For the reaction $X_2Y_{4(l)} \rightarrow 2XY_{2(g)}$ at $300 \ K$,the values of $\Delta U$ and $\Delta S$ are $2 \ kcal$ and $20 \ cal \ K^{-1}$ respectively. The value of $\Delta G$ for the reaction is (in $cal$)

  • A
    $-3400$
  • B
    $3400$
  • C
    $-2800$
  • D
    $2000$

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The molar heat capacity $(C_p)$ of $CD_2O$ is $10 \, cal \, K^{-1} \, mol^{-1}$ at $1000 \, K$. The change in entropy associated with cooling of $32 \, g$ of $CD_2O$ vapour from $1000 \, K$ to $100 \, K$ at constant pressure will be.....$cal \, deg^{-1}$ ($D = $ deuterium,atomic mass $= 2 \, u$)

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