Equal volumes of $1 \, M \, HCl$ and $1 \, M \, H_2SO_4$ are neutralized by a dilute $NaOH$ solution,and $x$ and $y \, kcal$ of heat are liberated,respectively. Which of the following is correct?

Calculate the heat of formation for propene $(C_3H_6)$ using the following thermochemical equations:
$(i) C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H_1 = -94.05 \ k.cal/mole$
$(ii) H_{2(g)} + \frac{1}{2} O_{2(g)} \to H_2O_{(l)}; \Delta H_2 = -68.32 \ k.cal/mole$
$(iii) C_3H_{6(g)} + \frac{9}{2} O_{2(g)} \to 3 CO_{2(g)} + 3 H_2O_{(l)}; \Delta H_3 = -499.7 \ k.cal/mole$
(Note: The original question provided propane combustion data; assuming propene combustion data for consistency).

Calculate the enthalpy of formation of sucrose $(C_{12}H_{22}O_{11})$ in $kJ \, mol^{-1}$ using the following data:
$(i) \, C_{12}H_{22}O_{11} + 12O_2 \to 12CO_2 + 11H_2O, \, \Delta H = -5200.7 \, kJ \, mol^{-1}$
$(ii) \, C + O_2 \to CO_2, \, \Delta H = -394.5 \, kJ \, mol^{-1}$
$(iii) \, H_2 + \frac{1}{2}O_2 \to H_2O, \, \Delta H = -285.8 \, kJ \, mol^{-1}$

For the reaction $R \rightarrow P$,the following potential energy diagram is given. What will be the enthalpy change $(\Delta H)$ for the given reaction (in $kJ$)?

Based on the following thermochemical equations:
$H_2O_{(g)} + C_{(s)} \to CO_{(g)} + H_{2(g)}; \Delta H = 131 \ kJ$
$CO_{(g)} + \frac{1}{2}O_{2(g)} \to CO_{2(g)}; \Delta H = -282 \ kJ$
$H_{2(g)} + \frac{1}{2}O_{2(g)} \to H_2O_{(g)}; \Delta H = -242 \ kJ$
$C_{(s)} + O_{2(g)} \to CO_{2(g)}; \Delta H = X \ kJ$
The value of $X$ is ...... $kJ$.

The bond energies of $H-H$ and $Cl-Cl$ are $430 \, kJ/mol$ and $240 \, kJ/mol$ respectively. If $\Delta_f H$ for $HCl$ is $-90 \, kJ/mol$,then the bond enthalpy of $HCl$ will be ...... $kJ/mol$.