Write about the Wolff-Kishner reduction reaction. Or,write the reduction reaction of aldehydes and ketones by the Wolff-Kishner reduction reaction.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The Wolff-Kishner reduction is a chemical reaction used to reduce the carbonyl group of aldehydes and ketones to a $CH_{2}$ group.
Mechanism and Reaction:
$1$. The aldehyde or ketone is first treated with hydrazine $(NH_{2}NH_{2})$ to form a hydrazone intermediate,with the loss of a water molecule $(H_{2}O)$.
$2$. The hydrazone is then heated (at $453-473 \ K$) with a strong base like potassium hydroxide $(KOH)$ in a high-boiling solvent such as ethylene glycol.
$3$. This process results in the evolution of nitrogen gas $(N_{2})$ and the formation of the corresponding hydrocarbon.
General Reaction:
$>C=O + NH_{2}-NH_{2}$ $\xrightarrow{-H_{2}O} >C=N-NH_{2}$ $\xrightarrow{KOH, \Delta, \text{ethylene glycol}} >CH_{2} + N_{2}$
Example $1$: Reduction of acetaldehyde to ethane
$CH_{3}CHO + NH_{2}NH_{2}$ $\rightarrow CH_{3}CH=NNH_{2}$ $\xrightarrow{KOH, \text{glycol}, \Delta} CH_{3}CH_{3} + N_{2}$
Example $2$: Reduction of acetone to propane
$(CH_{3})_{2}CO + NH_{2}NH_{2}$ $\rightarrow (CH_{3})_{2}C=NNH_{2}$ $\xrightarrow{KOH, \text{glycol}, \Delta} CH_{3}CH_{2}CH_{3} + N_{2}$

Explore More

Similar Questions

What is $X$ in the following reaction?
$2 CH_3COCH_3 \stackrel{Ba(OH)_2}{\longrightarrow} X$

Which of the following is not the product of an intramolecular aldol condensation?

Which one of the following aldehydes will not form an aldol when treated with $dil. \, NaOH$?

The product $B$ is formed by the reaction of cyclohexanone with hydroxylamine $(NH_2OH)$ to form an oxime $(A)$,followed by a Beckmann rearrangement using polyphosphoric acid $(PPA)$. Identify the product $B$.

Difficult
View Solution

The major product of which of the following reactions is not obtained by a rearrangement reaction?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo