Consider the reaction at $300 \ K$:
$C_6H_{6(l)} + \frac{15}{2}O_{2(g)} \longrightarrow 6CO_{2(g)} + 3H_2O_{(l)} ; \Delta H = -3271 \ kJ$
What is $\Delta U$ for the combustion of $1.5 \ mol$ of benzene at $27 \ ^\circ C$? .....$kJ$

  • A
    $-3267.25$
  • B
    $-4900.88$
  • C
    $-4906.5$
  • D
    $-3274.75$

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Enthalpy of combustion of $CH_4, C_2H_6$ and $C_3H_8$ are $-210.8, -368.4$ and $-526.2 \ k \ cal \ mol^{-1}$ respectively. Enthalpy of combustion of hexane can be predicted as........$k \ cal \ mol^{-1}$

Given below are two statements:
Statement-$I$: For isothermal irreversible change of an ideal gas,$q = -w = P_{\text{ext}} (V_{\text{final}} - V_{\text{initial}})$
Statement-$II$: For adiabatic change,$\Delta U = W_{\text{adiabatic}}$
The correct answer is

$CsOH + HCl \to CsCl + H_2O$,$\Delta H = -13.4 \ K \ cal/mol$
$CsOH + HA \to CsA + H_2O$,$\Delta H = -10.4 \ K \ cal/mol$
Then calculate $\Delta H$ of ionisation of $HA$ in $K \ cal/mol$.

The reaction $NH_2CN_{(s)} + \frac{3}{2}O_{2(g)} \to N_{2(g)} + CO_{2(g)} + H_2O_{(l)}$ is carried out in a bomb calorimeter. The heat evolved is $743 \ kJ \ mol^{-1}$. Calculate the value of $\Delta H$ at $300 \ K$ in $kJ \ mol^{-1}$.

Difficult
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Calculate the enthalpy change on freezing of $1.0 \ mol$ of water at $10.0^{\circ} C$ to ice at $-10.0^{\circ} C$. Given: $\Delta_{fus} H = 6.03 \ kJ \ mol^{-1}$ at $0^{\circ} C$,$C_p [H_2 O_{(l)}] = 75.3 \ J \ mol^{-1} \ K^{-1}$,$C_p [H_2 O_{(s)}] = 36.8 \ J \ mol^{-1} \ K^{-1}$.

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