Among the following given substances,the one with zero $\Delta_{f}H^{\circ}$ is

Fill in the blanks:
$(i)$ The enthalpy change that occurs when one mole of a compound is formed from its constituent elements in their standard states is called the ...... of that compound.
$(ii)$ The total heat change in a chemical reaction is equal to the algebraic sum of the heat changes of the individual steps of the reaction. This law was given by ............. .
$(iii)$ $A$ process during which there is no exchange of heat between the system and the surroundings is called an ................ process.
$(iv)$ The standard enthalpy value of any element in its standard state is considered to be ...... .

Given:
$(i) \, C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = x \, kJ \, mol^{-1}$
$(ii) \, C(\text{graphite}) + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\ominus = y \, kJ \, mol^{-1}$
$(iii) \, CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = z \, kJ \, mol^{-1}$
Based on the above thermochemical equations,find out which one of the following algebraic relationships is correct?

Enthalpies of formation of $CCl_{4(g)}$,$H_2O_{(g)}$,$CO_{2(g)}$ and $HCl_{(g)}$ are $-105$,$-242$,$-394$ and $-92 \ kJ \ mol^{-1}$ respectively. The magnitude of enthalpy of the reaction given below is $...... \ kJ \ mol^{-1}$ (nearest integer): $CCl_{4(g)} + 2H_2O_{(g)} \rightarrow CO_{2(g)} + 4HCl_{(g)}$

Calculate $\Delta H$ in $kJ$ for the following reaction:
$C_{(s)} + O_{2(g)} \longrightarrow CO_{2(g)}$
Given that:
$H_2O_{(g)} + C_{(s)} \longrightarrow CO_{(g)} + H_{2(g)} ; \Delta H = +131 \ kJ$
$CO_{(g)} + \frac{1}{2} O_{2(g)} \longrightarrow CO_{2(g)} ; \Delta H = -282 \ kJ$
$H_{2(g)} + \frac{1}{2} O_{2(g)} \longrightarrow H_2O_{(g)} ; \Delta H = -242 \ kJ$

The heat of neutralisation of an acid by a base is highest when: