For a reaction involving substances $x$,$y$,and $z$,if the overall order of the reaction is $0.5$,which of the following rate laws is applicable?

  • A
    Rate $= K [C_x] [C_y] [C_z]$
  • B
    Rate $= K [C_x]^{0.5} [C_y]^{0.5} [C_z]^{0.5}$
  • C
    Rate $= K [C_x]^{1.5} [C_y]^{-1} [C_z]^0$
  • D
    Rate $= K [C_x] [C_z]^0 / [C_y]^2$

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For the elementary reaction $M \rightarrow N$,the rate of disappearance of $M$ increases by a factor of $8$ upon doubling the concentration of $M$. The order of the reaction with respect to $M$ is :

For the reaction $2 NO_{(g)} + Cl_{2_{(g)}} \rightarrow 2NOCl_{(g)}$,when the concentration of $Cl_2$ is doubled,the rate of the reaction becomes twice the original rate. When the concentration of $NO$ is doubled,the rate becomes four times the original rate. What is the overall order of the reaction?

Define the following terms:
$(1)$ Elementary reaction
$(2)$ Complex reaction

During the kinetic study of the reaction,$2A + B \rightarrow C + D,$ the following results were obtained:
$Run$ $[A] / mol \ L^{-1}$ $[B] / mol \ L^{-1}$ Initial rate of formation of $D / mol \ L^{-1} \ min^{-1}$
$I.$ $0.1$ $0.1$ $6.0 \times 10^{-3}$
$II.$ $0.3$ $0.2$ $7.2 \times 10^{-2}$
$III.$ $0.3$ $0.4$ $2.88 \times 10^{-1}$
$IV.$ $0.4$ $0.1$ $2.40 \times 10^{-2}$

Based on the above data,which one of the following is correct?

Write the unit of the rate constant for the following reactions:
$1.$ Fourth order
$2.$ Third order

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