The boiling point of water in a $0.1 \ m$ molal silver nitrate solution (solution $A$) is $x \ ^{\circ}C$. To this solution $A$,an equal volume of $0.1 \ m$ molal aqueous barium chloride solution is added to make a new solution $B$. The difference in the boiling points of water in the two solutions $A$ and $B$ is $y \times 10^{-2} \ ^{\circ}C$. (Assume: Densities of the solutions $A$ and $B$ are the same as that of water and the soluble salts dissociate completely. Use: Molal elevation constant,$K_b = 0.5 \ K \ kg \ mol^{-1}$; Boiling point of pure water as $100 \ ^{\circ}C$.) $(1)$ The value of $x$ is $(2)$ The value of $|y|$ is

  • A
    $100.1, 2.50$
  • B
    $101, 2.55$
  • C
    $102, 2.60$
  • D
    $103, 2.66$

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$6 \ g$ of a mixture of naphthalene $(C_{10}H_8)$ and anthracene $(C_{14}H_{10})$ is dissolved in $300 \ g$ of benzene. If the depression in freezing point is $0.70 \ K$,the composition of naphthalene and anthracene in the mixture respectively in $g$ are (molal depression constant of benzene is $5.1 \ K \ kg \ mol^{-1}$)

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