Gases deviate from ideal behaviour at high pressures because the gas molecules

Which statement is correct regarding a real gas?

The relation between pressure exerted by an ideal gas $(P_{ideal})$ and observed pressure $(P_{real})$ is given by the equation
$P_{ideal} = P_{real} + \frac{an^2}{V^2}$
$(i)$ If pressure is taken in $N \ m^{-2}$,number of moles in $mol$,and volume in $m^3$,calculate the unit of $a$.
$(ii)$ What will be the unit of $a$ when pressure is in atmosphere and volume in $dm^3$?

The Van der Waals equation reduces itself to the ideal gas equation at

At a temperature of $27\,^{\circ}C$,if the volume of $2\, \text{moles}$ of $NH_3$ gas is $5\, L$ according to the van der Waals equation,what will be its pressure in $atm$? ($a = 4.17$,$b = 0.03711$)

Which of the curves $(Z \ vs \ p)$ will be followed by a real gas?