Carnallite in solution in $H_2O$,shows the properties of

Which one has the highest boiling point?

The elevation in boiling point of a solution of $13.44 \ g$ of $CuCl_2$ in $1 \ kg$ of water using the following information will be (Molecular weight of $CuCl_2 = 134.4 \ g \ mol^{-1}$ and $K_b = 0.52 \ K \ kg \ mol^{-1}$)

$0.8 \ mL$ of acetic acid of density $1.06 \ g \ mL^{-1}$ when dissolved in $1 \ kg$ of water causes a depression in freezing point by $0.0325^{\circ} C$. The Van't Hoff factor is:
$(K_{f} \text{ of } H_2O = 1.86 \ K \ kg \ mol^{-1})$

$A$ $0.5 \ m$ aqueous solution of a weak acid $(HX)$ is $20\%$ ionized. If $K_f$ for the solvent is $1.86 \ K \ kg \ mol^{-1}$,the depression in freezing point of the solution is ..... $K$.

The elevation in the boiling point of an aqueous solution of $NaCl$ is $0.01^{\circ}C$. If its van't Hoff factor is $1.92$,the molality of the $NaCl$ solution is: $(K_{b} \text{ for water} = 0.52 \ K \ kg \ mol^{-1})$ (in $m$)