Rate law for the reaction $aA + bB \rightarrow cC + dD$ is $r = k[A][B]$. Which of the following conditions does $NOT$ affect the rate of reaction?

  • A
    Concentration of $A$ is doubled and concentration of $B$ is kept constant.
  • B
    Concentration of $B$ is doubled and concentration of $A$ is kept constant.
  • C
    Concentration of $B$ is doubled and concentration of $A$ is halved.
  • D
    Concentration of $A$ is kept constant and concentration of $B$ is halved.

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For a certain reaction,the rate $= k[A]^2[B]$. When the initial concentration of $A$ is tripled keeping the concentration of $B$ constant,the initial rate would:

When the concentration of $A$ in the reaction $A + B \rightleftharpoons AB$ is doubled,the rate of reaction will be

For the reaction ${H_{2(g)} + I_{2(g)} \to 2HI_{(g)}}$,the possible mechanism is given below:
$I_2 \underset{k_{-1}}{\stackrel{k_1}{\rightleftharpoons}} 2 I$ (fast step)
${2I + H_2 \xrightarrow{K_2} 2HI}$ (slow step)
Determine the rate law for the reaction.

The following results have been obtained during the kinetic studies of the reaction:
$2 A + B \rightarrow C + D$
Experiment $[A] / mol \, L^{-1}$ $[B] / mol \, L^{-1}$ Initial rate of formation of $D / mol \, L^{-1} \, min^{-1}$
$I$ $0.1$ $0.1$ $6.0 \times 10^{-3}$
$II$ $0.3$ $0.2$ $7.2 \times 10^{-2}$
$III$ $0.3$ $0.4$ $2.88 \times 10^{-1}$
$IV$ $0.4$ $0.1$ $2.40 \times 10^{-2}$

Determine the rate law and the rate constant for the reaction.

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$1 \ L$ of $2 \ M$ $CH_3COOH$ is mixed with $1 \ L$ of $3 \ M$ $C_2H_5OH$ to form an ester. The rate of the reaction with respect to the initial rate when each solution is diluted with an equal volume of water will be (in times).

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