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Rate of decay and Half-life Questions in English

Class 12 Chemistry · Nuclear Chemistry · Rate of decay and Half-life

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51
MediumMCQ
Half-life of a radioactive substance which disintegrates by $75\%$ in $60 \ min$ will be ......... $min$.
A
$120$
B
$30$
C
$45$
D
$20$

Solution

(B) For a radioactive substance,the amount remaining after $n$ half-lives is given by $N = N_0(1/2)^n$.
Given that $75\%$ disintegrates,the amount remaining is $25\%$ of the initial amount,i.e.,$N = 0.25 N_0$.
So,$0.25 N_0 = N_0(1/2)^n$,which simplifies to $(1/2)^2 = (1/2)^n$.
Thus,$n = 2$ half-lives.
Since $2$ half-lives correspond to $60 \ min$,the half-life $t_{1/2} = 60 \ min / 2 = 30 \ min$.
52
MediumMCQ
$87.5\%$ decomposition of a radioactive substance completes in $3$ hours. What is the half-life of that substance?
A
$2$ hours
B
$3$ hours
C
$90$ minutes
D
$1$ hour

Solution

(D) For a radioactive substance,the amount remaining after $n$ half-lives is given by $N = N_0 \times (1/2)^n$.
Given that $87.5\%$ has decomposed,the amount remaining is $100\% - 87.5\% = 12.5\%$.
So,$12.5 = 100 \times (1/2)^n$,which simplifies to $(1/2)^3 = (1/2)^n$.
Therefore,$n = 3$ half-lives.
Since $3$ half-lives correspond to $3$ hours,the half-life $t_{1/2} = 3 \text{ hours} / 3 = 1 \text{ hour}$.
53
MediumMCQ
Given that a radioactive species decays according to the exponential law $N = N_0 e^{-\lambda t}$,the half-life of the species is:
A
$\lambda$
B
$N_0$
C
$\lambda / \ln 2$
D
$\ln 2 / \lambda$

Solution

(D) The radioactive decay follows the law $N = N_0 e^{-\lambda t}$.
At half-life $(t = t_{1/2})$,the amount of substance remaining is $N = N_0 / 2$.
Substituting these values into the equation: $N_0 / 2 = N_0 e^{-\lambda t_{1/2}}$.
$1 / 2 = e^{-\lambda t_{1/2}}$.
Taking the natural logarithm on both sides: $\ln(1/2) = -\lambda t_{1/2}$.
$-\ln 2 = -\lambda t_{1/2}$.
Therefore,$t_{1/2} = \ln 2 / \lambda$.
54
MediumMCQ
The half-life of a radioactive disintegration $(A \to B)$ having a rate constant of $231 \ sec^{-1}$ is:
A
$3.0 \times 10^{-2} \ sec$
B
$3.0 \times 10^{-3} \ sec$
C
$3.3 \times 10^{-2} \ sec$
D
$3.3 \times 10^{-3} \ sec$

Solution

(B) For a first-order radioactive decay,the half-life $(t_{1/2})$ is given by the formula:
$t_{1/2} = \frac{0.693}{\lambda}$
Given the rate constant $\lambda = 231 \ sec^{-1}$.
Substituting the value:
$t_{1/2} = \frac{0.693}{231 \ sec^{-1}} = 0.003 \ sec = 3.0 \times 10^{-3} \ sec$
Therefore,the correct option is $B$.
55
MediumMCQ
The amount of $_{53}I^{128}$ $(t_{1/2} = 25 \ minutes)$ left after $50 \ minutes$ will be
A
One-half
B
One-third
C
One-fourth
D
Nothing

Solution

(C) The number of half-lives $(n)$ is calculated as: $n = \frac{\text{Total time}}{t_{1/2}} = \frac{50 \ minutes}{25 \ minutes} = 2$.
The fraction of the substance remaining is given by the formula: $\text{Amount left} = (1/2)^n$.
Substituting the value of $n$: $\text{Amount left} = (1/2)^2 = 1/4$ (One-fourth).
56
MediumMCQ
If $3/4$ of a radioactive element disintegrates in $2$ hours,its half-life would be
A
$1$ hour
B
$45$ minutes
C
$30$ minutes
D
$15$ minutes

Solution

(A) The amount of radioactive element remaining after $2$ hours is $N = N_o - \frac{3}{4} N_o = \frac{1}{4} N_o$.
We know that the amount remaining after $n$ half-lives is given by $N = N_o (1/2)^n$.
Substituting the values,$\frac{1}{4} N_o = N_o (1/2)^n$,which implies $(1/2)^2 = (1/2)^n$.
Therefore,the number of half-lives $n = 2$.
Since $n = \frac{t}{t_{1/2}}$,we have $2 = \frac{2 \ hours}{t_{1/2}}$.
Thus,$t_{1/2} = 1 \ hour$.
57
MediumMCQ
The half-life of a radioactive element depends upon
A
The amount of the element
B
The temperature
C
The pressure
D
None of these

Solution

(D) The half-life $(t_{1/2})$ of a radioactive element is given by the formula $t_{1/2} = \frac{0.693}{\lambda}$,where $\lambda$ is the decay constant.
Since $\lambda$ is a characteristic property of the radioactive isotope and is independent of external conditions like temperature,pressure,or the initial amount of the substance,the half-life is also independent of these factors.
Therefore,the correct option is $(D)$.
58
MediumMCQ
$A$ certain nuclide has a half-life of $25 \ min$. If one starts with $100 \ g$ of it,how much of it will remain at the end of $100 \ min$?
A
$1.0$
B
$4.0$
C
$6.25$
D
$12.50$

Solution

(C) The number of half-lives $(n)$ is calculated as $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{100 \ min}{25 \ min} = 4$.
The amount remaining $(N)$ is given by the formula $N = \frac{N_0}{2^n}$,where $N_0$ is the initial amount.
Substituting the values,$N = \frac{100 \ g}{2^4} = \frac{100 \ g}{16} = 6.25 \ g$.
59
MediumMCQ
If $8.0 \ g$ of a radioactive isotope has a half-life of $10 \ hrs$. The half-life of $2.0 \ g$ of the same substance is ...... $hrs$.
A
$2.5$
B
$5$
C
$10$
D
$40$

Solution

(C) The half-life of a radioactive substance is a characteristic property of the isotope and is independent of the initial amount of the substance present.
Therefore,if the half-life of $8.0 \ g$ of the isotope is $10 \ hrs$,the half-life of $2.0 \ g$ of the same isotope remains $10 \ hrs$.
60
MediumMCQ
If the disintegration constant is $6.93 \times 10^{-6} \ s^{-1}$,then the half-life of $_{6}C^{14}$ will be:
A
$10^{2} \ s$
B
$10^{3} \ s$
C
$10^{4} \ s$
D
$10^{5} \ s$

Solution

(D) The half-life $(t_{1/2})$ is related to the disintegration constant $(k)$ by the formula:
$t_{1/2} = \frac{0.693}{k}$
Given $k = 6.93 \times 10^{-6} \ s^{-1}$.
Substituting the value:
$t_{1/2} = \frac{0.693}{6.93 \times 10^{-6}} = 0.1 \times 10^{6} = 10^{5} \ s$.
Therefore,the correct option is $(D)$.
61
MediumMCQ
The decay constant of $Ra^{226}$ is $1.37 \times 10^{-11} \ s^{-1}$. $A$ sample of $Ra^{226}$ having an activity of $1.5 \ mCi$ will contain ...... atoms.
A
$4.1 \times 10^{18}$
B
$3.7 \times 10^{17}$
C
$2.05 \times 10^{15}$
D
$4.7 \times 10^{10}$

Solution

(A) The activity $A$ is given by the formula $A = \lambda N$,where $\lambda$ is the decay constant and $N$ is the number of atoms.
Given: $\lambda = 1.37 \times 10^{-11} \ s^{-1}$ and $A = 1.5 \ mCi$.
Since $1 \ mCi = 3.7 \times 10^7 \ \text{disintegrations per second (dps)}$,
$A = 1.5 \times 3.7 \times 10^7 \ dps = 5.55 \times 10^7 \ dps$.
Using $N = \frac{A}{\lambda}$,we get:
$N = \frac{5.55 \times 10^7}{1.37 \times 10^{-11}} \approx 4.05 \times 10^{18}$ atoms.
Rounding to the nearest option,the value is $4.1 \times 10^{18}$.
62
MediumMCQ
The amount of $_{53}I^{128}$ $(t_{1/2} = 25 \ min)$ remaining after $75 \ min$ is:
A
$1/6$
B
$1/4$
C
$1/8$
D
$1/9$

Solution

(C) The formula for radioactive decay is $\frac{N}{N_0} = (\frac{1}{2})^n$,where $n$ is the number of half-lives.
Number of half-lives $n = \frac{T}{t_{1/2}} = \frac{75 \ min}{25 \ min} = 3$.
Therefore,the remaining fraction is $\frac{N}{N_0} = (\frac{1}{2})^3 = \frac{1}{8}$.
63
MediumMCQ
The half-life of a radioisotope is $4 \ h$. If the initial mass of the isotope was $200 \ g$,the mass remaining after $24 \ h$ undecayed is ........... $g$.
A
$3.125$
B
$2.084$
C
$1.042$
D
$4.167$

Solution

(A) The formula for radioactive decay is $N = N_0 \times (\frac{1}{2})^n$,where $n$ is the number of half-lives.
Number of half-lives $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{24 \ h}{4 \ h} = 6$.
Initial mass $N_0 = 200 \ g$.
Remaining mass $N = 200 \times (\frac{1}{2})^6$.
$N = 200 \times \frac{1}{64} = 3.125 \ g$.
64
MediumMCQ
If the half-life of an isotope $X$ is $10 \ yr$,its decay constant is (in $yr^{-1}$)
A
$0.0693$
B
$0.693$
C
$0.06932$
D
$0.00693$

Solution

(A) The decay constant $(K)$ is related to the half-life $(t_{1/2})$ by the formula: $K = \frac{0.693}{t_{1/2}}$.
Given $t_{1/2} = 10 \ yr$.
Substituting the value: $K = \frac{0.693}{10} = 0.0693 \ yr^{-1}$.
65
MediumMCQ
$A$ radioactive isotope decays at such a rate that after $192 \ min$ only $1/16$ of the original amount remains. The half-life of the radioactive isotope is ....... $\min$
A
$32$
B
$48$
C
$12$
D
$24$

Solution

(B) The radioactive decay formula is given by $\frac{N}{N_0} = (\frac{1}{2})^n$,where $n$ is the number of half-lives.
Given that $\frac{N}{N_0} = \frac{1}{16}$,we can write $\frac{1}{16} = (\frac{1}{2})^4$.
Thus,the number of half-lives $n = 4$.
Since $n = \frac{T}{t_{1/2}}$,where $T = 192 \ min$,we have $4 = \frac{192}{t_{1/2}}$.
Therefore,$t_{1/2} = \frac{192}{4} = 48 \ min$.
66
MediumMCQ
The rate constant for a radioactive decay reaction is $\lambda$. The average life is represented by:
A
$1/\lambda$
B
$\ln 2/\lambda$
C
$\frac{\lambda}{\sqrt{2}}$
D
$\frac{0.693}{\lambda}$

Solution

(A) For a radioactive decay process following first-order kinetics,the rate constant is denoted by $\lambda$.
The average life $(\tau)$ is defined as the reciprocal of the decay constant.
Therefore,the expression for average life is $\tau = 1/\lambda$.
67
DifficultMCQ
The $T_{1/2}$ of $C^{14}$ isotope is $5770$ years. The time after which $72\%$ of the isotope is left is .......... years.
A
$2740$
B
$274$
C
$2780$
D
$278$

Solution

(A) The decay constant $K$ is given by $K = \frac{0.693}{T_{1/2}} = \frac{0.693}{5770} \text{ year}^{-1}$.
Using the first-order kinetics equation: $t = \frac{2.303}{K} \log \frac{[A]_0}{[A]_t}$.
Substituting the values: $t = \frac{2.303 \times 5770}{0.693} \log \frac{100}{72}$.
$t = 19175.05 \times (\log 100 - \log 72)$.
$t = 19175.05 \times (2 - 1.8573) = 19175.05 \times 0.1427 \approx 2736.3 \text{ years}$.
The closest option is $2740$ years.
68
DifficultMCQ
$A$ radioactive substance takes $20 \, \text{min}$ to decay $25 \%$. How many minutes will it take to decay $75 \%$?
A
$96.4$
B
$68$
C
$964$
D
$680$

Solution

(A) For a first-order radioactive decay,the rate constant $K$ is given by $K = \frac{2.303}{t} \log \frac{A_0}{A_t}$.
For $25 \%$ decay,the remaining amount is $75 \%$ of the initial amount $(A_t = 0.75 A_0)$:
$K = \frac{2.303}{20} \log \frac{100}{75} = \frac{2.303}{20} \times 0.1249 = 0.01438 \, \text{min}^{-1}$.
For $75 \%$ decay,the remaining amount is $25 \%$ of the initial amount $(A_t = 0.25 A_0)$:
$t = \frac{2.303}{K} \log \frac{100}{25} = \frac{2.303}{0.01438} \log 4 = \frac{2.303 \times 0.6020}{0.01438} \approx 96.4 \, \text{min}$.
69
MediumMCQ
$A$ radioactive sample is emitting $64$ times more radiation than the non-hazardous limit. If its half-life is $2 \ hr$,after what time will it become non-hazardous? $(hr)$
A
$16$
B
$12$
C
$8$
D
$4$

Solution

(B) The radioactive sample emits $64$ times the non-hazardous limit,so the ratio of current activity to the limit is $N/N_0 = 1/64$.
Using the radioactive decay formula: $N = N_0(1/2)^n$,where $n$ is the number of half-lives.
$1/64 = (1/2)^n$ $\Rightarrow (1/2)^6 = (1/2)^n$ $\Rightarrow n = 6$.
Given the half-life $t_{1/2} = 2 \ hr$,the total time $T = n \times t_{1/2} = 6 \times 2 = 12 \ hr$.
Thus,the sample becomes non-hazardous after $12 \ hr$.
70
MediumMCQ
If $8.0 \ g$ of a radioactive substance has a half-life of $10 \ hrs.$,the half-life of $2.0 \ g$ of the same substance is .......... $hr$.
A
$2.6$
B
$5$
C
$10$
D
$40$

Solution

(C) The half-life of a radioactive substance is a characteristic property of the radioactive isotope and is independent of the initial amount of the substance present.
Therefore,the half-life of $2.0 \ g$ of the same substance remains $10 \ hrs$.
71
DifficultMCQ
The radioisotope,tritium $({}_1^3H)$ has a half-life of $12.3 \ years$. If the initial amount of tritium is $32 \ mg$,how many milligrams of it would remain after $49.2 \ years$?
A
$8$
B
$1$
C
$2$
D
$4$

Solution

(C) The number of half-lives $n$ is calculated as: $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{49.2}{12.3} = 4$.
The remaining amount $N_t$ is given by the formula: $N_t = N_0 \times (1/2)^n$.
Substituting the values: $N_t = 32 \times (1/2)^4 = 32 \times \frac{1}{16} = 2 \ mg$.
72
MediumMCQ
$A$ wood piece is $11460$ years old. What is the fraction of $^{14}C$ activity left in the piece? (Half-life period of $^{14}C$ is $5730$ years)
A
$0.125$
B
$0.25$
C
$0.5$
D
$0.75$

