The rate constant of esterification $(k) = k'\, [H_2O]$ rate constant of esterification $2.0\times 10^{-3}\,min^{-1}$ calculate $k'$.
$k=k^{\prime}\left[\mathrm{H}_{2} \mathrm{O}\right]$
$\begin{aligned} \therefore k^{\prime} =\frac{k}{\left[\mathrm{H}_{2} \mathrm{O}\right]}=\frac{2.0 \times 10^{-3} \mathrm{~min}^{-1}}{55.5 \mathrm{~mol} \mathrm{~L}^{-1}} \\ =0.036 \times 10^{-3} \mathrm{~mol}^{-1} \mathrm{~L} \mathrm{~min}^{-1} \\ =3.6 \times 10^{-5} \mathrm{~mol}^{-1} \mathrm{~L} \mathrm{~min}^{-1} \end{aligned}$
In the reaction : $P + Q \longrightarrow R + S$ the time taken for $75\%$ reaction of $P$ is twice the time taken for $50\%$ reaction of $P$. The concentration of $Q$ varies with reaction time as shown in the figure. The overall order of the reaction is
Write unit of rate constant of following reaction :
$1.$ $\frac {1}{2}$ order
$2.$ $\frac {3}{2}$ order
In which of the following cases, does the reaction go farthest to completion
Decay of $_{92}{U^{235}}$is .....order reaction
During the kinetic study of the reaction, $2A + B \rightarrow C + D,$ following results were obtained
Run | $[A]/mol\,L^{-1}$ | $[B]/mol\,L^{-1}$ | Initial rate of formation of $D/mol\,L^{-1}\,min^{-1}$ |
$I.$ | $0.1$ | $0.1$ | $6.0 \times 10^{-3}$ |
$II.$ | $0.3$ | $0.2$ | $7.2 \times 10^{-2}$ |
$III.$ | $0.3$ | $0.4$ | $2.88 \times 10^{-1}$ |
$IV.$ | $0.4$ | $0.1$ | $2.40 \times 10^{-2}$ |
Based on the above data which one of the following is correct?