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Mix Examples of Some Basic Concept of Chemistry Questions in English

Class 11 Chemistry · Some Basic Concepts of Chemistry · Mix Examples of Some Basic Concept of Chemistry

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151
DifficultMCQ
Which of the following contain the same number of atoms?
$A$. $2 \text{ g}$ of $O_2$ gas
$B$. $4 \text{ g}$ of $SO_2$ gas
$C$. $1400 \text{ mL}$ of $O_2$ at $STP$
$D$. $0.05 \text{ L}$ of $He$ at $STP$
$E$. $0.0625 \text{ mol}$ of $H_2$ gas
Choose the correct answer from the options given below:
A
$A$ and $B$ only
B
$B$ and $C$ only
C
$C$ and $D$ only
D
$A, C$ and $E$ only

Solution

(D) To find the number of atoms,we calculate the moles of molecules and multiply by the atomicity and Avogadro's number $(N_A)$:
$A$. $2 \text{ g}$ of $O_2 = 2/32 = 0.0625 \text{ mol}$. Atoms = $0.0625 \times 2 \times N_A = 0.125 N_A$.
$B$. $4 \text{ g}$ of $SO_2 = 4/64 = 0.0625 \text{ mol}$. Atoms = $0.0625 \times 3 \times N_A = 0.1875 N_A$.
$C$. $1400 \text{ mL}$ of $O_2 = 1.4 \text{ L} / 22.4 \text{ L/mol} = 0.0625 \text{ mol}$. Atoms = $0.0625 \times 2 \times N_A = 0.125 N_A$.
$D$. $0.05 \text{ L}$ of $He = 0.05 / 22.4 \approx 0.00223 \text{ mol}$. Atoms = $0.00223 N_A$.
$E$. $0.0625 \text{ mol}$ of $H_2$. Atoms = $0.0625 \times 2 \times N_A = 0.125 N_A$.
Comparing the results,options $A, C$,and $E$ have the same number of atoms $(0.125 N_A)$.
152
DifficultMCQ
The correct order of the total number of atoms present in
$(A)$ $2$ moles of cyclohexane
$(B)$ $684 \text{ g}$ of sucrose
$(C)$ $90.8 \text{ L}$ of dihydrogen at $STP$
is:
A
$C > A > B$
B
$C > B > A$
C
$B > C > A$
D
$B > A > C$

Solution

(D) Step $1$: Calculate the number of atoms in $2$ moles of cyclohexane $(C_6H_{12})$.
One molecule of cyclohexane contains $6 + 12 = 18$ atoms.
Total atoms $= 2 \text{ mol} \times 18 \times N_A = 36 N_A$.
Step $2$: Calculate the number of atoms in $684 \text{ g}$ of sucrose $(C_{12}H_{22}O_{11})$.
Molar mass of sucrose $= (12 \times 12) + (22 \times 1) + (11 \times 16) = 144 + 22 + 176 = 342 \text{ g/mol}$.
Moles of sucrose $= 684 \text{ g} / 342 \text{ g/mol} = 2 \text{ mol}$.
One molecule of sucrose contains $12 + 22 + 11 = 45$ atoms.
Total atoms $= 2 \text{ mol} \times 45 \times N_A = 90 N_A$.
Step $3$: Calculate the number of atoms in $90.8 \text{ L}$ of dihydrogen $(H_2)$ at $STP$.
Moles of $H_2 = 90.8 \text{ L} / 22.7 \text{ L/mol} \approx 4 \text{ mol}$ (using standard molar volume $22.7 \text{ L/mol}$ at $1 \text{ bar}$ $STP$).
One molecule of $H_2$ contains $2$ atoms.
Total atoms $= 4 \text{ mol} \times 2 \times N_A = 8 N_A$.
Comparing the values: $B (90 N_A) > A (36 N_A) > C (8 N_A)$.
Thus,the correct order is $B > A > C$.

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