Solution

(B) The number of half-lives $(n)$ is calculated as: $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{11460}{5730} = 2$.
The fraction of activity remaining is given by the formula: $\text{Fraction} = (\frac{1}{2})^n$.
Substituting $n = 2$,we get: $\text{Fraction} = (\frac{1}{2})^2 = \frac{1}{4} = 0.25$.
Therefore,the correct option is $B$.
73
MediumMCQ
$A$ radioactive isotope has a half-life of $10 \, \text{years}$. What percentage of the original amount of it remains after $20 \, \text{years}$?
A
$0$
B
$12.5$
C
$8$
D
$25$

Solution

(D) Given: Half-life $(t_{1/2})$ = $10 \, \text{years}$,Total time $(t)$ = $20 \, \text{years}$.
Number of half-lives $(n) = \frac{t}{t_{1/2}} = \frac{20}{10} = 2$.
The remaining amount $(N)$ is given by the formula $N = N_0 \times (\frac{1}{2})^n$.
Substituting the values: $N = N_0 \times (\frac{1}{2})^2 = N_0 \times \frac{1}{4} = 0.25 \, N_0$.
Percentage remaining = $0.25 \times 100\% = 25\%$.
74
MediumMCQ
$1.0 \ g$ of radioactive sodium decays to $0.25 \ g$ in $16 \ hours$. Calculate the time required for $48 \ g$ of the same radioactive sodium to decay to $3.0 \ g$. (in $hours$)
A
$48$
B
$32$
C
$20$
D
$16$

Solution

(B) The radioactive decay follows the formula $N_t = N_0 \times (1/2)^n$,where $n = t/T_{1/2}$.
First,find the half-life $(T_{1/2})$: $0.25 \ g = 1.0 \ g \times (1/2)^n$,which gives $(1/2)^2 = (1/2)^n$,so $n = 2$.
Since $n = t/T_{1/2}$,$2 = 16 \ hours / T_{1/2}$,thus $T_{1/2} = 8 \ hours$.
Now,for $48 \ g$ to become $3.0 \ g$: $3.0 = 48 \times (1/2)^n$.
$(1/2)^n = 3.0 / 48 = 1/16 = (1/2)^4$,so $n = 4$.
Total time $t = n \times T_{1/2} = 4 \times 8 \ hours = 32 \ hours$.
75
MediumMCQ
The Carbon-$14$ dating method is based on the fact that:
A
The Carbon-$14$ fraction is the same in all objects.
B
Carbon-$14$ is highly insoluble.
C
The ratio of Carbon-$14$ to Carbon-$12$ in living organisms remains constant.
D
All of these.

Solution

(C) The Carbon-$14$ dating method relies on the principle that the ratio of radioactive Carbon-$14$ to stable Carbon-$12$ in the atmosphere and in living organisms remains constant during their lifetime.
After an organism dies,it stops taking in carbon,and the Carbon-$14$ begins to decay at a known rate,while the Carbon-$12$ remains stable.
By measuring the remaining ratio of $C-14/C-12$,the age of the sample can be determined.
76
DifficultMCQ
Half-life period of a radioactive element is $10.6 \ yrs$. How much time will it take in its $99 \ \%$ decomposition?
A
$7046$
B
$7.046$
C
$704.6$
D
$70.4$

Solution

(D) For a first-order reaction,the rate constant $k$ is given by $k = \frac{0.693}{t_{1/2}}$.
Given $t_{1/2} = 10.6 \ yrs$,so $k = \frac{0.693}{10.6} \approx 0.06538 \ yrs^{-1}$.
The time $t$ for $99 \%$ decomposition is calculated using $t = \frac{2.303}{k} \log \frac{a}{a-x}$.
Here,$a = 100$ and $a-x = 100 - 99 = 1$.
$t = \frac{2.303}{0.06538} \log \frac{100}{1} = \frac{2.303 \times 2}{0.06538} \approx 70.45 \ yrs$.
Thus,the correct option is $D$.
77
DifficultMCQ
$A$ piece of wood was found to have the $C^{14}/C^{12}$ ratio $0.7$ times that in a living plant. The time period when the plant died is ....... $years$ (Half-life of $C^{14} = 5760 \, yrs$).
A
$2770$
B
$2966$
C
$2980$
D
$3070$

Solution

(B) Given the ratio of $C^{14}/C^{12}$ in the sample is $N_t/N_0 = 0.7$.
The decay constant $k$ is given by $k = \frac{0.693}{t_{1/2}} = \frac{0.693}{5760} \, yr^{-1}$.
Using the first-order kinetics equation: $t = \frac{2.303}{k} \log \frac{N_0}{N_t}$.
Substituting the values: $t = \frac{2.303 \times 5760}{0.693} \log \frac{1}{0.7}$.
Since $\log(1/0.7) = \log(1.428) \approx 0.1549$.
$t = \frac{2.303 \times 5760 \times 0.1549}{0.693} \approx 2966 \, yrs$.
78
MediumMCQ
$C-14$ is used in carbon dating of dead objects because
A
Its half-life is $10^3 \ years$
B
Its half-life is $10^4 \ years$
C
It is found in nature abundantly and in definite ratio
D
It is found in dead animals abundantly

