When it is not possible to calculate the enthalpy of a reaction experimentally,it can be calculated by .....

Given that $C + O_{2} \longrightarrow CO_{2} ; \Delta H^{\circ} = -x \ kJ$ and $2 CO + O_{2} \longrightarrow 2 CO_{2} ; \Delta H^{\circ} = -y \ kJ$. The heat of formation of carbon monoxide will be

Calculate the heat of reaction for the process: $NH_3(g) + HCl(g) \rightarrow NH_4Cl(s)$ given the following data:
$(i)$ $NH_3(g) + aq \rightarrow NH_3(aq)$,$\Delta H = -8.4 \, Kcal$
$(ii)$ $HCl(g) + aq \rightarrow HCl(aq)$,$\Delta H = -17.3 \, Kcal$
$(iii)$ $NH_3(aq) + HCl(aq) \rightarrow NH_4Cl(aq)$,$\Delta H = -12.5 \, Kcal$
$(iv)$ $NH_4Cl(s) + aq \rightarrow NH_4Cl(aq)$,$\Delta H = +3.9 \, Kcal$ (in $, Kcal$)

Equal volumes of $1 \, M \, HCl$ and $1 \, M \, H_2SO_4$ are neutralized by a dilute $NaOH$ solution,and $x$ and $y \, kcal$ of heat are liberated,respectively. Which of the following is correct?

Based on Hess's law calculations,what is the average $S-O$ bond energy in $SO_3$ if $\Delta H_f^o$ of $SO_3$ is $-270 \ kJ \ mol^{-1}$. Given: Bond energy of $O=O$ is $495 \ kJ \ mol^{-1}$,heat of sublimation for $S_{(s)}$ is $277 \ kJ \ mol^{-1}$,and bond energy of $S=O$ is not provided,but we assume the formation reaction: $S_{(s)} + \frac{3}{2} O_{2(g)} \rightarrow SO_{3(g)}$. Use the atomization energy of $S_{(s)} = 277 \ kJ \ mol^{-1}$ and $O=O = 495 \ kJ \ mol^{-1}$. Calculate the average $S-O$ bond energy in $SO_3$.

Given:
$(i) \, C(\text{graphite}) + O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = x \, kJ \, mol^{-1}$
$(ii) \, C(\text{graphite}) + \frac{1}{2} O_{2(g)} \to CO_{(g)}; \Delta_r H^\ominus = y \, kJ \, mol^{-1}$
$(iii) \, CO_{(g)} + \frac{1}{2} O_{2(g)} \to CO_{2(g)}; \Delta_r H^\ominus = z \, kJ \, mol^{-1}$
Based on the above thermochemical equations,find out which one of the following algebraic relationships is correct?