In the following reaction,
$C_6H_5NHCOC_6H_5 \xrightarrow[conc. \ H_2SO_4]{conc. \ HNO_3} X$
the structure of the major product $X$ is

  • A
    $N$-($3$-nitrophenyl)benzamide
  • B
    $N$-($4$-nitrophenyl)benzamide
  • C
    $N$-phenyl$-3-$nitrobenzamide
  • D
    $N$-phenyl$-4-$nitrobenzamide

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$A$ mixture of ethyl amine,chloroform,and alcoholic $KOH$ on heating gives:

Assertion : Acetamide reacts with $Br_2$ in presence of methanolic $CH_3ONa$ to form methyl $N$-methylcarbamate.
Reason : Methyl isocyanate is formed as an intermediate which reacts with methanol to form methyl $N$-methylcarbamate.

Identify the product $B$ in the following reaction sequence:
$F-C_6H_4-NO_2 \xrightarrow[(ii) H_2/Ni]{(CH_3)_2NH, DMF, \Delta} (B)$

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Reduction of nitrobenzene with $Zn$ and alcoholic $KOH$ solution results in the formation of the following compound:

When a primary amine is heated with $NaNO_2/HCl$,a gas is evolved with brisk effervescence. Identify the gas.
$R-NH_2 \xrightarrow{NaNO_2/HCl} ..................$

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