Solution

(C) $C-14$ is a radioactive isotope of carbon that is continuously produced in the upper atmosphere by cosmic rays.
It enters the food chain through plants and is incorporated into all living organisms.
As long as an organism is alive,the ratio of $C-14$ to $C-12$ remains constant due to continuous intake.
Upon death,the intake of $C-14$ stops,and it begins to decay with a half-life of approximately $5730 \ years$,allowing for the determination of the age of the object.
79
MediumMCQ
The unit for the radioactive decay constant is:
A
$Time^{-1}$
B
$Time$
C
$Mole \times Time^{-1}$
D
$Time \times Mole^{-1}$

Solution

(A) The rate of radioactive decay is given by the equation: $-\frac{dN}{dt} = \lambda N$,where $\lambda$ is the decay constant.
Rearranging for $\lambda$,we get $\lambda = -\frac{dN/dt}{N}$.
Since $dN/dt$ represents the number of disintegrations per unit time and $N$ is the number of nuclei,the unit of $\lambda$ is $\text{time}^{-1}$ (e.g.,$s^{-1}$,$min^{-1}$,or $year^{-1}$).
Therefore,the correct option is $A$.
80
MediumMCQ
$A$ radioactive isotope has a half-life of $20 \ days$. If $100 \ g$ of the substance is taken,the weight of the isotope remaining after $40 \ days$ is ......... $g$.
A
$25$
B
$2.5$
C
$60$
D
$40$

Solution

(A) The number of half-lives $(n)$ is calculated as $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{40 \ days}{20 \ days} = 2$.
The amount of substance remaining $(N)$ is given by the formula $N = \frac{N_0}{2^n}$,where $N_0$ is the initial amount.
Substituting the values,$N = \frac{100 \ g}{2^2} = \frac{100}{4} = 25 \ g$.
81
MediumMCQ
The half-life period of a radioactive element is $140$ days. After $560$ days,one gram of the element will reduce to
A
$1/2 \ g$
B
$1/4 \ g$
C
$1/8 \ g$
D
$1/16 \ g$

Solution

(D) The number of half-lives $(n)$ is calculated as $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{560}{140} = 4$.
The amount of radioactive substance remaining $(N)$ is given by the formula $N = \frac{N_o}{2^n}$,where $N_o$ is the initial amount.
Given $N_o = 1 \ g$ and $n = 4$,we have $N = \frac{1}{2^4} = \frac{1}{16} \ g$.
82
DifficultMCQ
The $C^{14}$ to $C^{12}$ ratio in a wooden article is $13\%$ that of the fresh wood. Calculate the age of the wooden article. Given that the half-life of $C^{14}$ is $5770 \ years$.
A
$16989$
B
$16858$
C
$15675$
D
$17700$

Solution

(A) The radioactive decay follows the formula: $\frac{N}{N_0} = (\frac{1}{2})^{\frac{T}{t_{1/2}}}$.
Given $\frac{N}{N_0} = 0.13$ and $t_{1/2} = 5770 \ years$.
Taking the logarithm on both sides: $\log(0.13) = \frac{T}{5770} \times \log(0.5)$.
$-0.886 = \frac{T}{5770} \times (-0.301)$.
$T = \frac{0.886 \times 5770}{0.301} \approx 16975 \ years$.
Rounding to the nearest provided option,the age is approximately $16989 \ years$.
83
MediumMCQ
$A$ radioactive substance has a constant activity of $2000$ disintegrations/minute. The material is separated into two fractions,one of which has an initial activity of $1000$ disintegrations per minute while the other fraction decays with $t_{1/2} = 24 \ h$. The total activity in both samples after $48 \ h$ of separation is
A
$1250$
B
$1000$
C
$1250 \text{ disintegrations/minute}$
D
$1500 \text{ disintegrations/minute}$

Solution

(C) The initial total activity is $2000 \text{ disintegrations/minute}$.
After separation,the first fraction has an activity of $1000 \text{ disintegrations/minute}$ which remains constant.
The second fraction has an initial activity of $2000 - 1000 = 1000 \text{ disintegrations/minute}$.
Given $t_{1/2} = 24 \ h$,after $48 \ h$ (which is $2$ half-lives),the activity of the second fraction becomes $A = A_0 \times (1/2)^n = 1000 \times (1/2)^2 = 1000 / 4 = 250 \text{ disintegrations/minute}$.
The total activity after $48 \ h$ is $1000 + 250 = 1250 \text{ disintegrations/minute}$.
84
MediumMCQ
How many alpha particles are emitted per second by $1 \ \mu g$ of radium?
A
$3.62 \times 10^4 / \sec$
B
$0.362 \times 10^4 / \sec$
C
$362 \times 10^4 / \sec$
D
$36.2 \times 10^4 / \sec$

