The heat of solution of anhydrous $CuSO_4$ and $CuSO_4 \cdot 5 H_2 O$ are $-70 \ kJ \ mol^{-1}$ and $+12 \ kJ \ mol^{-1}$ respectively. The heat of hydration of $CuSO_4$ to $CuSO_4 \cdot 5 H_2 O$ is $-x \ kJ$. The value of $x$ is:

The standard enthalpy of formation $(\Delta_fH^o)$ at $298 \ K$ for methane,$CH_{4(g)}$ is $-74.8 \ kJ \ mol^{-1}$. The additional information required to determine the average energy for $C-H$ bond formation would be

If $H^{+} + OH^{-} \to H_2O + 13.7 \ kcal$,then the heat of neutralization for complete neutralization of one mole of $H_2SO_4$ by base will be.......$kcal$

Which of the following heat of reaction expresses the bond energy of $HCl$?

Given:
$(i) \, C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = x \, kJ \, mol^{-1}$
$(ii) \, C(\text{graphite}) + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\ominus = y \, kJ \, mol^{-1}$
$(iii) \, CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = z \, kJ \, mol^{-1}$
Based on the above thermochemical equations,find out which one of the following algebraic relationships is correct?

$S + \frac{3}{2} O_2 \to SO_3 + 2x \ kcal$
$SO_2 + \frac{1}{2} O_2 \to SO_3 + y \ kcal$
Find out the heat of formation of $SO_2$.