Which of the following statements is correct?

  • A
    Molecularity of a reaction can be fractional.
  • B
    Zero order reaction never stops.
  • C
    $A$ first order reaction must be homogeneous.
  • D
    The rate constant of a reaction becomes equal to the pre-exponential factor when the absolute temperature is infinity.

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According to the collision theory,which of the following statements is $NOT$ correct?

In a reaction, for every $10^{\circ} C$ rise of temperature, the rate is doubled. If the temperature is increased from $10^{\circ} C$ to $100^{\circ} C$, the rate of the reaction will become $:-$ (in $times$)

The rate constants for the decomposition of acetaldehyde have been measured over the temperature range $700-1000 \ K$. The data has been analysed by plotting a $\ln \ k \ vs \ \frac{10^{3}}{T}$ graph,which gives a slope of $-18.5$. The value of activation energy for the reaction is $...... \ kJ \ mol^{-1}$. (Nearest integer) (Given: $R = 8.31 \ J \ K^{-1} \ mol^{-1}$)

If the half-lives of a first-order reaction at $350 \ K$ and $300 \ K$ are $2 \ s$ and $20 \ s$ respectively,the activation energy of the reaction in $kJ \ mol^{-1}$ is:

For a certain gaseous reaction,the temperature is increased by $10\,^{\circ}C$ from $25\,^{\circ}C$ to $35\,^{\circ}C$. If the rate of the reaction doubles,what will be the value of the activation energy $(E_a)$?

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