The dimension of rate constant of a second order reaction involves
Neither time nor concentration
Only time
Time and concentration
Time and square of concentration
The rate law for the reaction below is given by the expression $k\left[ A \right]\left[ B \right]$
$A + B \to$ Product
If the concentration of $B$ is increased from $0.1$ to $0.3\, mole$, keeping the value of $A$ at $0.1\, mole$, the rate constant will be
For the elementary reaction $M \rightarrow N$, the rate of disappearance of $M$ increases by a factor of $8$ upon doubling the concentration of $M$. The order of the reaction with respect to $M$ is :
Define following term / Give definition :
$(1)$ Rate law / Rate equation / Rate expression
$(2)$ Unimolecular reaction
The reaction, ${N_2}{O_5} \longrightarrow 2NO + \frac{1}{2}\,{O_2}$ is of first order for $N_2O_5$ with rate constant $6.2 \times 10^{-4}\, s^{-1}$. what is the value of rate of reaction when $[N_2O_5] = 1.25\, mol\, L^{-1}$
The experimental data for decomposition of $N _{2} O _{5}$
$\left[2 N _{2} O _{5} \rightarrow 4 NO _{2}+ O _{2}\right]$
in gas phase at $318 \,K$ are given below:
$t/s$ | $0$ | $400$ | $800$ | $1200$ | $1600$ | $2000$ | $2400$ | $2800$ | $3200$ |
${10^2} \times \left[ {{N_2}{O_5}} \right]/mol\,\,{L^{ - 1}}$ | $1.63$ | $1.36$ | $1.14$ | $0.93$ | $0.78$ | $0.64$ | $0.53$ | $0.43$ | $0.35$ |
$(i)$ Plot $\left[ N _{2} O _{5}\right]$ against $t$
$(ii)$ Find the half-life period for the reaction.
$(iii)$ Draw a graph between $\log \left[ N _{2} O _{5}\right]$ and $t$
$(iv)$ What is the rate law $?$
$(v)$ Calculate the rate constant.
$(vi)$ Calculate the half-life period from $k$ and compare it with $(ii)$.