The relation between pressure exerted by an ideal gas $(P_{ideal})$ and observed pressure $(P_{real})$ is given by the equation
$P_{ideal} = P_{real} + \frac{an^2}{V^2}$
$(i)$ If pressure is taken in $N \ m^{-2}$,number of moles in $mol$,and volume in $m^3$,calculate the unit of $a$.
$(ii)$ What will be the unit of $a$ when pressure is in atmosphere and volume in $dm^3$?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Given the equation: $P_{ideal} = P_{real} + \frac{an^2}{V^2}$
$(i)$ Rearranging for $a$: $a = \frac{(P_{ideal} - P_{real}) \cdot V^2}{n^2}$
Since the term $\frac{an^2}{V^2}$ must have the same units as pressure $(P)$:
Units of $a = \frac{\text{Units of } P \cdot (\text{Units of } V)^2}{(\text{Units of } n)^2}$
Given $P = N \ m^{-2}$,$V = m^3$,and $n = mol$:
Units of $a = \frac{N \ m^{-2} \cdot (m^3)^2}{(mol)^2} = N \ m^4 \ mol^{-2}$
$(ii)$ Given $P = atm$,$V = dm^3$,and $n = mol$:
Units of $a = \frac{atm \cdot (dm^3)^2}{(mol)^2} = atm \ dm^6 \ mol^{-2}$

Explore More

Similar Questions

For a gas at $STP$,the compressibility factor is greater than $1$. What will be the value of its molar volume $(V_m)$?

$A$ gas such as carbon monoxide would be most likely to obey the ideal gas law at

At low pressure,the van der Waals equation becomes:

When is deviation more in the behaviour of a gas from the ideal gas equation $PV = nRT$?

At low pressures,van der Waals' equation is written as $(P + \frac{a}{V^2})V = RT$. The compressibility factor $Z$ will be

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo