Sometimes a radioactive nucleus decays into a nucleus which itself is radioactive. An example is
$^{38}S \xrightarrow{2.48 \ h} ^{38}Cl \xrightarrow{0.62 \ h} ^{38}Ar$
Assume that we start with $1000$ $^{38}S$ nuclei at time $t = 0$. The number of $^{38}Cl$ nuclei is zero at $t = 0$ and will again be zero at $t = \infty$. At what value of $t$ would the number of $^{38}Cl$ nuclei be a maximum?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(C) Let $N_1$ be the number of $^{38}S$ nuclei and $N_2$ be the number of $^{38}Cl$ nuclei.
The decay constants are $\lambda_1 = \frac{\ln 2}{2.48} \approx 0.2794 \ h^{-1}$ and $\lambda_2 = \frac{\ln 2}{0.62} \approx 1.118 \ h^{-1}$.
The rate of change of $N_2$ is given by $\frac{dN_2}{dt} = \lambda_1 N_1 - \lambda_2 N_2$.
For $N_2$ to be maximum,$\frac{dN_2}{dt} = 0$,which implies $\lambda_1 N_1 = \lambda_2 N_2$.
The number of nuclei at time $t$ is $N_1(t) = N_0 e^{-\lambda_1 t}$.
The solution for $N_2(t)$ is $N_2(t) = N_0 \frac{\lambda_1}{\lambda_2 - \lambda_1} (e^{-\lambda_1 t} - e^{-\lambda_2 t})$.
Setting $\frac{dN_2}{dt} = 0$ leads to $t_{max} = \frac{\ln(\lambda_2 / \lambda_1)}{\lambda_2 - \lambda_1}$.
Substituting the values: $t_{max} = \frac{\ln(1.118 / 0.2794)}{1.118 - 0.2794} = \frac{\ln(4)}{0.8386} \approx \frac{1.386}{0.8386} \approx 1.65 \ h$.

Explore More

Similar Questions

An element $A$ decays into element $C$ by a two-step process:
$A \to B + {\;_2}He^4$
$B \to C + 2e^-$
Then:

$A$ nucleus of mass $218\, amu$ in a free state decays to emit an $\alpha$-particle. The kinetic energy of the emitted $\alpha$-particle is $6.7\, MeV$. The recoil energy (in $MeV$) of the daughter nucleus is:

$A$ nucleus $_n^mX$ emits one $\alpha$ particle and two $\beta^-$ particles. The resulting nucleus is

The decay of a proton to a neutron is:

$A$ radioactive element $X$ emits six $\alpha$-particles and four $\beta$-particles,leading to the final product ${ }_{82}^{208} Pb$. The element $X$ is:

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo