The possible mechanism for the reaction
$2NO + Br \to 2NOBr$ is
$NO + Br_2 \rightleftharpoons NOBr_2$ (Fast)
$NOBr_2 + NO \to 2NOBr$ (Slow)
The rate law expression is
$r = K\, [NO][Br_2]$
$r = K\, [NO][NOBr_2]^2$
$r = K\, [NO]^2[Br_2]$
$r = K \,[NOBr_2][NO]^2[Br_2]$
For a reaction $2A + B \to $ Products, doubling the initial concentration of both the reactants increases the rate by a factor of $8$, and doubling the concentration of $+B$ alone doubles the rate. The rate law for the reaction is
When a reaction is progressing
Time required for completion of ionic reactions in comparison to molecular reactions is
Write the rate equation for the reaction $2A + B\to C$ if the order of the reaction is zero.
In a chemical reaction $A$ is converted into $B$ . The rates of reaction, starting with initial concentrations of $A$ as $2 \times {10^{ - 3}}\,M$ and $1 \times {10^{ - 3}}\,M$ , are equal to $2.40 \times {10^{ - 4}}\,M{s^{ - 1}}$ and $0.60 \times {10^{ - 4}}\,M{s^{ - 1}}$ respectively. The order of reaction with respect to reactant $A$ will be