The mechanism of the reaction,$2NO_{(g)} + 2H_{2(g)} \to N_{2(g)} + 2H_2O_{(g)}$ is:
Step $1$: $2NO_{(g)} + H_{2(g)} \xrightarrow{\text{slow}} N_2 + H_2O_2$
Step $2$: $H_2O_2 + H_2 \xrightarrow{\text{fast}} 2H_2O$
Then the correct statement is:

  • A
    Rate $= k [NO]^2 [H_2]$
  • B
    Rate $= k [H_2O_2] [H_2]$
  • C
    On doubling the concentration of $H_2$,keeping the concentration of $NO$ constant,the rate will become double
  • D
    If the initial concentration of $H_2$ and $NO$ is $C_0$ and after time $t$ the concentration of $N_2$ is $x$,then Rate $= k (C_0 - 2x)^2$

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$A$ reaction $2A + B \xrightarrow{k} C + D$ is first order with respect to $A$ and second order with respect to $B$. Initial concentration $(t = 0)$ of $A$ is $C_0$ while $B$ is $2C_0$. If at $t = 30 \min$ the concentration of $C$ is $C_0/4$,then the rate expression at $t = 30 \min$ is:

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The mechanism of the reaction $2NO_2 + F_2 \to 2NO_2F$ is given by:
$(i)$ $NO_2 \xrightarrow{slow} NO + O$
$(ii)$ $F_2 + O + NO \xrightarrow{fast} NO_2F + F$
$(iii)$ $F + NO_2 \xrightarrow{fast} NO_2F$
Select the correct statement.

In a multistep reaction,the overall rate of reaction is equal to the

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