Write differential rate expression of following reaction and give its order of reaction :
$2 N _{2} O _{5} \rightarrow 4 NO _{2}( g )+ O _{2}$
$C _{4} H _{9} Cl + OH ^{-} \rightarrow C _{4} H _{9} OH + Cl ^{-}$
The unit of rate constant for a zero order reaction is
Consider a reaction $\mathrm{aG}+\mathrm{bH} \rightarrow$ Products. When concentration of both the reactants $\mathrm{G}$ and $\mathrm{H}$ is doubled, the rate increases by eight times. However, when concentration of $\mathrm{G}$ is doubled keeping the concentration of $\mathrm{H}$ fixed, the rate is doubled. The overall order of the reaction is
The mechanism of the reaction $A + 2B \to D$ is
$2B\xrightarrow{k}{B_2}\,\left[ {Slow} \right]$
${B_2} + A \to D\,\left[ {Fast} \right]$
The rate law expression, order with respect to $A$, order with respect to $'B'$ and overall order of reaction are respectively
Select the rate law that corresponds to the data shown for the following reaction $A+ B\to C$
Expt. No. | $(A)$ | $(B)$ | Initial Rate |
$1$ | $0.012$ | $0.035$ | $0.10$ |
$2$ | $0.024$ | $0.070$ | $0.80$ |
$3$ |
$0.024$ |
$0.035$ | $0.10$ |
$4$ | $0.012$ | $0.070$ | $0.80$ |
In a reaction involving hydrolysis of an organic chloride in presence of large excess of water$RCl + {H_2}O \to ROH + HCl$