During the kinetic study of the reaction, $2A + B \rightarrow C + D,$ following results were obtained

Run $[A]/mol\,L^{-1}$ $[B]/mol\,L^{-1}$ Initial rate of formation of $D/mol\,L^{-1}\,min^{-1}$
$I.$ $0.1$ $0.1$ $6.0 \times 10^{-3}$
$II.$ $0.3$ $0.2$ $7.2 \times 10^{-2}$
$III.$ $0.3$ $0.4$ $2.88 \times 10^{-1}$
$IV.$ $0.4$ $0.1$ $2.40 \times 10^{-2}$

Based on the above data which one of the following is correct?

  • [AIPMT 2010]
  • A

    Rate $= k[A]^2[B]$

  • B

    Rate $= k[A][B]$

  • C

    Rate $= k[A]^2[B]^2$

  • D

    Rate $= k[A][B]^2$

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$A $ gaseous hypothetical chemical equation $2A$ $ \rightleftharpoons  $ $4B + C$ is carried out in a closed vessel. The concentration of $ B$  is found to increase by $5 \times {10^{ - 3}}mol\,\,{l^{ - 1}}$ in $10 $ second. The rate of appearance of $B$  is

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$1.$ The rate of reaction depends on ........... step.

$2.$ In bimolecular reaction the reaction take place with ........... species and ........... .

$3.$ The order of reaction is determine by ...........

For a chemical reaction....can never be a fraction

The reaction between $A$ and $B$ is first order with respect to $A$ and zero order with respect to $B$. Fill in the blanks in the following table:

Experiment $[ A ] / mol\, ^{-1}$ $[ B ] / mol\, ^{-1}$ Initial rate $/$ $mol$ $L^{-1}$ $min$ $^{-1}$
$I$ $0.1$ $0.1$ $2.0 \times 10^{-2}$
$II$ - $0.2$ $4.0 \times 10^{-2}$
$III$ $0.4$ $0.4$ -
$IV$ - $0.2$ $2.0 \times 10^{-2}$

 

For $n^{th}$ order reaction where $(n < 1)$