The molar heat capacity $(C_p)$ of $CD_2O$ is $10 \, cal \, K^{-1} \, mol^{-1}$ at $1000 \, K$. The change in entropy associated with cooling of $32 \, g$ of $CD_2O$ vapour from $1000 \, K$ to $100 \, K$ at constant pressure will be.....$cal \, deg^{-1}$ ($D = $ deuterium,atomic mass $= 2 \, u$)

One mole of an ideal monoatomic gas is heated in a process $PV^{5/2} = \text{constant}$. The amount of heat absorbed in the process for a $36 \ ^\circ C$ rise in temperature is (in $cal$):

For the following reaction $Fe_2O_{3(s)} + 3 CO_{(g)} \longrightarrow 2 Fe_{(s)} + 3 CO_{2(g)}$,$\Delta H^{\circ} = -29.8 \ kJ$ and $\Delta S^{\circ} = 15 \ JK^{-1}$. What is the value of $\Delta S_{\text{total}}$ at $298 \ K$ (in $JK^{-1}$)?

Match the following items in List-$I$ with their corresponding expressions in List-$II$.

List-$I$	List-$II$
$A$. At constant volume the change in internal energy of a system	$I$. $W = -2.303 nRT \log \frac{V_f}{V_i}$
$B$. Isothermal irreversible change	$II$. $W_{adiabatic} = \Delta U$
$C$. Isothermal reversible change	$III$. $q_V = \Delta U$
$D$. Adiabatic change	$IV$. $W = -p_{ex} (V_f - V_i)$
	$V$. $\Delta U = \Delta H - \Delta nRT$

The $C_p$ of an ideal gas is $10.314 \ J \ mol^{-1} \ K^{-1}$. One mole of this gas is expanded against a constant pressure of $p \ atm$. The change in temperature during expansion is $1.0 \ K$. The values of $q$ (in $J$) and $\Delta H$ (in $J \ mol^{-1}$) are respectively

$200 \ mL$ of $0.2 \ M \ HCl$ is mixed with $300 \ mL$ of $0.1 \ M \ NaOH$. The molar heat of neutralization of this reaction is $-57.1 \ kJ \ mol^{-1}$. The increase in temperature in $^{\circ}C$ of the system on mixing is $x \times 10^{-2}$. The value of $x$ is ....... . (Nearest integer)
[Given : Specific heat of water $= 4.18 \ J \ g^{-1} \ K^{-1}$
Density of water $= 1.00 \ g \ cm^{-3}$]
(Assume no volume change on mixing)