Which of the following complexes is an outer orbital complex?

  • A
    $[Ni(NH_3)_6]^{2+}$
  • B
    $[Mn(CN)_6]^{4-}$
  • C
    $[Co(NH_3)_6]^{3+}$
  • D
    $[Fe(CN)_6]^{4-}$

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Cobalt chloride when dissolved in water forms a pink-colored complex $X$ which has an octahedral geometry. This solution,upon treatment with concentrated $HCl$,forms a deep blue complex $Y$ which has a $Z$ geometry. $X$,$Y$,and $Z$,respectively,are:

Match List-$I$ with List-$II$.
List-$I$ List-$II$
$A$. $[MnBr_4]^{2-}$ $I$. $d^2sp^3$ and diamagnetic
$B$. $[FeF_6]^{3-}$ $II$. $sp^3d^2$ and paramagnetic
$C$. $[Co(C_2O_4)_3]^{3-}$ $III$. $sp^3$ and diamagnetic
$D$. $[Ni(CO)_4]$ $IV$. $sp^3$ and paramagnetic

Choose the correct answer from the options given below:

Match List-$I$ with List-$II$.
List-$I$ List-$II$
$A. Ni(CO)_4$ $I. sp^3$
$B. [Ni(CN)_4]^{2-}$ $II. sp^3d^2$
$C. [Co(CN)_6]^{3-}$ $III. d^2sp^3$
$D. [CoF_6]^{3-}$ $IV. dsp^2$

Choose the correct answer from the options given below.

The number of unpaired electrons in $Ni(CO)_4$ is ..........

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In the complex $cis-[Cr(en)_2Cl_2]^+$,the oxidation state of $Cr$,the type of $d$-orbital involved in the valence shell,and the coordination number are respectively:

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