(N/A) The electron gain enthalpy values of $17^{\text{th}}$ group elements (halogens) are highly negative because they have a general electronic configuration of $ns^{2} np^{5}$. They require only one electron to achieve the stable noble gas configuration $(ns^{2} np^{6})$,making the process highly exothermic.
Although fluorine $(F)$ has the smallest size,its electron gain enthalpy is less negative than that of chlorine $(Cl)$. This is due to the strong inter-electronic repulsions in the relatively small $2p$ subshell of fluorine,which makes the addition of an electron less favorable compared to chlorine.
As we move down the group from $Cl$ to $At$,the atomic size increases,which decreases the effective nuclear attraction for the incoming electron,resulting in a decrease in the magnitude of negative electron gain enthalpy.
| Element | $F$ | $Cl$ | $Br$ | $I$ | $At$ |
| $\Delta_{eg} H \ (kJ \ mol^{-1})$ | $-328$ | $-349$ | $-325$ | $-295$ | $-279$ |