The rate law for a reaction between the substances $ A $ and $B$ is given by, rate $= k{[A]^n}{[B]^m}$. On doubling the concentration of $A$ and halving the concentration of $B$, the ratio of the new rate to the earlier rate of the reaction will be as
$\frac{1}{{{2^{(m + n)}}}}$
$(m + n)$
$(n - m)$
${2^{(n - m)}}$
Why is the probability of reaction with molecularity higher than three very rare ?
If $R = K{[NO]^2}[{O_2}],$ rate constant may be increased by
Write the rate equation for the reaction $2A + B\to C$ if the order of the reaction is zero.
The following mechanism has been proposed for the reaction of $NO$ with $Br_2$ to form $NOBr$ :
$NO(g) + Br_2 (g) \rightleftharpoons NOBr_2 (g)$
$NOBr_2(g)+ NO(g) \longrightarrow 2NOBr(g)$
If the second step is the rate determining step, the order of the reaction with respect to $NO(g)$ is
For the decomposition of azoisopropane to hexane and nitrogen at $543$ $K ,$ the following data are obtained.
$t$ $(sec)$ | $P(m m \text { of } H g)$ |
$0$ | $35.0$ |
$360$ | $54.0$ |
$720$ | $63.0$ |
Calculate the rate constant.