From the rate expression for the following reactions, determine their order of reaction and the dimensions of the rate constants.
$(iv)$ $C _{2} H _{5} Cl ( g ) \rightarrow C _{2} H _{4}( g )+ HCl ( g ) \quad$ Rate $=k\left[ C _{2} H _{5} Cl \right]$
$(iv)$ Given rate $=k\left[ C _{2} H _{5} Cl \right]$ Therefore, order of the reaction $=1$
Dimension of $k=\frac{\text { Rate }}{\left[ C _{2} H _{5} Cl \right]}$
$=\frac{\operatorname{mol}\, L ^{-1} \,s ^{-1}}{ mol \,L ^{-1}}$
$= s ^{-1}$
For the reaction, $2N_2O_5 \to 4NO_2 + O_2$ rate and rate constant are $1.02 \times 10^{-4}\, mol\,L^{-1}\,s^{-1}$ and $3.4 \times10^{-5}\,s^{-1}$ respectively. The concentration of $N_2O_5$ in $mol\,L^{-1}$ will be
Differential form of the rate equation is
$\frac{{dx}}{{dt}} = k\left[ P \right]{\left[ Q \right]^{0.5}}{\left[ R \right]^{0.5}}$
Which statement about the above equation is wrong?
If $R = K{[NO]^2}[{O_2}],$ rate constant may be increased by
Consider the following single step reaction in gas phase at constant temperature.
$2 \mathrm{~A}_{(\mathrm{g})}+\mathrm{B}_{(\mathrm{g})} \rightarrow \mathrm{C}_{(\mathrm{g})}$
The initial rate of the reaction is recorded as $r_1$ when the reaction starts with $1.5 \mathrm{~atm}$ pressure of $\mathrm{A}$ and $0.7 \mathrm{~atm}$ pressure of B. After some time, the rate $r_2$ is recorded when the pressure of $C$ becomes $0.5 \mathrm{~atm}$. The ratio $r_1: r_2$ is $\qquad$ $\times 10^{-1}$.
(Nearest integer)
$2 NO ( g )+ Cl _{2}( g ) \rightleftharpoons 2 NOCl ( s )$
This reaction was studied at $-10^{\circ} C$ and the following data was obtained
run | $[ NO ]_{0}$ | $\left[ Cl _{2}\right]_{0}$ | $r _{0}$ |
$1$ | $0.10$ | $0.10$ | $0.18$ |
$2$ | $0.10$ | $0.20$ | $0.35$ |
$3$ | $0.20$ | $0.20$ | $1.40$ |
$[ NO ]_{0}$ and $\left[ Cl _{2}\right]_{0}$ are the initial concentrations and $r _{0}$ is the initial reaction rate.
The overall order of the reaction is ..........
(Round off to the Nearest Integer).