Which one of the following statements is correct for $d^4$ ions $(P = \text{pairing energy})$?

  • A
    When $\Delta_0 > P$,low-spin complex forms
  • B
    When $\Delta_0 < P$,low-spin complex forms
  • C
    When $\Delta_0 > P$,high-spin complex forms
  • D
    When $\Delta_0 < P$,both high-spin and low-spin complexes form

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$CuSO_4 \cdot 5 H_2O$ is blue in colour while $CuSO_4$ is colourless. Why?

The electronic spectrum of $[Ti(H_2O)_6]^{3+}$ shows a single broad peak with a maximum at $20,300 \, cm^{-1}$. The crystal field stabilization energy $(CFSE)$ of the complex ion,in $kJ \, mol^{-1}$,is :

Absorbed colour of the solutions of the following complexes $[M(NH_3)_6]^{2+}$,$[M(H_2O)_6]^{2+}$ and $[MCl_4]^{2-}$ are respectively (having the same metal ion):

Match the electronic configurations in List-$I$ with appropriate metal complex ions in List-$II$ and choose the correct option.
[Atomic Number: $Fe=26, Mn=25, Co=27$]
List-$I$ List-$II$
$P$. $t_{2g}^6 e_g^0$ $1$. $[Fe(H_2O)_6]^{2+}$
$Q$. $t_{2g}^3 e_g^2$ $2$. $[Mn(H_2O)_6]^{2+}$
$R$. $e^2 t_2^3$ $3$. $[Co(NH_3)_6]^{3+}$
$S$. $t_{2g}^4 e_g^2$ $4$. $[FeCl_4]^{-}$
$5$. $[CoCl_4]^{2-}$

Which of the following spectrochemical series is correct?

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