Which of the following would give a linear plot?
($k$ is the rate constant of an elementary reaction and $T$ is temperature in absolute scale)

  • A
    $k$ vs $T$
  • B
    $k$ vs $1 / T$
  • C
    $\ln k$ vs $T$
  • D
    $\ln k$ vs $1 / T$

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According to the collision theory of chemical reactions:

From the given data for the reaction $H_2 + I_2 \rightarrow 2HI$,calculate the activation energy $(E_a)$:
$T_1 = 769 \ K, \ 1/T_1 = 1.3 \times 10^{-3} \ K^{-1}, \ \log_{10} K_1 = 2.9$
$T_2 = 667 \ K, \ 1/T_2 = 1.5 \times 10^{-3} \ K^{-1}, \ \log_{10} K_2 = 1.1$

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All energetically effective collisions do not result in a chemical change. Explain with the help of an example.

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For the forward reaction $X \rightarrow Y$,the activation energy is $60 \ kJ \ mol^{-1}$ and $\Delta H = -20 \ kJ \ mol^{-1}$. What is the activation energy for the reverse reaction $Y \rightarrow X$ in $kJ \ mol^{-1}$?

The first order rate constant for the decomposition of ethyl iodide by the reaction $C_{2}H_{5}I_{(g)} \rightarrow C_{2}H_{4(g)} + HI_{(g)}$ at $600 \ K$ is $1.60 \times 10^{-5} \ s^{-1}$. Its energy of activation is $209 \ kJ/mol$. Calculate the rate constant of the reaction at $700 \ K$.

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