Consider the reaction $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$. The equilibrium constant of the above reaction is $K_p$. If pure ammonia is left to dissociate,the partial pressure of ammonia at equilibrium is given by (Assume that $P_{NH_3} \ll P_{total}$ at equilibrium and $P$ is the total pressure).

  • A
    $\frac{3^{3/2}K_p^{1/2}P^2}{16}$
  • B
    $\frac{K_p^{1/2}P^2}{16}$
  • C
    $\frac{K_p^{1/2}P^2}{4}$
  • D
    $\frac{3^{3/2}K_p^{1/2}P^2}{4}$

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For a reaction $A_{(s)} \rightleftharpoons B_{(s)} + C_{(g)}$,the set of all correct statements are:
$(a) \ K$ is independent of $[A]$.
$(b) \ K$ is dependent on partial pressure of $C$ at a given temperature.
$(c) \ \Delta H$ will be independent of temperature.
$(d) \ \Delta H$ is independent of the catalyst addition.

Solid carbon,$CaO$ and $CaCO_3$ are mixed and allowed to attain equilibrium at $T \text{ K}$. $CaCO_3(s) \rightleftharpoons CaO(s) + CO_2(g)$ $K_{p1} = 0.08 \text{ atm}$. $C(s) + CO_2(g) \rightleftharpoons 2CO(g)$ $K_{p2} = 2 \text{ atm}$. The partial pressure of $CO$ is . . . . . . $\times 10^{-1} \text{ atm}$.

$0.6 \ mol$ of $NH_3$ in a reaction vessel of $2 \ dm^3$ capacity was brought to equilibrium. The vessel was then found to contain $0.15 \ mol$ of $H_2$ formed by the reaction $2NH_{3(g)} \rightleftharpoons N_{2(g)} + 3H_{2(g)}$. Which of the following statements is true?

Equilibrium constants for the following reactions are given (pressure in $atm$) for the reactions at $0\,^{\circ}C$. Select the option mentioning the correct order of True $(T)$ or False $(F)$ statements:
$(A) \ A \cdot 6H_2O_{(s)} \rightleftharpoons A \cdot 2H_2O_{(s)} + 4H_2O_{(g)}; \ K_P = 1.6 \times 10^{-11}$
$(B) \ B \cdot 12H_2O_{(s)} \rightleftharpoons B \cdot 7H_2O_{(s)} + 5H_2O_{(g)}; \ K_P = 2.43 \times 10^{-13}$
$(C) \ C \cdot 10H_2O_{(s)} \rightleftharpoons C_{(s)} + 10H_2O_{(g)}; \ K_P = 10^{-30}$
Aqueous tension of $H_2O$ at $0\,^{\circ}C$ is given as $0.76 \ torr$.
$(I)$ The most effective drying agent will be $C_{(s)}$ out of $C_{(s)}$,$B \cdot 7H_2O_{(s)}$,and $A \cdot 2H_2O_{(s)}$.
$(II)$ At $0\,^{\circ}C$,$A \cdot 6H_2O_{(s)}$ and $B \cdot 12H_2O_{(s)}$ will be efflorescent.
$(III)$ If $R.H.$ is less than $100\%$ in a chamber at $0\,^{\circ}C$,then none of the substances can act as deliquescent.

In a $1 \, L$ container,the reaction of $2 \, mol$ $N_2$ and $5 \, mol$ $H_2$ occurs. If the equilibrium concentration of $NH_3$ is half the equilibrium concentration of $N_2$,what is the equilibrium constant $(K_c)$?

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