What is the main difference between $P \to T$ diagram of water and $C{O_2}$ ?

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The slope of fusion curve for water is negative while for $\mathrm{CO}_{2}$ gas it is positive.

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Values for latent heat in Column$-\,I$ and its values are given in Column$-\,II$. Match the followings :

Column $-\,I$ Column $-\,II$
$(a)$ Latent heat of vaporization $L_V$ $(i)$ $22.6\, \times \,{10^5}\,J\,/kg$
$(b)$ Latent heat of fusion $L_f$ $(ii)$ $33.3\, \times \,{10^5}\,J\,/kg$
    $(iii)$ $3.33\, \times \,{10^5}\,J\,/kg$