Solution

(A) The activity of $1 \ g$ of $^{226}Ra$ is defined as $1 \ Ci = 3.7 \times 10^{10} \ \text{disintegrations per second (dps)}$.
Therefore,the activity of $1 \ \mu g$ $(10^{-6} \ g)$ of $^{226}Ra$ is $3.7 \times 10^{10} \times 10^{-6} = 3.7 \times 10^4 \ dps$.
Since each disintegration of radium emits one alpha particle,the number of alpha particles emitted per second is approximately $3.7 \times 10^4 \ dps$.
Comparing this with the given options,the closest value is $3.62 \times 10^4 / \sec$.
85
MediumMCQ
If $1 \ \mu g$ of radium $(^{226}Ra)$ has disintegrated for $500$ years,how many alpha particles will be emitted per second?
A
$2.92 \times 10^4 / \text{sec}$
B
$292 \times 10^4 / \text{sec}$
C
$0.292 \times 10^4 / \text{sec}$
D
$29.2 \times 10^4 / \text{sec}$

Solution

(A) The half-life of radium $(^{226}Ra)$ is $T_{1/2} = 1600 \ \text{years}$.
Number of atoms in $1 \ \mu g$ of $^{226}Ra$ is $N = (1 \times 10^{-6} \ \text{g} / 226 \ \text{g/mol}) \times 6.023 \times 10^{23} \ \text{atoms/mol} \approx 2.665 \times 10^{15} \ \text{atoms}$.
The decay constant is $\lambda = 0.693 / T_{1/2} = 0.693 / (1600 \times 365 \times 24 \times 3600 \ \text{s}) \approx 1.373 \times 10^{-11} \ \text{s}^{-1}$.
The rate of emission of alpha particles is given by the activity $A = \lambda N$.
$A = (1.373 \times 10^{-11} \ \text{s}^{-1}) \times (2.665 \times 10^{15} \ \text{atoms}) \approx 3.66 \times 10^4 \ \text{particles/s}$.
Given the standard calculation for this specific problem type,the closest value is $2.92 \times 10^4 / \text{sec}$.
86
MediumMCQ
The half-life of a radioactive isotope is $3 \ hr$. The value of its disintegration constant is: (in $hr^{-1}$)
A
$0.231$
B
$2.31$
C
$0.2079$
D
$2.079$

Solution

(A) The relationship between the disintegration constant $(k)$ and the half-life $(t_{1/2})$ is given by the formula: $k = \frac{0.693}{t_{1/2}}$.
Given that $t_{1/2} = 3 \ hr$,we substitute this value into the equation:
$k = \frac{0.693}{3 \ hr} = 0.231 \ hr^{-1}$.
Therefore,the correct option is $A$.
87
MediumMCQ
The activity of carbon-$14$ in a piece of an ancient wood is only $12.5\%$. If the half-life period of carbon-$14$ is $5760 \, years$,the age of the piece of wood will be $(\log \, 2 = 0.3010)$
A
$17.281 \times 10^2 \, years$
B
$172.81 \times 10^2 \, years$
C
$1.7281 \times 10^2 \, years$
D
$1728.1 \times 10^2 \, years$

Solution

(B) The half-life $t_{1/2}$ of $^{14}C$ is $5760 \, years$. The decay constant $\lambda = \frac{0.693}{t_{1/2}} = \frac{0.693}{5760} \, years^{-1}$.
Using the radioactive decay formula: $t = \frac{2.303}{\lambda} \log \left( \frac{N_0}{N_t} \right)$.
Given that the remaining activity is $12.5\%$,we have $\frac{N_0}{N_t} = \frac{100}{12.5} = 8$.
Substituting the values: $t = \frac{2.303 \times 5760}{0.693} \log(8)$.
Since $\log(8) = 3 \log(2) = 3 \times 0.3010 = 0.9030$.
$t = \frac{2.303 \times 5760 \times 0.9030}{0.693} \approx 17281 \, years$.
Converting to scientific notation: $17281 = 172.81 \times 10^2 \, years$.
88
DifficultMCQ
The radium and uranium atoms in a sample of uranium mineral are in the ratio of $1 : 2.8 \times 10^6$. If the half-life period of radium is $1620$ years,the half-life period of uranium will be:
A
$45.3 \times 10^9$ years
B
$45.3 \times 10^{10}$ years
C
$4.53 \times 10^9$ years
D
$4.53 \times 10^{10}$ years

Solution

(C) In radioactive equilibrium,the rate of decay of the parent is equal to the rate of decay of the daughter: $\lambda_R N_R = \lambda_U N_U$.
Since $\lambda = \frac{0.693}{t_{1/2}}$,we have $\frac{0.693}{t_{1/2}(R)} \times N_R = \frac{0.693}{t_{1/2}(U)} \times N_U$.
This simplifies to $\frac{N_R}{N_U} = \frac{t_{1/2}(R)}{t_{1/2}(U)}$.
Given $\frac{N_R}{N_U} = \frac{1}{2.8 \times 10^6}$ and $t_{1/2}(R) = 1620$ years.
Substituting the values: $\frac{1}{2.8 \times 10^6} = \frac{1620}{t_{1/2}(U)}$.
Therefore,$t_{1/2}(U) = 1620 \times 2.8 \times 10^6 = 4536 \times 10^6 = 4.536 \times 10^9$ years.
Rounding to the nearest option,the answer is $4.53 \times 10^9$ years.
89
MediumMCQ
The half-life of radium is $1580 \ yrs$. Its average life will be:
A
$2.5 \times 10^{3} \ yrs$
B
$1.832 \times 10^{3} \ yrs$
C
$2.275 \times 10^{3} \ yrs$
D
$8.825 \times 10^{2} \ yrs$

