Identify the false statement from the following.
- AThe boiling point of a solution containing a non-volatile solute is always higher than that of the pure solvent.
- BAt any temperature,the vapour pressure of a solution containing a non-volatile solute is lower than that of the pure solvent.
- CThe boiling point of a liquid is the temperature at which its vapour pressure equals atmospheric pressure.
- DThe molal elevation constant is the boiling point elevation produced by a $1$ molal solution.
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An aqueous solution of urea (molar mass $60 \ g \ mol^{-1}$) boils at $100.18 \ ^\circ C$ at $1 \ atm$ pressure. If $K_f$ and $K_b$ for water are $1.86$ and $0.512 \ K \ kg \ mol^{-1}$ respectively,at what temperature will this solution freeze (in $K$)?
Medium
View SolutionThe number of pairs of solutions having the same value of osmotic pressure from the following is:
(Assume $100\%$ ionization)
$A.$ $0.500 \ M \ C_2H_5OH \ (aq)$ and $0.25 \ M \ KBr \ (aq)$
$B.$ $0.100 \ M \ K_4[Fe(CN)_6] \ (aq)$ and $0.100 \ M \ FeSO_4(NH_4)_2SO_4 \ (aq)$
$C.$ $0.05 \ M \ K_4[Fe(CN)_6] \ (aq)$ and $0.25 \ M \ NaCl \ (aq)$
$D.$ $0.15 \ M \ NaCl \ (aq)$ and $0.1 \ M \ BaCl_2 \ (aq)$
$E.$ $0.02 \ M \ KCl \cdot MgCl_2 \cdot 6H_2O \ (aq)$ and $0.05 \ M \ KCl \ (aq)$
(Assume $100\%$ ionization)
$A.$ $0.500 \ M \ C_2H_5OH \ (aq)$ and $0.25 \ M \ KBr \ (aq)$
$B.$ $0.100 \ M \ K_4[Fe(CN)_6] \ (aq)$ and $0.100 \ M \ FeSO_4(NH_4)_2SO_4 \ (aq)$
$C.$ $0.05 \ M \ K_4[Fe(CN)_6] \ (aq)$ and $0.25 \ M \ NaCl \ (aq)$
$D.$ $0.15 \ M \ NaCl \ (aq)$ and $0.1 \ M \ BaCl_2 \ (aq)$
$E.$ $0.02 \ M \ KCl \cdot MgCl_2 \cdot 6H_2O \ (aq)$ and $0.05 \ M \ KCl \ (aq)$
DifficultJEE MAIN 2023
View SolutionWhen a solute is added to a solvent,the freezing point of the solution decreases to $1.86 \ K$. What is the value of $\Delta T_b$? $[K_f = 1.86, K_b = 0.512]$
Medium
View SolutionCalculate the osmotic pressure in $atm$ of an aqueous solution of urea at $37\,^oC$,which has a freezing point of $0.52\,^oC$. Assume molality and molarity are numerically equal. $(K_f = 1.86\,^oC\, m^{-1})$
Medium
View SolutionWhich one of the following statements is false?
Easy
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