The $pH$ of a $0.1 \, M$ monobasic acid is measured to be $2$. Its osmotic pressure at a given temperature $T \, K$ is (in $, RT$)

Match the following.

List-$I$	List-$II$
$(A)$ Azeotrope	$(I)$ $\Delta T_b = i K_b m$
$(B)$ Henry's law	$(II)$ $p = K_H x$
$(C)$ Cryoscopic constant	$(III)$ $\Delta T_f / m$
$(D)$ Van't Hoff factor	$(IV)$ Deviation from Raoult's law
	$(V)$ $\pi = CRT$

The correct answer is

Which of the following graphs correctly represents the changes in thermodynamic properties during the formation of $1 \, mol$ of an ideal binary solution?

Assertion : Lowering of vapour pressure is directly proportional to osmotic pressure of the solution.
Reason : Osmotic pressure is a colligative property.

$6 \ g$ of a mixture of naphthalene $(C_{10}H_8)$ and anthracene $(C_{14}H_{10})$ is dissolved in $300 \ g$ of benzene. If the depression in freezing point is $0.70 \ K$,the composition of naphthalene and anthracene in the mixture respectively in $g$ are (molal depression constant of benzene is $5.1 \ K \ kg \ mol^{-1}$)

The values of $K_b$ and $K_f$ for water are $0.52 \, K \, kg \, mol^{-1}$ and $1.86 \, K \, kg \, mol^{-1}$ respectively. If the solution boils at $0.78 \, K$ above the boiling point of water,then the freezing point of the solution will be ........ $K$.