$0.8 \ mL$ of acetic acid of density $1.06 \ g \ mL^{-1}$ when dissolved in $1 \ kg$ of water causes a depression in freezing point by $0.0325^{\circ} C$. The Van't Hoff factor is:
$(K_{f} \text{ of } H_2O = 1.86 \ K \ kg \ mol^{-1})$

The freezing point of equimolal aqueous solution will be highest for

$19.5 \text{ g}$ of fluoroacetic acid (molar mass = $78 \text{ g mol}^{-1}$) is dissolved in $500 \text{ g}$ of water at $298 \text{ K}$. The depression in the freezing point of water was $1^\circ\text{C}$. What is $K_a$ of fluoroacetic acid? (For water,$K_f = 1.86 \text{ K kg mol}^{-1}$). Assume molarity and molality to have same values.

The addition of a polar solvent to a solid electrolyte results in

Osmotic pressure of a $4.44\%$ solution of anhydrous $CaCl_2$ was found to be $16.42 \ atm$ at $27 \, ^\circ C$. What is the degree of dissociation of $CaCl_2$ in $\%$?

We have three aqueous solutions of $NaCl$ labelled as '$A$','$B$' and '$C$' with concentrations $0.1 \ M$,$0.01 \ M$,and $0.001 \ M$ respectively. The value of the Van't Hoff factor for these solutions will be in the order . . . . . . .