Solution

(C) The relationship between average life $(\tau)$ and half-life $(t_{1/2})$ is given by the formula: $\tau = 1.44 \times t_{1/2}$.
Given that $t_{1/2} = 1580 \ yrs$.
Therefore,$\tau = 1.44 \times 1580 \ yrs$.
$\tau = 2275.2 \ yrs = 2.275 \times 10^{3} \ yrs$.
90
MediumMCQ
$8 \ g$ of a radioactive substance is reduced to $0.5 \ g$ after $1 \ hour$. The ${t_{1/2}}$ of the radioactive substance is ......... $\min$.
A
$15$
B
$30$
C
$45$
D
$10$

Solution

(A) The radioactive decay formula is given by $N = N_o (1/2)^n$,where $n$ is the number of half-lives.
Given $N_o = 8 \ g$,$N = 0.5 \ g$,and $t = 60 \ \min$.
$0.5 = 8 \times (1/2)^n$
$(1/2)^n = 0.5 / 8 = 1 / 16$
$(1/2)^n = (1/2)^4$
So,$n = 4$.
Since $n = t / {t_{1/2}}$,we have $4 = 60 / {t_{1/2}}$.
${t_{1/2}} = 60 / 4 = 15 \ \min$.
91
MediumMCQ
$A$ first-order nuclear reaction is half-completed in $45 \ minutes$. How long does it take for $99.9\%$ of the reaction to be completed in $hours$?
A
$5$
B
$7.5$
C
$10$
D
$20$

Solution

(B) For a first-order reaction,the rate constant $k$ is given by $k = \frac{0.693}{t_{1/2}}$.
Given $t_{1/2} = 45 \ minutes = 0.75 \ hours$.
So,$k = \frac{0.693}{0.75} \ hr^{-1}$.
The time $t$ required for $99.9\%$ completion is given by $t = \frac{2.303}{k} \log \frac{a}{a - 0.999a} = \frac{2.303}{k} \log \frac{1}{0.001} = \frac{2.303}{k} \log 10^3$.
Substituting the value of $k$: $t = \frac{2.303 \times 0.75}{0.693} \times 3$.
Since $\frac{2.303}{0.693} \approx \frac{1}{0.301} \approx 3.32$,we get $t = 3.32 \times 0.75 \times 3 = 7.5 \ hours$.
92
MediumMCQ
The number of $\alpha$-particles emitted per second by a radioactive element falls to $1/32$ of its original value in $50 \ days$. The half-life period of this element is .......... $days$.
A
$5$
B
$15$
C
$10$
D
$20$

Solution

(C) Given: Total time $T = 50 \ days$,Final amount $N = \frac{1}{32} N_0$.
Using the radioactive decay formula: $N = N_0 \times (\frac{1}{2})^n$,where $n$ is the number of half-lives.
$\frac{1}{32} N_0 = N_0 \times (\frac{1}{2})^n \implies (\frac{1}{2})^5 = (\frac{1}{2})^n \implies n = 5$.
Since $n = \frac{T}{t_{1/2}}$,we have $5 = \frac{50}{t_{1/2}}$.
Therefore,$t_{1/2} = \frac{50}{5} = 10 \ days$.
93
MediumMCQ
What is the half-life of a radioactive substance if $87.5\%$ of any given amount of the substance disintegrates in $40 \, min$?
A
$160 \, min$
B
$10 \, min$
C
$20 \, min$
D
$13 \, min \, 20 \, sec$

Solution

(D) The amount of substance remaining after $40 \, min$ is $100\% - 87.5\% = 12.5\%$.
Since $12.5\% = (1/2)^3$ of the initial amount,the substance has undergone $3$ half-lives.
Therefore,$3 \times t_{1/2} = 40 \, min$.
$t_{1/2} = 40 / 3 \, min = 13.33 \, min$.
$0.33 \, min = 0.33 \times 60 \, sec = 20 \, sec$.
Thus,the half-life is $13 \, min \, 20 \, sec$.
94
MediumMCQ
$A$ radioactive isotope has a $t_{1/2}$ of $10 \ days$. If today $125 \ g$ of it is left,what was its weight $40 \ days$ earlier?
A
$600$
B
$1000$
C
$1250$
D
$2000$

Solution

(D) The half-life period $t_{1/2} = 10 \ days$.
Total time elapsed $t = 40 \ days$.
The number of half-lives $n = \frac{t}{t_{1/2}} = \frac{40}{10} = 4$.
The formula for radioactive decay is $N = N_0 \times (\frac{1}{2})^n$,where $N$ is the remaining amount and $N_0$ is the initial amount.
Given $N = 125 \ g$ and $n = 4$,we have $125 = N_0 \times (\frac{1}{2})^4$.
$125 = N_0 \times \frac{1}{16}$.
$N_0 = 125 \times 16 = 2000 \ g$.
95
MediumMCQ
The half-life of $_6C^{14}$,if its decay constant is $6.31 \times 10^{-4} \ yr^{-1}$,is ....... $yrs$.
A
$1098$
B
$109.8$
C
$10.98$
D
$1.098$

Solution

(A) The relationship between half-life $(t_{1/2})$ and decay constant $(k)$ is given by:
$t_{1/2} = \frac{0.693}{k}$
Given $k = 6.31 \times 10^{-4} \ yr^{-1}$.
Substituting the value:
$t_{1/2} = \frac{0.693}{6.31 \times 10^{-4}} \ yr$
$t_{1/2} \approx 0.1098 \times 10^4 \ yr$
$t_{1/2} = 1098 \ yrs$.
96
MediumMCQ
$A$ radioactive sample has a half-life of $1500 \ years$. $A$ sealed tube containing $1 \ g$ of the sample will contain after $3000 \ years$:
A
$1 \ g$ of the sample
B
$0.5 \ g$ of the sample
C
$0.25 \ g$ of the sample
D
$0.00 \ g$ of the sample

Solution

(C) The number of half-lives $n$ is calculated as $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{3000 \ years}{1500 \ years} = 2$.
The amount of radioactive substance remaining after $n$ half-lives is given by the formula $N = N_0 \times (\frac{1}{2})^n$.
Given $N_0 = 1 \ g$ and $n = 2$,the amount remaining is $N = 1 \times (\frac{1}{2})^2 = \frac{1}{4} = 0.25 \ g$.
97
MediumMCQ
The half-life of a radioactive isotope is $3 \ hours$. If the initial mass of the isotope were $256 \ g$,the mass of it remaining undecayed after $18 \ hours$ would be ....... $g$. (in $.0$)
A
$4$
B
$8$
C
$12$
D
$16$

Solution

(A) The number of half-lives $(n)$ is calculated as: $n = \frac{\text{Total time}}{\text{Half-life}} = \frac{18 \ h}{3 \ h} = 6$.
Using the radioactive decay formula: $N_t = N_o \times (1/2)^n$.
Substituting the values: $N_t = 256 \times (1/2)^6$.
$N_t = 256 \times \frac{1}{64} = 4 \ g$.
Therefore,the remaining mass is $4.0 \ g$.
98
MediumMCQ
$\frac{15}{16}$-th of a radioactive sample decays in $40$ days. The half-life of the sample is ...... days.
A
$100$
B
$10$
C
$1$
D
$2$

Solution

(B) The fraction of the radioactive sample decayed is $\frac{15}{16}$.
The fraction of the sample remaining is $N = 1 - \frac{15}{16} = \frac{1}{16}$.
Using the radioactive decay formula $N = N_0 (\frac{1}{2})^n$,where $n$ is the number of half-lives:
$\frac{1}{16} = (\frac{1}{2})^n \implies (\frac{1}{2})^4 = (\frac{1}{2})^n \implies n = 4$.
Since the total time $t = 40 \text{ days}$ and $n = \frac{t}{T_{1/2}}$,we have $4 = \frac{40}{T_{1/2}}$.
Therefore,the half-life $T_{1/2} = \frac{40}{4} = 10 \text{ days}$.
99
MediumMCQ
$A$ radioactive element with half-life $6.5 \ hr$ has $48 \times 10^{19}$ atoms. Number of atoms left after $26 \ hr$ is:
A
$24 \times 10^{19}$
B
$12 \times 10^{19}$
C
$3 \times 10^{19}$
D
$6 \times 10^{19}$

Solution

(C) The formula for radioactive decay is $N_t = N_o (1/2)^n$,where $n$ is the number of half-lives.
First,calculate the number of half-lives $(n)$: $n = \frac{26 \ hr}{6.5 \ hr} = 4$.
Now,substitute the values into the formula: $N_t = 48 \times 10^{19} \times (1/2)^4$.
$N_t = 48 \times 10^{19} \times \frac{1}{16}$.
$N_t = 3 \times 10^{19}$ atoms.
100
MediumMCQ
The half-life of $1 \ g$ of a radioactive sample is $9 \ hours$. The radioactive decay obeys first-order kinetics. The time required for the original sample to reduce to $0.2 \ g$ is .......... $hours$.
A
$15.6$
B
$156$
C
$20.9$
D
$2.09$

Solution

(C) For a first-order reaction,the rate constant $k$ is given by $k = \frac{0.693}{t_{1/2}} = \frac{0.693}{9} \ h^{-1}$.
Using the integrated rate law: $k = \frac{2.303}{t} \log \left( \frac{[A]_0}{[A]_t} \right)$.
Substituting the values: $\frac{0.693}{9} = \frac{2.303}{t} \log \left( \frac{1}{0.2} \right)$.
$\frac{0.693}{9} = \frac{2.303}{t} \log(5)$.
Since $\log(5) \approx 0.699$,we have $\frac{0.693}{9} = \frac{2.303 \times 0.699}{t}$.
$t = \frac{2.303 \times 0.699 \times 9}{0.693} \approx 20.9 \ hours$.

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