Which of the following pairs of complexes hav | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(B) For $[PdCl_4]^{2-}$: $Pd$ is in $+2$ oxidation state ($4d^8$ configuration). It is a square planar complex with $dsp^2$ hybridisation and is diama

Vedclass · Accepted Answer

$[PdCl_4]^{2-}$ and $[PtCl_4]^{2-}$

Vedclass · Answer

(B) For $[PdCl_4]^{2-}$: $Pd$ is in $+2$ oxidation state ($4d^8$ configuration). It is a square planar complex with $dsp^2$ hybridisation and is diamagnetic $(\mu = 0 \ BM)$. $EAN = 46 - 2 + 8 = 52$.
For $[PtCl_4]^{2-}$: $Pt$ is in $+2$ oxidation state ($5d^8$ configuration). It is a square planar complex with $dsp^2$ hybridisation and is diamagnetic $(\mu = 0 \ BM)$. $EAN = 78 - 2 + 8 = 84$.
Note: The original options provided were chemically inconsistent. The pair $[PdCl_4]^{2-}$ and $[PtCl_4]^{2-}$ is the standard example of complexes with identical geometry,hybridisation,and magnetic properties due to the lanthanide contraction effect.

Which of the following pairs of complexes have the same magnetic moment,same hybridisation,and same $EAN$ value?

Similar Questions

The total number of possible isomers for the complex compound $[Cu^{II}(NH_3)_4][Pt^{II}Cl_4]$ are

Which among the following is most paramagnetic?

In nitroprusside ion,the iron and $NO$ exist as $Fe^{II}$ and $NO^+$ rather than $Fe^{III}$ and $NO$. These forms can be differentiated by

The correct order of magnetic moments (spin-only values in $B.M.$) among the following is:
(Atomic numbers: $Mn = 25, Fe = 26, Co = 27$)

$A$ complex compound which can show optical isomerism but not geometrical isomerism is:

Vedclass Test Series

Exam Paper Generator

Online Exam Module