For the non - stoichimetre reaction $2A + B \rightarrow C + D,$ the following kinetic data were obtained in three separate experiments, all at $298\, K.$
Initial Concentration $(A)$ |
Initial Concentration $(A)$ |
Initial rate of formation of $C$ $(mol\,L^{-1}\,s^{-1})$ |
$0.1\,M$ | $0.1\,M$ | $1.2\times 10^{-3}$ |
$0.1\,M$ | $0.2\,M$ | $1.2\times 10^{-3}$ |
$0.2\,M$ | $0.1\,M$ | $2.4 \times 10^{-3}$ |
The rate law for the formation of $C$ is :
$\frac{{dc}}{{dt}} = k[A][B]$
$\frac{{dc}}{{dt}} = k[A]^2[B]$
$\frac{{dc}}{{dt}} = k[A][B]^2$
$\frac{{dc}}{{dt}} = k[A]$
Select the rate law that corresponds to the data shown for the following reaction $A+ B\to C$
Expt. No. | $(A)$ | $(B)$ | Initial Rate |
$1$ | $0.012$ | $0.035$ | $0.10$ |
$2$ | $0.024$ | $0.070$ | $0.80$ |
$3$ |
$0.024$ |
$0.035$ | $0.10$ |
$4$ | $0.012$ | $0.070$ | $0.80$ |
The hypothetical reaction : $2A + B \to C + D$ is catalyzed by $E$ as indicated in the possible mechanism below -
Step$-1$ : ${\text{A + E }} \rightleftharpoons AE$ (fast)
Step$-2$ :${\text{AE + A }} \to {A_2} + E$ (slow)
Step$-3$ :${{\text{A}}_2}{\text{ + B }} \to {\text{D}}$ (fast)
what rate law best agrees with this mechanism
Select the rate law for reaction $A + B \longrightarrow C$
Exp | $[A]$ | $[B]$ | Rate |
$1$ | $0.012$ | $0.035$ | $0.10$ |
$2$ | $0.024$ | $0.070$ | $0.80$ |
$3$ | $0.024$ | $0.035$ | $0.10$ |
$4$ | $0.012$ | $0.070$ | $0.80$ |
The rate of reaction, $A + B + C \longrightarrow P$ is given by
$r = \frac{{ - d\left[ A \right]}}{{dt}} = K\,{\left[ A \right]^{\frac{1}{2}}}\,{\left[ B \right]^{\frac{1}{2}}}\,{\left[ C \right]^{\frac{1}{4}}}$
The order of reaction is
If doubling the initial concentration of reactant doubles $t_{1/2}$ of reaction, the order of reaction is