M$ unit are respectively
For reaction :
$2NO_2(g) + O_3(g) \to N_2O_5(g) + O_2(g)$
rate law is $R = K\, [NO_2]' [O_3]'$.
Which of these possible reaction mechanisms is consistent with the rate law?
Mechanism $I :$
$NO_2(g) + O_3(g) \to NO_3(g) + O_2(g)$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5(g)$ (fast)
Mechanism $II :$
$O_3(g) \rightleftharpoons O_2(g) + [O]$ (fast)
$NO_2(g) + [O] \to NO_3$ (slow)
$NO_3(g) + NO_2(g) \to N_2O_5$ (fast)