Which among the following reactions does not occur?

  • A
    $C_2H_5Br + AgNO_2 \rightarrow C_2H_5NO_2 + AgBr$
  • B
    $C_2H_5Br + AgCN \rightarrow C_2H_5NC + AgBr$
  • C
    $C_2H_5Br + KCN \rightarrow C_2H_5NC + KBr$
  • D
    $C_2H_5Br + KNO_2 \rightarrow C_2H_5-O-N=O + KBr$

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The major product obtained in the above reaction is

The major product of the following reaction is:

Which of the following procedures would be best for achieving the following reaction?

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For each of the following pairs of $E_2$ reactions,select the one that occurs with the greater rate constant:
$(1)$ $CH_3-CH_2-CH_2-Cl + CH_3-C(CH_3)_2-O^-$
$(2)$ $CH_3-CH_2-CH_2-I + CH_3-C(CH_3)_2-O^-$
$(3)$ $CH_3-CH(Br)-CH_3 + CH_3-O^-$
$(4)$ $CH_3-CH(Br)-CH_3 + CH_3-S^-$
$(5)$ $Ph-CH_2-CH(Br)-CH_2-CH_3 + OH^-$
$(6)$ $Ph-CH_2-CH_2-CH(Br)-CH_3 + OH^-$

Which describes the best stereochemical aspects of the following reaction?
$Ph-C(CH_3)(CD_3)(OH) + HBr \rightarrow \text{Product}$

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