Which of the following graphs correctly represents the changes in thermodynamic properties during the formation of $1 \, mol$ of an ideal binary solution?

The osmotic pressure of a solution of $NaCl$ is $0.10 \ atm$ and that of a glucose solution is $0.20 \ atm.$ The osmotic pressure of a solution formed by mixing $1 \ L$ of the sodium chloride solution with $2 \ L$ of the glucose solution is $x \times 10^{-3} \ atm.$ $x$ is.......... (nearest integer)

Elevation in boiling point for $1.5 \, m$ solution of glucose in water is $4 \, K$. The depression in freezing point for $4.5 \, m$ solution of glucose in water is $4 \, K$. The ratio of molal elevation constant to molal depression constant $(K_{b} / K_{f})$ is $....$

$A$ saturated solution of $Ag_2SO_4$ shows a $0.003 \ K$ rise in boiling point. Calculate the $K_{sp}$ of $Ag_2SO_4$. Given: $K_b = 5 \ K \ kg \ mol^{-1}$ and $1 \ m = 1 \ M$.

Statement $1$: The cold pack used by athletes to treat injuries on the field works by dissolving a solute in water,which causes the temperature to decrease. Statement $2$: Adding a non-volatile solute to a solvent decreases its freezing point.

An aqueous solution of $NaCl$ shows the depression of freezing point of water equal to $0.372 \, K$. The boiling point of $BaCl_2$ solution of same molality will be .........$^oC$. $[K_f(H_2O) = 1.86 \, K \, kg \, mol^{-1}; K_b(H_2O) = 0.52 \, K \, kg \, mol^{-1}]$