Define hydrogen bond. Is it weaker or stronger than the van der Waals forces?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) hydrogen bond is defined as an attractive force acting between the hydrogen atom attached to an electronegative atom of one molecule and an electronegative atom of a different molecule (or the same molecule).
Due to the difference in electronegativities,the bond pair between hydrogen and the electronegative atom is shifted away from the hydrogen atom. As a result,the hydrogen atom acquires a partial positive charge $(H^{\delta+})$ and the electronegative atom acquires a partial negative charge $(X^{\delta-})$.
$H^{\delta+} - X^{\delta-} \dots\dots H^{\delta+} - X^{\delta-} \dots\dots H^{\delta+} - X^{\delta-}$
The magnitude of $H$-bonding is maximum in the solid state and minimum in the gaseous state.
There are two types of $H$-bonds:
$(i)$ Intermolecular $H$-bond,e.g.,$HF$,$H_2O$.
$(ii)$ Intramolecular $H$-bond,e.g.,$o$-nitrophenol (as shown in the structure).
Hydrogen bonds are stronger than van der Waals forces because hydrogen bonds are considered an extreme form of dipole-dipole interaction.

Explore More

Similar Questions

Explain the types of Hydrogen bond,provide examples,and discuss their effect on physical properties.

Difficult
View Solution

Water is liquid due to

In which of the following compounds is hydrogen bonding $NOT$ present?

In which of the following compounds does hydrogen bonding not play a role in its boiling point?

The strongest intermolecular hydrogen bond is present in which of the following pairs of molecules?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo