Which of the following mixtures is known as Proof Spirit (by volume)?

Identify the correct statement from the following properties.

For a dilute solution containing $2.5 \ g$ of a non-volatile non-electrolyte solute in $100 \ g$ of water,the elevation in boiling point at $1 \ atm$ pressure is $2 \ ^\circ C$. Assuming the amount of solute is much lower than the amount of solvent,the vapour pressure $(mm \ Hg)$ of the solution is: (take $K_b = 0.76 \ K \ kg \ mol^{-1}$)

Distilled water boils at $373.15 \ K$ and freezes at $273.15 \ K$. $A$ solution of glucose in distilled water boils at $373.202 \ K$. What is the freezing point (in $K$) of the same solution? (For water,$K_{b}=0.52 \ K \ kg \ mol^{-1}, \ K_{f}=1.86 \ K \ kg \ mol^{-1}$)

An aqueous solution contains $6\%$ and $4\%$ by weight of a weak acid $(HA)$ and urea respectively. If the depression in freezing point is $\frac{13.6}{3} \, ^{\circ}C$,calculate the $K_a$ of $HA$. [Given: $K_f = 1.8 \, K \, kg/mol$,Molecular weight of $HA = 60$,$d_{solution} = 1 \, g/mL$]

Calculate the solubility (in $\text{moles/litre}$) of a saturated aqueous solution of $Ag_3PO_4$ if the vapour pressure of the solution becomes $750 \ torr$ at $373 \ K$. (Assume vapour pressure of pure water at $373 \ K$ is $760 \ torr$ and density of water is $1 \ g/mL$)